MULBERRY FRAGRANCE

Hazard statements (CLP)

H317, H411

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

Signal word

Warning

Hazard statements

H317, May cause an allergic skin reaction. H411, Toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains 5-METHYL-2-PHENYL-2-HEXENAL, ALLYL CYCLOHEXYLPROPIONATE, ALPHA-ISOMETHYL IONONE, CITRONELLOL, HEXYL CINNAMAL, LIMONENE, LINALOOL, METHYL CINNAMATE, P-ANISYL ACETATE. May produce an allergic reaction.

Precautionary statements

P261, Avoid breathing vapour or dust. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

Sensitisers declared on a CLP 5-METHYL-2-PHENYL-2-HEXENAL, ALLYL Hazard Label: CYCLOHEXYLPROPIONATE, ALPHA-ISOMETHYL IONONE, CITRONELLOL, HEXYL CINNAMAL, LIMONENE, LINALOOL, METHYL CINNAMATE, P-ANISYL ACETATE Hydrocarbon Concentration %: 0.000%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Sensitization - Skin Category 1 danger: Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H317, May cause an allergic skin reaction. H411, Toxic to aquatic life with long lasting effects. 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Warning Hazard statements: H317, May cause an allergic skin reaction. H411, Toxic to aquatic life with long lasting effects. 28 Supplemental EUH208, Contains 5-METHYL-2-PHENYL-2-HEXENAL, ALLYL CYCLOHEXYLPROPIONATE, Information: ALPHA-ISOMETHYL IONONE, CITRONELLOL, HEXYL CINNAMAL, LIMONENE, LINALOOL, METHYL CINNAMATE, P-ANISYL ACETATE. May produce an allergic reaction. Precautionary P261, Avoid breathing vapour or dust. statements: P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: 2.3 Other hazards Other hazards: Sensitisers declared on a CLP 5-METHYL-2-PHENYL-2-HEXENAL, ALLYL Hazard Label: CYCLOHEXYLPROPIONATE, ALPHA-ISOMETHYL IONONE, CITRONELLOL, HEXYL CINNAMAL, LIMONENE, LINALOOL, METHYL CINNAMATE, P-ANISYL ACETATE Hydrocarbon Concentration %: 0.000% Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs dermal: ATE = 2600 VANILLIN 121-33-5 204-465-2 5-<10% EDI 2;H319,- mg/kg bw-oral: ATE = 3300 mg/kg bw HELIOTROPINE 120-57-0 204-409-7 1-<5% SS 1B;H317,- oral: ATE = 2700 mg/kg bw 259-174-3, 54464-57-2, TETRAMETHYL 54464-59-4, 259-175-9, SCI 2-SS 1B-EH C1; ACETYLOCTAHYDRON 68155-66-8, 268-978-3, 01-2119489989-04-xxxx 1-<5% H315-H317-H410,- APHTHALENES 268-979-9, 68155-67-9 915-730-3 28 DIMETHYL-4- SCI 2-EH C3;H315- ISOHEPTENAL 67674-46-8 266-885-2 01-2120741268-52-xxxx 1-<5% H412,- DIMETHYL ACETAL METHYLPENTENYL- SCI 2-EH C2;H315- CYCLOHEXENE-1- 72403-67-9 276-650-6 1-<5% H411,- METHYL-ACETATE CIS-2-TERT- oral: ATE = 4600 BUTYLCYCLOHEXYL 20298-69-5 243-718-1 01-2119970713-33-xxxx 1-<5% EH C2;H411,- mg/kg bw ACETATE ETHYL 4940-11-8 225-582-5 1-<5% ATO 4;H302,- oral: ATE = 1200 HYDROXYPYRONE mg/kg bw inhalation: ATE = 1.5 ATO 4-ATI 4-EDI 2- mg/l (dusts or mists)- BENZALDEHYDE 100-52-7 202-860-4 01-2119455540-44-xxxx 1-<5% STO-SE 3(RI);H302- dermal: ATE = 2500 H319-H332-H335,- mg/kg bw-oral: ATE = 1430 mg/kg bw ALLYL ATO 4-ATD 4-SS 1-EH dermal: ATE = 1600 CYCLOHEXYLPROPIO 2705-87-5 220-292-5 01-2119976355-27-xxxx 0.1-<1% A1-EH C2;H302-H312- mg/kg bw-oral: ATE = NATE H317-H400-H411,- 380 mg/kg bw P-ANISYL ACETATE 104-21-2 203-185-8 0.1-<1% SS 1B;H317,- ATO 4-SCI 2-SS 1A- oral: ATE = 1400 DELTA-DAMASCONE 57378-68-4 260-709-8 0.1-<1% EH A1-EH C1;H302- mg/kg bw H315-H317-H410,- HEXYL CINNAMAL 101-86-0 202-983-3 0.1-<1% SS 1B-EH A1-EH C2; oral: ATE = 3100 H317-H400-H411,- mg/kg bw LINALOOL 78-70-6 201-134-4 01-2119474016-42-xxxx 0.1-<1% SCI 2-EDI 2-SS 1B; oral: ATE = 2790 H315-H317-H319,- mg/kg bw FL 3-SCI 2-SS 1B-AH LIMONENE 5989-27-5 227-813-5 0.1-<1% 1-EH A1-EH C3;H226- H304-H315-H317- H400-H412,- 5-METHYL-2-PHENYL- 21834-92-4 244-602-3 0.1-<1% SS 1B;H317,- 2-HEXENAL REACTION MASS OF inhalation: ATE = 0.46 ALLYL (2- METHYLBUTOXY) 67634-00-8, 266-803-5, ATO 4-ATD 4-ATI 2-EH mg/l (dusts or mists)- ACETATE & ALLYL (3- 67634-01-9 266-804-0, 0.1-<1% A1;H302-H312-H330- dermal: ATE = 1100 916-328-0 H400,- METHOXYBUTOXY) mg/kg bw-oral: ATE = 500 mg/kg bw ACETATE 106-22-9, 203-375-0, 1117-61-9, 214-250-5, 26489-01-0, 247-737-6, SCI 2-EDI 2-SS 1B; dermal: ATE = 2650 CITRONELLOL 6812-78-8, 229-887-4, 01-2119453995-23-xxxx 0.1-<1% H315-H317-H319,- mg/kg bw-oral: ATE = 3450 mg/kg bw 141-25-3, 205-473-9, 7540-51-4 231-415-7 ALPHA-ISOMETHYL 127-51-5 204-846-3 0.1-<1% SS 1B-EH C2;H317- IONONE H411,- METHYL CINNAMATE 103-26-4 203-093-8 0.1-<1% SS 1B;H317,- oral: ATE = 2610 mg/kg bw Substances with Community workplace exposure limits: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs DIETHYL PHTHALATE 84-66-2 201-550-6 01-2119486682-27-xxxx 50-100% -;-,- ISOBUTYL ACETATE 110-19-0 203-745-1 0.1-<1% FL 2-STO-SE 3(NE); H225-H336,EUH066 28 Substances that are endocrine disruptors according to Regulation (EU) 2017/2100 or Regulation (EU) 2018/605, greater than 0.1%: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: Flush immediately with water for at least 15 minutes. Contact physician if symptoms persist. Skin exposure: IF ON SKIN: Wash with plenty of soap and water. Ingestion: Rinse mouth with water and obtain medical attention. 4.2 Most important symptoms and effects, both acute and delayed May cause an allergic skin reaction. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. Section 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 28 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation Do not eat, drink or smoke when using this product.