TOBACCO & VANILLA FRAGRANCE

Hazard statements (CLP)

H315, H317, H319, H410

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Signal word

Warning

Hazard statements

H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H410, Very toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains (1S,2R,5S,7R,8R)-8-METHOXY-2,6,6,8-TETRAMETHYLTRICYCLO[5.3.1.0 ^{1,5}]UNDECANE, ALPHA-ZINGIBERENE, COUMARIN, EUGENOL, TRANS-ANETHOLE. May produce an allergic reaction.

Precautionary statements

P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

Sensitisers declared on a CLP (1S,2R,5S,7R,8R)-8-METHOXY-2,6,6,8- Hazard Label: TETRAMETHYLTRICYCLO[5.3.1.0^{1,5}]UNDECANE, ALPHA-ZINGIBERENE, COUMARIN, EUGENOL, TRANS- ANETHOLE Hydrocarbon Concentration %: 0.000%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Skin Corrosion / Irritation Category 2 danger: Eye Damage / Irritation Category 2 Sensitization - Skin Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 1 H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H410, Very toxic to aquatic life with long lasting effects. 16 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Warning Hazard statements: H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H410, Very toxic to aquatic life with long lasting effects. Supplemental EUH208, Contains (1S,2R,5S,7R,8R)-8-METHOXY-2,6,6,8-TETRAMETHYLTRICYCLO[5.3.1.0 Information: ^{1,5}]UNDECANE, ALPHA-ZINGIBERENE, COUMARIN, EUGENOL, TRANS-ANETHOLE. May produce an allergic reaction. Precautionary P261, Avoid breathing vapour or dust. statements: P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: 2.3 Other hazards Other hazards: Sensitisers declared on a CLP (1S,2R,5S,7R,8R)-8-METHOXY-2,6,6,8- Hazard Label: TETRAMETHYLTRICYCLO[5.3.1.0^{1,5}]UNDECANE, ALPHA-ZINGIBERENE, COUMARIN, EUGENOL, TRANS- ANETHOLE Hydrocarbon Concentration %: 0.000% 16 Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs 259-174-3, 54464-57-2, TETRAMETHYL 54464-59-4, 259-175-9, SCI 2-SS 1B-EH C1; ACETYLOCTAHYDRON 68155-66-8, 268-978-3, 01-2119489989-04-xxxx 20-<50% H315-H317-H410,- APHTHALENES 268-979-9, 68155-67-9 915-730-3 4-TERT- oral: ATE = 3370 BUTYLCYCLOHEXYL 32210-23-4 250-954-9 01-2119976286-24-xxxx 10-<20% SS 1B;H317,- mg/kg bw ACETATE BENZYL BENZOATE 120-51-4 204-402-9 10-<20% ATO 4-EH A1-EH C2; oral: ATE = 1160 H302-H400-H411,- mg/kg bw ETHYL VANILLIN 121-32-4 204-464-7 1-<5% EDI 2;H319,- oral: ATE = 3000 mg/kg bw dermal: ATE = 2600 VANILLIN 121-33-5 204-465-2 1-<5% EDI 2;H319,- mg/kg bw-oral: ATE = 3300 mg/kg bw OCTAHYDROCOUMAR dermal: ATE = 3500 IN 4430-31-3 224-623-4 1-<5% EDI 1;H318,- mg/kg bw-oral: ATE = 3900 mg/kg bw HELIOTROPINE 120-57-0 204-409-7 1-<5% SS 1B;H317,- oral: ATE = 2700 mg/kg bw ATO 4-ATI 4-EDI 2; inhalation: ATE = 4178 BENZYL ALCOHOL 100-51-6 202-859-9 01-2119492630-38-xxxx 1-<5% H302-H319-H332,- ppmV (gas)-oral: ATE = 1570 mg/kg bw DIMETHYL PHENETHYL 10094-34-5 233-221-8 01-2120742578-44-xxxx 1-<5% EH C2;H411,- BUTYRATE EUGENOL 97-53-0 202-589-1 0.1-<1% EDI 2-SS 1B;H317- oral: ATE = 2500 H319,- mg/kg bw ALPHA-ZINGIBERENE 495-60-3 0.1-<1% SS 1B;H317,- (1S,2R,5S,7R,8R)-8- METHOXY-2,6,6,8- SS 1B-EH A1-EH C1; TETRAMETHYLTRICY 67874-81-1 267-510-5 0.1-<1% H317-H410,- CLO[5.3.1.0^{1,5}] UNDECANE COUMARIN 91-64-5 202-086-7 0.1-<1% ATO 4-SS 1B-EH C3; oral: ATE = 500 mg/kg H302-H317-H412,- bw TRANS-ANETHOLE 4180-23-8 224-052-0 0.1-<1% SS 1B;H317,- oral: ATE = 3000 mg/kg bw SCI 2-EDI 2-SS 1A-EH oral: ATE = 2220 CINNAMAL 104-55-2 203-213-9 0.1-<1% C3;H315-H317-H319- mg/kg bw H412,- Substances with Community workplace exposure limits: Not Applicable Substances that are endocrine disruptors according to Regulation (EU) 2017/2100 or Regulation (EU) 2018/605, greater than 0.1%: Not Applicable 16 Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin exposure: IF ON SKIN: Wash with plenty of soap and water. Ingestion: Rinse mouth with water and obtain medical attention. 4.2 Most important symptoms and effects, both acute and delayed Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. Section 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 16 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation Do not eat, drink or smoke when using this product. 7.2 Conditions for safe storage, including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s): Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: Not Applicable 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Under normal conditions of use and where adequate ventilation is available to prevent build up of excessive vapour, this material should not require special engineering controls. However, in conditions of high or prolonged use, or high temperature or other conditions which increase exposure, the following engineering controls can be used to minimise exposure to personnel: a) Increase ventilation of the area with local exhaust ventilation. b) Personnel can use an approved, appropriately fitted respirator with organic vapour cartridge or canisters and particulate filters. c) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. Section 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Physical State/Colour: Clear colourless to pale yellow liquid 16 Odour: Not determined Odour threshold: Not determined Melting point / freezing point: Not determined Boiling point or initial boiling point and boiling Not determined range: Flammability: Not determined Lower and upper explosion limit: Not determined Flash point: > 100 °C Auto-ignition temperature: Not determined Decomposition temperature: Not relevant pH: Not determined Kinematic viscosity: Not determined Solubility: Not determined Partition coefficient: n-octanol/water (log Not determined value): Vapour pressure: 0.02142532 mmHg Density and/or relative density: 1.0120 Relative vapour density: Not determined Particle characteristics: Not determined 9.2 Other information: None available Section 10. Stability and reactivity 10.1 Reactivity: Presents no significant reactivity hazard, by itself or in contact with water. 10.2 Chemical stability: Good stability under normal storage conditions. 10.3 Possibility of hazardous reactions: Not expected under normal conditions of use.