ORANGE CLOVE FRAGRANCE

Hazard statements (CLP)

H304, H315, H317, H319, H400, H411

Code

Statements

H304

May be fatal if swallowed and enters airways

SECTION 2: Hazards identification

Signal word

Danger

Hazard statements

H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H400, Very toxic to aquatic life. H411, Toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains (1S,5S)-6,6-DIMETHYL-2-METHYLIDENEBICYCLO[3.1.1]HEPTANE, 4-(1- METHYLETHYL)-CYCLOHEXANEMETHANOL, ALPHA-PINENES, BETA-CARYOPHYLLENE, BETA-PINENES, CINNAMYL ALCOHOL, CITRAL, COUMARIN, EUCALYPTOL, EUGENOL, EUGENYL ACETATE, GERANIOL, GERANYL ACETATE, HEXYL CINNAMAL, LINALOOL, LINALYL ACETATE, NEROL, NERYL ACETATE, PHENETHYL SALICYLATE. May produce an allergic reaction.

Precautionary statements

P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331, Do not induce vomiting. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P391, Collect spillage. P405, Store locked up. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

Sensitisers declared on a CLP (1S,5S)-6,6-DIMETHYL-2-METHYLIDENEBICYCLO[3.1.1] Hazard Label: HEPTANE, 4-(1-METHYLETHYL)- CYCLOHEXANEMETHANOL, ALPHA-PINENES, BETA- CARYOPHYLLENE, BETA-PINENES, CINNAMYL ALCOHOL, CITRAL, COUMARIN, EUCALYPTOL, EUGENOL, EUGENYL ACETATE, GERANIOL, GERANYL ACETATE, HEXYL CINNAMAL, LINALOOL, LINALYL ACETATE, NEROL, NERYL ACETATE, PHENETHYL SALICYLATE Hydrocarbon Concentration %: 22.879%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Skin Corrosion / Irritation Category 2 danger: Eye Damage / Irritation Category 2 Sensitization - Skin Category 1 Aspiration Hazard Category 1 Hazardous to the Aquatic Environment - Acute Hazard Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H400, Very toxic to aquatic life. H411, Toxic to aquatic life with long lasting effects. 18 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Danger Hazard statements: H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H400, Very toxic to aquatic life. H411, Toxic to aquatic life with long lasting effects. Supplemental EUH208, Contains (1S,5S)-6,6-DIMETHYL-2-METHYLIDENEBICYCLO[3.1.1]HEPTANE, 4-(1- Information: METHYLETHYL)-CYCLOHEXANEMETHANOL, ALPHA-PINENES, BETA-CARYOPHYLLENE, BETA-PINENES, CINNAMYL ALCOHOL, CITRAL, COUMARIN, EUCALYPTOL, EUGENOL, EUGENYL ACETATE, GERANIOL, GERANYL ACETATE, HEXYL CINNAMAL, LINALOOL, LINALYL ACETATE, NEROL, NERYL ACETATE, PHENETHYL SALICYLATE. May produce an allergic reaction. Precautionary P261, Avoid breathing vapour or dust. statements: P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331, Do not induce vomiting. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P391, Collect spillage. P405, Store locked up. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: 18 2.3 Other hazards Other hazards: Sensitisers declared on a CLP (1S,5S)-6,6-DIMETHYL-2-METHYLIDENEBICYCLO[3.1.1] Hazard Label: HEPTANE, 4-(1-METHYLETHYL)- CYCLOHEXANEMETHANOL, ALPHA-PINENES, BETA- CARYOPHYLLENE, BETA-PINENES, CINNAMYL ALCOHOL, CITRAL, COUMARIN, EUCALYPTOL, EUGENOL, EUGENYL ACETATE, GERANIOL, GERANYL ACETATE, HEXYL CINNAMAL, LINALOOL, LINALYL ACETATE, NEROL, NERYL ACETATE, PHENETHYL SALICYLATE Hydrocarbon Concentration %: 22.879% Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs METHYLCINNAMIC 101-39-3 202-938-8 10-<20% SS 1B-EH A1-EH C2; oral: ATE = 2050 ALDEHYDE H317-H400-H411,- mg/kg bw FL 3-SCI 2-SS 1B-AH LIMONENE 5989-27-5 227-813-5 10-<20% 1-EH A1-EH C3;H226- H304-H315-H317- H400-H412,- EUGENOL 97-53-0 202-589-1 10-<20% EDI 2-SS 1B;H317- oral: ATE = 2500 H319,- mg/kg bw BETA- 87-44-5 201-746-1 5-<10% SS 1B-AH 1;H304- CARYOPHYLLENE H317,- CITRAL 5392-40-5 226-394-6 01-2119462829-23-xxxx 1-<5% SCI 2-EDI 2-SS 1; H315-H317-H319,- SCI 2-EDI 2-SS 1A-EH oral: ATE = 2220 CINNAMAL 104-55-2 203-213-9 1-<5% C3;H315-H317-H319- mg/kg bw H412,- LINALYL ACETATE 115-95-7 204-116-4 01-2119454789-19-xxxx 1-<5% SCI 2-EDI 2-SS 1B; H315-H317-H319,- CINNAMYL ALCOHOL 104-54-1 203-212-3 1-<5% ATO 4-SS 1B-EH C2; oral: ATE = 2000 H302-H317-H411,- mg/kg bw 4-(1-METHYLETHYL)- 5502-75-0, 939-719-8, SCI 2-SS 1B;H315- CYCLOHEXANEMETH 13828-37-0 237-539-8 01-2119983532-32-xxxx 1-<5% H317,- ANOL ATO 4-ATD 4-ATI 4- Skin Sens. 1; H317; C ≥ 0.01%-inhalation: 97-54-1, 202-590-7, SCI 2-EDI 2-SS 1A- ATE = 1.5 mg/l (dusts ISOEUGENOL 5932-68-3, 227-678-2, 0.1-<1% STO-SE 3(RI);H302- or mists)-dermal: ATE 5912-86-7 227-633-7 H312-H315-H317- H319-H332-H335,- = 1912 mg/kg bw-oral: ATE = 1500 mg/kg bw HEXYL CINNAMAL 101-86-0 202-983-3 0.1-<1% SS 1B-EH A1-EH C2; oral: ATE = 3100 H317-H400-H411,- mg/kg bw LINALOOL 78-70-6 201-134-4 01-2119474016-42-xxxx 0.1-<1% SCI 2-EDI 2-SS 1B; oral: ATE = 2790 H315-H317-H319,- mg/kg bw EUGENYL ACETATE 93-28-7 202-235-6 0.1-<1% ATO 4-SS 1B;H302- oral: ATE = 1670 H317,- mg/kg bw PHENETHYL 87-22-9 201-732-5 0.1-<1% SCI 2-SS 1B-EH C2; oral: ATE = 2500 SALICYLATE H315-H317-H411,- mg/kg bw 18 NEROL 106-25-2 203-378-7 0.1-<1% SCI 2-EDI 2-SS 1B; oral: ATE = 4500 H315-H317-H319,- mg/kg bw FL 3-SCI 2-EDI 2-AH MYRCENE 123-35-3 204-622-5 0.1-<1% 1-EH A1-EH C2;H226- H304-H315-H319- H400-H411,- FL 3-ATO 4-SCI 2-SS ALPHA-PINENES 80-56-8 201-291-9 0.1-<1% 1B-AH 1-EH A1-EH oral: ATE = 500 mg/kg C1;H226-H302-H304- bw H315-H317-H410,- COUMARIN 91-64-5 202-086-7 0.1-<1% ATO 4-SS 1B-EH C3; oral: ATE = 500 mg/kg H302-H317-H412,- bw GERANIOL 106-24-1 203-377-1 01-2119552430-49-xxxx 0.1-<1% SCI 2-EDI 1-SS 1; oral: ATE = 3600 H315-H317-H318,- mg/kg bw FL 3-SCI 2-SS 1B-AH BETA-PINENES 127-91-3 204-872-5 0.1-<1% 1-EH A1-EH C1;H226- H304-H315-H317- H410,- EUCALYPTOL 470-82-6 207-431-5 0.1-<1% FL 3-SS 1B;H226- oral: ATE = 2480 H317,- mg/kg bw GERANYL ACETATE 105-87-3 203-341-5 01-2119973480-35-xxxx 0.1-<1% SCI 2-SS 1B-EH C3; H315-H317-H412,- (1S,5S)-6,6-DIMETHYL- FL 3-SCI 2-SS 1B-AH 2- 18172-67-3 242-060-2 0.1-<1% 1-EH A1-EH C1;H226- METHYLIDENEBICYCL H304-H315-H317- O[3.1.1]HEPTANE H410,- NERYL ACETATE 141-12-8 205-459-2 0.1-<1% SS 1B;H317,- Substances with Community workplace exposure limits: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs DIETHYL PHTHALATE 84-66-2 201-550-6 01-2119486682-27-xxxx 20-<50% -;-,- Substances that are endocrine disruptors according to Regulation (EU) 2017/2100 or Regulation (EU) 2018/605, greater than 0.1%: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin exposure: IF ON SKIN: Wash with plenty of soap and water. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. 4.2 Most important symptoms and effects, both acute and delayed May be fatal if swallowed and enters airways. 18