NENUKO FRAGRANCE

Hazard statements (CLP)

H304, H315, H317, H319, H411

Code

Statements

H304

May be fatal if swallowed and enters airways

SECTION 2: Hazards identification

Signal word

Danger

Hazard statements

H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains ALPHA-PINENES, BETA-CARYOPHYLLENE, CITRAL, DL-LIMONENE, GERANIOL, ISOEUGENOL, NERAL. May produce an allergic reaction.

Precautionary statements

P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331, Do not induce vomiting. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P391, Collect spillage. P405, Store locked up. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

Sensitisers declared on a CLP ALPHA-PINENES, BETA-CARYOPHYLLENE, CITRAL, DL- Hazard Label: LIMONENE, GERANIOL, ISOEUGENOL, NERAL Hydrocarbon Concentration %: 13.454%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Skin Corrosion / Irritation Category 2 danger: Eye Damage / Irritation Category 2 Sensitization - Skin Category 1 Aspiration Hazard Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects. 17 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Danger Hazard statements: H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects. Supplemental EUH208, Contains ALPHA-PINENES, BETA-CARYOPHYLLENE, CITRAL, DL-LIMONENE, Information: GERANIOL, ISOEUGENOL, NERAL. May produce an allergic reaction. Precautionary P261, Avoid breathing vapour or dust. statements: P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331, Do not induce vomiting. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P391, Collect spillage. P405, Store locked up. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: 2.3 Other hazards Other hazards: Sensitisers declared on a CLP ALPHA-PINENES, BETA-CARYOPHYLLENE, CITRAL, DL- Hazard Label: LIMONENE, GERANIOL, ISOEUGENOL, NERAL Hydrocarbon Concentration %: 13.454% 17 Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs FL 3-SCI 2-SS 1B-AH LIMONENE 5989-27-5 227-813-5 10-<20% 1-EH A1-EH C3;H226- H304-H315-H317- H400-H412,- LINALOOL 78-70-6 201-134-4 01-2119474016-42-xxxx 10-<20% SCI 2-EDI 2-SS 1B; oral: ATE = 2790 H315-H317-H319,- mg/kg bw LINALYL ACETATE 115-95-7 204-116-4 01-2119454789-19-xxxx 10-<20% SCI 2-EDI 2-SS 1B; H315-H317-H319,- ETHYL BETA- 93-18-5 202-226-7 5-<10% EDI 2-EH C2;H319- oral: ATE = 3110 NAPHTHYL ETHER H411,- mg/kg bw 1,3,4,6,7,8- HEXAHYDRO- 4,6,6,7,8,8- 1222-05-5 214-946-9 01-2119488227-29-xxxx 5-<10% EH A1-EH C1;H410,- HEXAMETHYLINDENO [5,6-C]PYRAN GERANIAL 141-27-5 205-476-5 1-<5% SCI 2-EDI 2-SS 1B; H315-H317-H319,- NERAL 106-26-3 203-379-2 1-<5% SCI 2-EDI 2-SS 1B; H315-H317-H319,- 2,6-DIMETHYL-7- SCI 2-EDI 2-STO-SE 3 oral: ATE = 3020 OCTEN-2-OL 18479-58-8 242-362-4 1-<5% (NE);H315-H319-H336, mg/kg bw - OXACYCLOHEXADEC 34902-57-3, 422-320-3 01-0000016883-62-xxxx 1-<5% EH A1-EH C1;H410,- EN-2-ONE 111879-80-2 2-ACETONAPHTHONE 93-08-3 202-216-2 1-<5% SCI 2-EDI 2-EH C2; oral: ATE = 3100 H315-H319-H411,- mg/kg bw TETRAHYDRO- METHYL- 63500-71-0 405-040-6 01-0000015458-64-xxxx 1-<5% EDI 2;H319,- (METHYLPROPYL)- PYRAN-4-OL METHYL 134-20-3 205-132-4 1-<5% EDI 2;H319,- oral: ATE = 2780 ANTHRANILATE mg/kg bw FL 3-SCI 2-SS 1B-AH DL-LIMONENE 138-86-3, 205-341-0, 0.1-<1% 1-EH A1-EH C3;H226- 7705-14-8 231-732-0 H304-H315-H317- H400-H412,- FL 3-SCI 2-EDI 2-AH MYRCENE 123-35-3 204-622-5 0.1-<1% 1-EH A1-EH C2;H226- H304-H315-H319- H400-H411,- CITRAL 5392-40-5 226-394-6 01-2119462829-23-xxxx 0.1-<1% SCI 2-EDI 2-SS 1; H315-H317-H319,- GERANIOL 106-24-1 203-377-1 01-2119552430-49-xxxx 0.1-<1% SCI 2-EDI 1-SS 1; oral: ATE = 3600 H315-H317-H318,- mg/kg bw FL 3-ATO 4-SCI 2-SS ALPHA-PINENES 80-56-8 201-291-9 0.1-<1% 1B-AH 1-EH A1-EH oral: ATE = 500 mg/kg C1;H226-H302-H304- bw H315-H317-H410,- BETA- 87-44-5 201-746-1 0.1-<1% SS 1B-AH 1;H304- CARYOPHYLLENE H317,- 17 ATO 4-ATD 4-ATI 4- Skin Sens. 1; H317; C ≥ 0.01%-inhalation: 97-54-1, 202-590-7, SCI 2-EDI 2-SS 1A- ATE = 1.5 mg/l (dusts ISOEUGENOL 5932-68-3, 227-678-2, <0.1% STO-SE 3(RI);H302- or mists)-dermal: ATE 5912-86-7 227-633-7 H312-H315-H317- H319-H332-H335,- = 1912 mg/kg bw-oral: ATE = 1500 mg/kg bw Substances with Community workplace exposure limits: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs DIETHYL PHTHALATE 84-66-2 201-550-6 01-2119486682-27-xxxx 20-<50% -;-,- Substances that are endocrine disruptors according to Regulation (EU) 2017/2100 or Regulation (EU) 2018/605, greater than 0.1%: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin exposure: IF ON SKIN: Wash with plenty of soap and water. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. 4.2 Most important symptoms and effects, both acute and delayed May be fatal if swallowed and enters airways. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. Section 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 17 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation Do not eat, drink or smoke when using this product. 7.2 Conditions for safe storage, including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s): Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: 17 Ingredient CAS EC Description Value UK Long-term exposure limit (8-hour TWA) 5 mg/m³