SIY FRAGRANCE

Hazard statements (CLP)

H315, H317, H319, H411

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Signal word

Warning

Hazard statements

H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains (1S,5S)-6,6-DIMETHYL-2-METHYLIDENEBICYCLO[3.1.1]HEPTANE, ALPHA-ISOMETHYL IONONE, CINNAMYL ALCOHOL, EUGENOL, GERANIOL, HELIOTROPINE, HEXYL SALICYLATE, NEROL, TETRAMETHYLTRICYCLOPROPANOL. May produce an allergic reaction.

Precautionary statements

P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

Sensitisers declared on a CLP (1S,5S)-6,6-DIMETHYL-2-METHYLIDENEBICYCLO[3.1.1] Hazard Label: HEPTANE, ALPHA-ISOMETHYL IONONE, CINNAMYL ALCOHOL, EUGENOL, GERANIOL, HELIOTROPINE, HEXYL SALICYLATE, NEROL, TETRAMETHYLTRICYCLOPROPANOL Hydrocarbon Concentration %: 0.000%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Skin Corrosion / Irritation Category 2 danger: Eye Damage / Irritation Category 2 Sensitization - Skin Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects. 31 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Warning Hazard statements: H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects. Supplemental EUH208, Contains (1S,5S)-6,6-DIMETHYL-2-METHYLIDENEBICYCLO[3.1.1]HEPTANE, Information: ALPHA-ISOMETHYL IONONE, CINNAMYL ALCOHOL, EUGENOL, GERANIOL, HELIOTROPINE, HEXYL SALICYLATE, NEROL, TETRAMETHYLTRICYCLOPROPANOL. May produce an allergic reaction. Precautionary P261, Avoid breathing vapour or dust. statements: P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: 2.3 Other hazards Other hazards: Sensitisers declared on a CLP (1S,5S)-6,6-DIMETHYL-2-METHYLIDENEBICYCLO[3.1.1] Hazard Label: HEPTANE, ALPHA-ISOMETHYL IONONE, CINNAMYL ALCOHOL, EUGENOL, GERANIOL, HELIOTROPINE, HEXYL SALICYLATE, NEROL, TETRAMETHYLTRICYCLOPROPANOL Hydrocarbon Concentration %: 0.000% 31 Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs BENZYL SALICYLATE 118-58-1 204-262-9 20-<50% SS 1B-EH C3;H317- oral: ATE = 2200 H412,- mg/kg bw 1,3,4,6,7,8- HEXAHYDRO- 4,6,6,7,8,8- 1222-05-5 214-946-9 01-2119488227-29-xxxx 10-<20% EH A1-EH C1;H410,- HEXAMETHYLINDENO [5,6-C]PYRAN 259-174-3, 54464-57-2, TETRAMETHYL 54464-59-4, 259-175-9, SCI 2-SS 1B-EH C1; ACETYLOCTAHYDRON 68155-66-8, 268-978-3, 01-2119489989-04-xxxx 10-<20% H315-H317-H410,- APHTHALENES 268-979-9, 68155-67-9 915-730-3 2,6-DIMETHYL-7- SCI 2-EDI 2-STO-SE 3 oral: ATE = 3020 OCTEN-2-OL 18479-58-8 242-362-4 1-<5% (NE);H315-H319-H336, mg/kg bw - 2-T- EDI 2-EH C2;H319- BUTYLCYCLOHEXYLO 139504-68-0 412-300-2 1-<5% H411,- XYBUTANOL dermal: ATE = 2600 VANILLIN 121-33-5 204-465-2 1-<5% EDI 2;H319,- mg/kg bw-oral: ATE = 3300 mg/kg bw TETRAHYDRO- METHYL- 63500-71-0 405-040-6 01-0000015458-64-xxxx 1-<5% EDI 2;H319,- (METHYLPROPYL)- PYRAN-4-OL ETHYL 106185-75-5, 701-122-3, EDI 2-EH C2;H319- TRIMETHYLCYCLOPE 28219-61-6 248-908-8 01-2119529224-45-xxxx 1-<5% H411,- NTENE BUTENOL PHENETHYL ATO 4-EDI 2;H302- dermal: ATE = 2500 ALCOHOL 60-12-8 200-456-2 01-2119963921-31-xxxx 1-<5% H319,- mg/kg bw-oral: ATE = 1610 mg/kg bw ETHYL 4940-11-8 225-582-5 1-<5% ATO 4;H302,- oral: ATE = 1200 HYDROXYPYRONE mg/kg bw HEXYL SALICYLATE 6259-76-3 228-408-6 01-2119638275-36-xxxx 0.1-<1% SS 1B-EH A1-EH C1; H317-H410,- GERANIOL 106-24-1 203-377-1 01-2119552430-49-xxxx 0.1-<1% SCI 2-EDI 1-SS 1; oral: ATE = 3600 H315-H317-H318,- mg/kg bw ALPHA-ISOMETHYL 127-51-5 204-846-3 0.1-<1% SS 1B-EH C2;H317- IONONE H411,- CINNAMYL ALCOHOL 104-54-1 203-212-3 0.1-<1% ATO 4-SS 1B-EH C2; oral: ATE = 2000 H302-H317-H411,- mg/kg bw (1S,5S)-6,6-DIMETHYL- FL 3-SCI 2-SS 1B-AH 2- 18172-67-3 242-060-2 0.1-<1% 1-EH A1-EH C1;H226- METHYLIDENEBICYCL H304-H315-H317- O[3.1.1]HEPTANE H410,- NEROL 106-25-2 203-378-7 0.1-<1% SCI 2-EDI 2-SS 1B; oral: ATE = 4500 H315-H317-H319,- mg/kg bw TETRAMETHYLTRICY 929625-08-1, SCI 2-SS 1-EH A1-EH CLOPROPANOL 1001252-30- 482-030-8 0.1-<1% C1;H315-H317-H410,- 7 (E)-1-(2,6,6- TRIMETHYL-1,3- 23726-93-4 245-844-2 01-2120105798-49-xxxx 0.1-<1% SCI 2-SS 1A-EH C2; dermal: ATE = 2900 CYCLOHEXADIEN-1- H315-H317-H411,- mg/kg bw YL)-2-BUTEN-1-ONE 31 EUGENOL 97-53-0 202-589-1 0.1-<1% EDI 2-SS 1B;H317- oral: ATE = 2500 H319,- mg/kg bw GERANYL 2345-26-8 219-062-7 0.1-<1% EH A1-EH C1;H410,- ISOBUTYRATE HELIOTROPINE 120-57-0 204-409-7 0.1-<1% SS 1B;H317,- oral: ATE = 2700 mg/kg bw Substances with Community workplace exposure limits: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs DIETHYL PHTHALATE 84-66-2 201-550-6 01-2119486682-27-xxxx 20-<50% -;-,- Substances that are endocrine disruptors according to Regulation (EU) 2017/2100 or Regulation (EU) 2018/605, greater than 0.1%: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin exposure: IF ON SKIN: Wash with plenty of soap and water. Ingestion: Rinse mouth with water and obtain medical attention. 4.2 Most important symptoms and effects, both acute and delayed Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. Section 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 31 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation Do not eat, drink or smoke when using this product. 7.2 Conditions for safe storage, including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge.