MADAME FRAGRANCE

Hazard statements (CLP)

H317, H411

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

Signal word

Warning

Hazard statements

H317, May cause an allergic skin reaction. H411, Toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains (E)-1-(2,6,6-TRIMETHYL-1,3-CYCLOHEXADIEN-1-YL)-2-BUTEN-1-ONE, 3-(2H-1,3-BENZODIOXOL-5-YL)-2-METHYLPROPANAL, BENZYL SALICYLATE, BETA- CARYOPHYLLENE, BETA-PINENES, CITRONELLOL, COUMARIN, CYCLAMEN ALDEHYDE, GERANIOL, GERANYL ACETATE, HYDROXYCITRONELLAL, LINALYL ACETATE, NEROL, PENTADECALACTONE, TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENES. May produce an allergic reaction.

Precautionary statements

P261, Avoid breathing vapour or dust. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

Sensitisers declared on a CLP (E)-1-(2,6,6-TRIMETHYL-1,3-CYCLOHEXADIEN-1-YL)-2- Hazard Label: BUTEN-1-ONE, 3-(2H-1,3-BENZODIOXOL-5-YL)-2- METHYLPROPANAL, BENZYL SALICYLATE, BETA- CARYOPHYLLENE, BETA-PINENES, CITRONELLOL, COUMARIN, CYCLAMEN ALDEHYDE, GERANIOL, GERANYL ACETATE, HYDROXYCITRONELLAL, LINALYL ACETATE, NEROL, PENTADECALACTONE, TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENES Hydrocarbon Concentration %: 3.355%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Sensitization - Skin Category 1 danger: Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H317, May cause an allergic skin reaction. H411, Toxic to aquatic life with long lasting effects. 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Warning Hazard statements: H317, May cause an allergic skin reaction. H411, Toxic to aquatic life with long lasting effects. 32 Supplemental EUH208, Contains (E)-1-(2,6,6-TRIMETHYL-1,3-CYCLOHEXADIEN-1-YL)-2-BUTEN-1-ONE, Information: 3-(2H-1,3-BENZODIOXOL-5-YL)-2-METHYLPROPANAL, BENZYL SALICYLATE, BETA- CARYOPHYLLENE, BETA-PINENES, CITRONELLOL, COUMARIN, CYCLAMEN ALDEHYDE, GERANIOL, GERANYL ACETATE, HYDROXYCITRONELLAL, LINALYL ACETATE, NEROL, PENTADECALACTONE, TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENES. May produce an allergic reaction. Precautionary P261, Avoid breathing vapour or dust. statements: P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: 2.3 Other hazards Other hazards: Sensitisers declared on a CLP (E)-1-(2,6,6-TRIMETHYL-1,3-CYCLOHEXADIEN-1-YL)-2- Hazard Label: BUTEN-1-ONE, 3-(2H-1,3-BENZODIOXOL-5-YL)-2- METHYLPROPANAL, BENZYL SALICYLATE, BETA- CARYOPHYLLENE, BETA-PINENES, CITRONELLOL, COUMARIN, CYCLAMEN ALDEHYDE, GERANIOL, GERANYL ACETATE, HYDROXYCITRONELLAL, LINALYL ACETATE, NEROL, PENTADECALACTONE, TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENES Hydrocarbon Concentration %: 3.355% Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs HEXYL CINNAMAL 101-86-0 202-983-3 1-<5% SS 1B-EH A1-EH C2; oral: ATE = 3100 H317-H400-H411,- mg/kg bw 32 TETRAHYDRO- METHYL- 63500-71-0 405-040-6 01-0000015458-64-xxxx 1-<5% EDI 2;H319,- (METHYLPROPYL)- PYRAN-4-OL LINALOOL 78-70-6 201-134-4 01-2119474016-42-xxxx 1-<5% SCI 2-EDI 2-SS 1B; oral: ATE = 2790 H315-H317-H319,- mg/kg bw 1,3,4,6,7,8- HEXAHYDRO- 4,6,6,7,8,8- 1222-05-5 214-946-9 01-2119488227-29-xxxx 1-<5% EH A1-EH C1;H410,- HEXAMETHYLINDENO [5,6-C]PYRAN FL 3-SCI 2-SS 1B-AH LIMONENE 5989-27-5 227-813-5 1-<5% 1-EH A1-EH C3;H226- H304-H315-H317- H400-H412,- ETHYL LINALOOL 10339-55-6 233-732-6 01-2119969272-32-xxxx 1-<5% SCI 2-EDI 2-SS 1B; oral: ATE = 5000 H315-H317-H319,- mg/kg bw 259-174-3, 54464-57-2, TETRAMETHYL 54464-59-4, 259-175-9, SCI 2-SS 1B-EH C1; ACETYLOCTAHYDRON 68155-66-8, 268-978-3, 01-2119489989-04-xxxx 1-<5% H315-H317-H410,- APHTHALENES 268-979-9, 68155-67-9 915-730-3 OCTAHYDRO- TETRAMETHYL- 5986-55-0 227-807-2 1-<5% EH C2;H411,- METHANO-1- NAPHTHOL 3-(2H-1,3- SS 1B-REP 2-EH C2; oral: ATE = 3562 BENZODIOXOL-5-YL) 1205-17-0 214-881-6 01-2120740119-58-xxxx 0.1-<1% H317-H361-H411,- mg/kg bw -2-METHYLPROPANAL CIS-3-HEXENYL 65405-77-8 265-745-8 01-2119987320-37-xxxx 0.1-<1% REP 2-EH A1-EH C2; oral: ATE = 2500 SALICYLATE H361-H400-H411,- mg/kg bw BENZYL SALICYLATE 118-58-1 204-262-9 0.1-<1% SS 1B-EH C3;H317- oral: ATE = 2200 H412,- mg/kg bw PENTADECALACTONE 106-02-5 203-354-6 01-2119987323-31-xxxx 0.1-<1% SS 1B-EH C2;H317- H411,- 106-22-9, 203-375-0, 1117-61-9, 214-250-5, 26489-01-0, 247-737-6, SCI 2-EDI 2-SS 1B; dermal: ATE = 2650 CITRONELLOL 6812-78-8, 229-887-4, 01-2119453995-23-xxxx 0.1-<1% H315-H317-H319,- mg/kg bw-oral: ATE = 3450 mg/kg bw 141-25-3, 205-473-9, 7540-51-4 231-415-7 GERANYL ACETATE 105-87-3 203-341-5 01-2119973480-35-xxxx 0.1-<1% SCI 2-SS 1B-EH C3; H315-H317-H412,- LINALYL ACETATE 115-95-7 204-116-4 01-2119454789-19-xxxx 0.1-<1% SCI 2-EDI 2-SS 1B; H315-H317-H319,- GERANIOL 106-24-1 203-377-1 01-2119552430-49-xxxx 0.1-<1% SCI 2-EDI 1-SS 1; oral: ATE = 3600 H315-H317-H318,- mg/kg bw COUMARIN 91-64-5 202-086-7 0.1-<1% ATO 4-SS 1B-EH C3; oral: ATE = 500 mg/kg H302-H317-H412,- bw HYDROXYCITRONELL 107-75-5 203-518-7 0.1-<1% EDI 2-SS 1B;H317- AL H319,- NEROL 106-25-2 203-378-7 0.1-<1% SCI 2-EDI 2-SS 1B; oral: ATE = 4500 H315-H317-H319,- mg/kg bw FL 3-SCI 2-SS 1B-AH BETA-PINENES 127-91-3 204-872-5 0.1-<1% 1-EH A1-EH C1;H226- H304-H315-H317- H410,- BETA- 87-44-5 201-746-1 0.1-<1% SS 1B-AH 1;H304- CARYOPHYLLENE H317,- CYCLAMEN 103-95-7 203-161-7 01-2119970582-32-xxxx 0.1-<1% SCI 2-SS 1B-EH C3; oral: ATE = 3810 ALDEHYDE H315-H317-H412,- mg/kg bw FL 3-REP 2-AH 1-EH oral: ATE = 3650 GAMMA-TERPINENE 99-85-4 202-794-6 0.1-<1% C2;H226-H304-H361- mg/kg bw H411,- 32 (E)-1-(2,6,6- TRIMETHYL-1,3- 23726-93-4 245-844-2 01-2120105798-49-xxxx 0.1-<1% SCI 2-SS 1A-EH C2; dermal: ATE = 2900 CYCLOHEXADIEN-1- H315-H317-H411,- mg/kg bw YL)-2-BUTEN-1-ONE Substances with Community workplace exposure limits: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs DIETHYL PHTHALATE 84-66-2 201-550-6 01-2119486682-27-xxxx 50-100% -;-,- Substances that are endocrine disruptors according to Regulation (EU) 2017/2100 or Regulation (EU) 2018/605, greater than 0.1%: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: Flush immediately with water for at least 15 minutes. Contact physician if symptoms persist. Skin exposure: IF ON SKIN: Wash with plenty of soap and water. Ingestion