LYCHEE PEONY FRAGRANCE

Hazard statements (CLP)

H226, H317, H319, H412

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Signal word

Warning

Hazard statements

H226, Flammable liquid and vapour. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H412, Harmful to aquatic life with long lasting effects.

Additional information

EUH208, Contains CIS-3-HEXENYL METHYL CARBONATE, CITRONELLOL, DIMETHYL HEPTENAL, DIMETHYLBUTYL CROTONATE, GERANIOL. May produce an allergic reaction.

Precautionary statements

P210, Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P233, Keep container tightly closed. P240, Ground/bond container and receiving equipment. P241, Use explosion-proof electrical, ventilating and lighting equipment. P242, Use only non-sparking tools. P243, Take precautionary measures against static discharge. P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P370/378, In case of fire: Use carbon dioxide, dry chemical, foam for extinction. P403/235, Store in a well-ventilated place. Keep cool. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

Sensitisers declared on a CLP CIS-3-HEXENYL METHYL CARBONATE, CITRONELLOL, Hazard Label: DIMETHYL HEPTENAL, DIMETHYLBUTYL CROTONATE, GERANIOL Hydrocarbon Concentration %: 0.000%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Flammable Liquid, Hazard Category 3 danger: Eye Damage / Irritation Category 2 Sensitization - Skin Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 3 H226, Flammable liquid and vapour. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H412, Harmful to aquatic life with long lasting effects. 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Warning 23 Hazard statements: H226, Flammable liquid and vapour. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H412, Harmful to aquatic life with long lasting effects. Supplemental EUH208, Contains CIS-3-HEXENYL METHYL CARBONATE, CITRONELLOL, DIMETHYL Information: HEPTENAL, DIMETHYLBUTYL CROTONATE, GERANIOL. May produce an allergic reaction. Precautionary P210, Keep away from heat, sparks, open flames and hot surfaces. - No smoking. statements: P233, Keep container tightly closed. P240, Ground/bond container and receiving equipment. P241, Use explosion-proof electrical, ventilating and lighting equipment. P242, Use only non-sparking tools. P243, Take precautionary measures against static discharge. P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P370/378, In case of fire: Use carbon dioxide, dry chemical, foam for extinction. P403/235, Store in a well-ventilated place. Keep cool. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: 2.3 Other hazards Other hazards: Sensitisers declared on a CLP CIS-3-HEXENYL METHYL CARBONATE, CITRONELLOL, Hazard Label: DIMETHYL HEPTENAL, DIMETHYLBUTYL CROTONATE, GERANIOL Hydrocarbon Concentration %: 0.000% 23 Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs CIS-2-TERT- oral: ATE = 4600 BUTYLCYCLOHEXYL 20298-69-5 243-718-1 01-2119970713-33-xxxx 5-<10% EH C2;H411,- mg/kg bw ACETATE (1R)-NOPYL ACETATE 35836-72-7 800-940-9 1-<5% EDI 2-SS 1B-EH C2; oral: ATE = 2940 H317-H319-H411,- mg/kg bw 4-TERT- oral: ATE = 3370 BUTYLCYCLOHEXYL 32210-23-4 250-954-9 01-2119976286-24-xxxx 1-<5% SS 1B;H317,- mg/kg bw ACETATE ISOBUTYL ACETATE 110-19-0 203-745-1 1-<5% FL 2-STO-SE 3(NE); H225-H336,EUH066 HEXYL CINNAMAL 101-86-0 202-983-3 1-<5% SS 1B-EH A1-EH C2; oral: ATE = 3100 H317-H400-H411,- mg/kg bw BENZYL ACETATE 140-11-4 205-399-7 1-<5% EH C3;H412,- oral: ATE = 2490 mg/kg bw LINALOOL 78-70-6 201-134-4 01-2119474016-42-xxxx 1-<5% SCI 2-EDI 2-SS 1B; oral: ATE = 2790 H315-H317-H319,- mg/kg bw FL 2-EDI 2-STO-SE 3 ETHYL ACETATE 141-78-6 205-500-4 1-<5% (NE);H225-H319-H336, EUH066 ETHYL OCTANOATE 106-32-1 203-385-5 1-<5% EH C2;H411,- GERANIOL 106-24-1 203-377-1 01-2119552430-49-xxxx 0.1-<1% SCI 2-EDI 1-SS 1; oral: ATE = 3600 H315-H317-H318,- mg/kg bw inhalation: ATE = 3 ATO 3-ATD 3-ATI 3-EH A1-EH C3;H301-H311- mg/l (vapour)-dermal: ALLYL CAPROATE 123-68-2 204-642-4 0.1-<1% H331-H400-H412,- ATE = 300 mg/kg bw- oral: ATE = 300 mg/kg bw 4-METHYL-3-DECEN-5- 81782-77-6 279-815-0 01-2119983528-21-xxxx 0.1-<1% EH A1-EH C2;H400- OL H411,- 106-22-9, 203-375-0, 1117-61-9, 214-250-5, 26489-01-0, 247-737-6, SCI 2-EDI 2-SS 1B; dermal: ATE = 2650 CITRONELLOL 6812-78-8, 229-887-4, 01-2119453995-23-xxxx 0.1-<1% H315-H317-H319,- mg/kg bw-oral: ATE = 3450 mg/kg bw 141-25-3, 205-473-9, 7540-51-4 231-415-7 DIMETHYLBUTYL 35206-51-0 252-438-9 01-2120739616-47-xxxx 0.1-<1% SCI 2-SS 1B;H315- CROTONATE H317,- CIS-3-HEXENYL 67633-96-9 266-797-4 01-2120735800-60-xxxx 0.1-<1% SCI 2-SS 1B;H315- METHYL CARBONATE H317,- DIMETHYL HEPTENAL 106-72-9 203-427-2 0.1-<1% SS 1B;H317,- Substances with Community workplace exposure limits: 23 Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs DIETHYL PHTHALATE 84-66-2 201-550-6 01-2119486682-27-xxxx 20-<50% -;-,- FL 2-EDI 2-STO-SE 3 ETHYL ACETATE 141-78-6 205-500-4 1-<5% (NE);H225-H319-H336, EUH066 ISOBUTYL ACETATE 110-19-0 203-745-1 1-<5% FL 2-STO-SE 3(NE); H225-H336,EUH066 Substances that are endocrine disruptors according to Regulation (EU) 2017/2100 or Regulation (EU) 2018/605, greater than 0.1%: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin exposure: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. Ingestion: Rinse mouth with water and obtain medical attention. 4.2 Most important symptoms and effects, both acute and delayed May cause an allergic skin reaction. Causes serious eye irritation. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. Section 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. 23 Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. 7.2 Conditions for safe storage, including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s): Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: 23 Ingredient CAS EC Description Value UK Long-term exposure limit (8-hour TWA) 5 mg/m³ (mg/m3) DIETHYL PHTHALATE 84-66-2