ROSE

Hazard statements (CLP)

H315, H317, H319, H411

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Signal word

Warning

Hazard statements

H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains (1S,5S)-6,6-DIMETHYL-2-METHYLIDENEBICYCLO[3.1.1]HEPTANE, (ETHOXYMETHYL)CYCLODODECANE, 3-(2H-1,3-BENZODIOXOL-5-YL)-2- METHYLPROPANAL, ALPHA-ISOMETHYL IONONE, BETA-PINENES, CITRAL, CITRONELLOL, DELTA-DAMASCONE, GERANIOL, GERANYL ACETATE, LIMONENE, LINALOOL, NEROL. May produce an allergic reaction.

Precautionary statements

P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

Sensitisers declared on a CLP (1S,5S)-6,6-DIMETHYL-2-METHYLIDENEBICYCLO[3.1.1] Hazard Label: HEPTANE, (ETHOXYMETHYL)CYCLODODECANE, 3-(2H- 1,3-BENZODIOXOL-5-YL)-2-METHYLPROPANAL, ALPHA- ISOMETHYL IONONE, BETA-PINENES, CITRAL, CITRONELLOL, DELTA-DAMASCONE, GERANIOL, GERANYL ACETATE, LIMONENE, LINALOOL, NEROL Hydrocarbon Concentration %: 0.000%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Skin Corrosion / Irritation Category 2 danger: Eye Damage / Irritation Category 2 Sensitization - Skin Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects. 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Warning 25 Hazard statements: H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects. Supplemental EUH208, Contains (1S,5S)-6,6-DIMETHYL-2-METHYLIDENEBICYCLO[3.1.1]HEPTANE, Information: (ETHOXYMETHYL)CYCLODODECANE, 3-(2H-1,3-BENZODIOXOL-5-YL)-2- METHYLPROPANAL, ALPHA-ISOMETHYL IONONE, BETA-PINENES, CITRAL, CITRONELLOL, DELTA-DAMASCONE, GERANIOL, GERANYL ACETATE, LIMONENE, LINALOOL, NEROL. May produce an allergic reaction. Precautionary P261, Avoid breathing vapour or dust. statements: P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: 2.3 Other hazards Other hazards: Sensitisers declared on a CLP (1S,5S)-6,6-DIMETHYL-2-METHYLIDENEBICYCLO[3.1.1] Hazard Label: HEPTANE, (ETHOXYMETHYL)CYCLODODECANE, 3-(2H- 1,3-BENZODIOXOL-5-YL)-2-METHYLPROPANAL, ALPHA- ISOMETHYL IONONE, BETA-PINENES, CITRAL, CITRONELLOL, DELTA-DAMASCONE, GERANIOL, GERANYL ACETATE, LIMONENE, LINALOOL, NEROL Hydrocarbon Concentration %: 0.000% 25 Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs 259-174-3, 54464-57-2, TETRAMETHYL 54464-59-4, 259-175-9, SCI 2-SS 1B-EH C1; ACETYLOCTAHYDRON 68155-66-8, 268-978-3, 01-2119489989-04-xxxx 10-<20% H315-H317-H410,- APHTHALENES 268-979-9, 68155-67-9 915-730-3 LINALYL ACETATE 115-95-7 204-116-4 01-2119454789-19-xxxx 1-<5% SCI 2-EDI 2-SS 1B; H315-H317-H319,- PHENETHYL ATO 4-EDI 2;H302- dermal: ATE = 2500 ALCOHOL 60-12-8 200-456-2 01-2119963921-31-xxxx 1-<5% H319,- mg/kg bw-oral: ATE = 1610 mg/kg bw HEXYL CINNAMAL 101-86-0 202-983-3 1-<5% SS 1B-EH A1-EH C2; oral: ATE = 3100 H317-H400-H411,- mg/kg bw HYDROXYCITRONELL 107-75-5 203-518-7 1-<5% EDI 2-SS 1B;H317- AL H319,- 2,4-DIMETHYL-4,4A,5,9 B- 27606-09-3 248-561-2 01-2120234292-65-xxxx 1-<5% ATO 4-EH C3;H302- oral: ATE = 500 mg/kg TETRAHYDROINDENO H412,- bw -1,3-DIOXIN 2-T- EDI 2-EH C2;H319- BUTYLCYCLOHEXYLO 139504-68-0 412-300-2 1-<5% H411,- XYBUTANOL GERANIOL 106-24-1 203-377-1 01-2119552430-49-xxxx 1-<5% SCI 2-EDI 1-SS 1; oral: ATE = 3600 H315-H317-H318,- mg/kg bw 106-22-9, 203-375-0, 1117-61-9, 214-250-5, 26489-01-0, 247-737-6, SCI 2-EDI 2-SS 1B; dermal: ATE = 2650 CITRONELLOL 6812-78-8, 229-887-4, 01-2119453995-23-xxxx 1-<5% H315-H317-H319,- mg/kg bw-oral: ATE = 3450 mg/kg bw 141-25-3, 205-473-9, 7540-51-4 231-415-7 (ETHOXYMETHYL) 58567-11-6 261-332-1 1-<5% SCI 2-SS 1B-EH C2; CYCLODODECANE H315-H317-H411,- NEROL 106-25-2 203-378-7 0.1-<1% SCI 2-EDI 2-SS 1B; oral: ATE = 4500 H315-H317-H319,- mg/kg bw FL 3-SCI 2-SS 1B-AH LIMONENE 5989-27-5 227-813-5 0.1-<1% 1-EH A1-EH C3;H226- H304-H315-H317- H400-H412,- ALPHA-ISOMETHYL 127-51-5 204-846-3 0.1-<1% SS 1B-EH C2;H317- IONONE H411,- 3-(2H-1,3- SS 1B-REP 2-EH C2; oral: ATE = 3562 BENZODIOXOL-5-YL) 1205-17-0 214-881-6 01-2120740119-58-xxxx 0.1-<1% H317-H361-H411,- mg/kg bw -2-METHYLPROPANAL FL 3-SCI 2-SS 1B-AH BETA-PINENES 127-91-3 204-872-5 0.1-<1% 1-EH A1-EH C1;H226- H304-H315-H317- H410,- CITRAL 5392-40-5 226-394-6 01-2119462829-23-xxxx 0.1-<1% SCI 2-EDI 2-SS 1; H315-H317-H319,- GERANYL ACETATE 105-87-3 203-341-5 01-2119973480-35-xxxx 0.1-<1% SCI 2-SS 1B-EH C3; H315-H317-H412,- (1S,5S)-6,6-DIMETHYL- FL 3-SCI 2-SS 1B-AH 2- 18172-67-3 242-060-2 0.1-<1% 1-EH A1-EH C1;H226- METHYLIDENEBICYCL H304-H315-H317- O[3.1.1]HEPTANE H410,- 25 LINALOOL 78-70-6 201-134-4 01-2119474016-42-xxxx 0.1-<1% SCI 2-EDI 2-SS 1B; oral: ATE = 2790 H315-H317-H319,- mg/kg bw ATO 4-SCI 2-SS 1A- oral: ATE = 1400 DELTA-DAMASCONE 57378-68-4 260-709-8 <0.1% EH A1-EH C1;H302- mg/kg bw H315-H317-H410,- Substances with Community workplace exposure limits: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs DIETHYL PHTHALATE 84-66-2 201-550-6 01-2119486682-27-xxxx 20-<50% -;-,- Substances that are endocrine disruptors according to Regulation (EU) 2017/2100 or Regulation (EU) 2018/605, greater than 0.1%: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin exposure: IF ON SKIN: Wash with plenty of soap and water. Ingestion: Rinse mouth with water and obtain medical attention. 4.2 Most important symptoms and effects, both acute and delayed Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. Section 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 25 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil.