LILY OF THE VALLEY

Hazard statements (CLP)

H317, H319, H412

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

Signal word

Warning

Hazard statements

H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H412, Harmful to aquatic life with long lasting effects.

Additional information

EUH208, Contains 2,4-DIMETHYL-3-CYCLOHEXENE CARBOXALDEHYDE, 3,4,5,6,6- PENTAMETHYLHEPT-3-EN-2-ONE (AND ISOMERS), 4-(1-METHYLETHYL)- CYCLOHEXANEMETHANOL, 4-TERT-BUTYLCYCLOHEXYL ACETATE, 4-TERT- BUTYLDIHYDROCINNAMALDEHYDE, ALPHA-ISOMETHYL IONONE, CITRONELLOL, CYCLAMEN ALDEHYDE, EUCALYPTOL, EUGENOL, HELIOTROPINE, LINALYL ACETATE, METHYL 2-OCTYNOATE, NEROL, TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENES. May produce an allergic reaction.

Precautionary statements

P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

Sensitisers declared on a CLP 2,4-DIMETHYL-3-CYCLOHEXENE CARBOXALDEHYDE, Hazard Label: 3,4,5,6,6-PENTAMETHYLHEPT-3-EN-2-ONE (AND ISOMERS), 4-(1-METHYLETHYL)- CYCLOHEXANEMETHANOL, 4-TERT- BUTYLCYCLOHEXYL ACETATE, 4-TERT- BUTYLDIHYDROCINNAMALDEHYDE, ALPHA-ISOMETHYL IONONE, CITRONELLOL, CYCLAMEN ALDEHYDE, EUCALYPTOL, EUGENOL, HELIOTROPINE, LINALYL ACETATE, METHYL 2-OCTYNOATE, NEROL, TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENES Hydrocarbon Concentration %: 0.000%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Eye Damage / Irritation Category 2 danger: Sensitization - Skin Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 3 H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H412, Harmful to aquatic life with long lasting effects. 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Warning Hazard statements: H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. 65 H412, Harmful to aquatic life with long lasting effects. Supplemental EUH208, Contains 2,4-DIMETHYL-3-CYCLOHEXENE CARBOXALDEHYDE, 3,4,5,6,6- Information: PENTAMETHYLHEPT-3-EN-2-ONE (AND ISOMERS), 4-(1-METHYLETHYL)- CYCLOHEXANEMETHANOL, 4-TERT-BUTYLCYCLOHEXYL ACETATE, 4-TERT- BUTYLDIHYDROCINNAMALDEHYDE, ALPHA-ISOMETHYL IONONE, CITRONELLOL, CYCLAMEN ALDEHYDE, EUCALYPTOL, EUGENOL, HELIOTROPINE, LINALYL ACETATE, METHYL 2-OCTYNOATE, NEROL, TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENES. May produce an allergic reaction. Precautionary P261, Avoid breathing vapour or dust. statements: P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: 2.3 Other hazards Other hazards: Sensitisers declared on a CLP 2,4-DIMETHYL-3-CYCLOHEXENE CARBOXALDEHYDE, Hazard Label: 3,4,5,6,6-PENTAMETHYLHEPT-3-EN-2-ONE (AND ISOMERS), 4-(1-METHYLETHYL)- CYCLOHEXANEMETHANOL, 4-TERT- BUTYLCYCLOHEXYL ACETATE, 4-TERT- BUTYLDIHYDROCINNAMALDEHYDE, ALPHA-ISOMETHYL IONONE, CITRONELLOL, CYCLAMEN ALDEHYDE, EUCALYPTOL, EUGENOL, HELIOTROPINE, LINALYL ACETATE, METHYL 2-OCTYNOATE, NEROL, TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENES Hydrocarbon Concentration %: 0.000% 65 Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs PHENETHYL ATO 4-EDI 2;H302- dermal: ATE = 2500 ALCOHOL 60-12-8 200-456-2 01-2119963921-31-xxxx 5-<10% H319,- mg/kg bw-oral: ATE = 1610 mg/kg bw LINALOOL 78-70-6 201-134-4 01-2119474016-42-xxxx 1-<5% SCI 2-EDI 2-SS 1B; oral: ATE = 2790 H315-H317-H319,- mg/kg bw 3-(O&P- SCI 2-SS 1B-EH A1- ETHYLPHENYL)-2,2- 67634-14-4, 266-818-7, 01-2120758796-34-xxxx 1-<5% EH C2;H315-H317- DIMETHYLPROPIONAL 67634-15-5 266-819-2 H400-H411,- DEHYDE (E)-4-(2,6,6- TRIMETHYL-1- 79-77-6 201-224-3 1-<5% EH C2;H411,- oral: ATE = 3940 CYCLOHEXEN-1-YL)-3- mg/kg bw BUTEN-2-ONE 2-T- EDI 2-EH C2;H319- BUTYLCYCLOHEXYLO 139504-68-0 412-300-2 1-<5% H411,- XYBUTANOL 106-22-9, 203-375-0, 1117-61-9, 214-250-5, 26489-01-0, 247-737-6, SCI 2-EDI 2-SS 1B; dermal: ATE = 2650 CITRONELLOL 6812-78-8, 229-887-4, 01-2119453995-23-xxxx 0.1-<1% H315-H317-H319,- mg/kg bw-oral: ATE = 3450 mg/kg bw 141-25-3, 205-473-9, 7540-51-4 231-415-7 CYCLAMEN 103-95-7 203-161-7 01-2119970582-32-xxxx 0.1-<1% SCI 2-SS 1B-EH C3; oral: ATE = 3810 ALDEHYDE H315-H317-H412,- mg/kg bw 2,4-DIMETHYL-3- SCI 2-SS 1B-EH C2; oral: ATE = 2330 CYCLOHEXENE 68039-49-6 268-264-1 0.1-<1% H315-H317-H411,- mg/kg bw CARBOXALDEHYDE 4-(1-METHYLETHYL)- 5502-75-0, 939-719-8, SCI 2-SS 1B;H315- CYCLOHEXANEMETH 13828-37-0 237-539-8 01-2119983532-32-xxxx 0.1-<1% H317,- ANOL 259-174-3, 54464-57-2, TETRAMETHYL 54464-59-4, 259-175-9, SCI 2-SS 1B-EH C1; ACETYLOCTAHYDRON 68155-66-8, 268-978-3, 01-2119489989-04-xxxx 0.1-<1% H315-H317-H410,- APHTHALENES 268-979-9, 68155-67-9 915-730-3 4-TERT- oral: ATE = 3370 BUTYLCYCLOHEXYL 32210-23-4 250-954-9 01-2119976286-24-xxxx 0.1-<1% SS 1B;H317,- mg/kg bw ACETATE EUGENOL 97-53-0 202-589-1 0.1-<1% EDI 2-SS 1B;H317- oral: ATE = 2500 H319,- mg/kg bw ALPHA-ISOMETHYL 127-51-5 204-846-3 0.1-<1% SS 1B-EH C2;H317- IONONE H411,- LINALYL ACETATE 115-95-7 204-116-4 01-2119454789-19-xxxx 0.1-<1% SCI 2-EDI 2-SS 1B; H315-H317-H319,- HELIOTROPINE 120-57-0 204-409-7 0.1-<1% SS 1B;H317,- oral: ATE = 2700 mg/kg bw NEROL 106-25-2 203-378-7 0.1-<1% SCI 2-EDI 2-SS 1B; oral: ATE = 4500 H315-H317-H319,- mg/kg bw EUCALYPTOL 470-82-6 207-431-5 0.1-<1% FL 3-SS 1B;H226- oral: ATE = 2480 H317,- mg/kg bw ALLYL ATO 4-EH A1-EH C1; oral: ATE = 682 mg/kg CYCLOHEXYLOXYACE 68901-15-5 272-657-3 0.1-<1% H302-H410,- bw TATE 65 279-822-9, 3,4,5,6,6- 81786-73-4, PENTAMETHYLHEPT- 81786-74-5, 279-823-4, SS 1B-EH C2;H317- oral: ATE = 2500 3-EN-2-ONE (AND 81786-75-6, 279-825-5, 0.1-<1% H411,- mg/kg bw 289-194-8, ISOMERS) 86115-11-9 939-627-8 4-TERT- SCI 2-SS 1B-STO-RE oral: ATE = 2500 BUTYLDIHYDROCINNA 18127-01-0 242-016-2 01-2119983533-30-xxxx 0.1-<1% 2-EH C3;H315-H317- mg/kg bw MALDEHYDE H373-H412,- BENZYL BENZOATE 120-51-4 204-402-9 0.1-<1% ATO 4-EH A1-EH C2; oral: ATE = 1160 H302-H400-H411,- mg/kg bw METHYL 28940-11-6 249-320-4 0.1-<1% SCI 1B-EDI 1-STO-SE BENZODIOXEPINONE 3(NE);H314-H336,- PHENYLETHYL 103-45-7 203-113-5 0.1-<1% EDI 1;H318,- oral: ATE = 2500 ACETATE mg/kg bw METHYL 2- 111-12-6 203-836-6 <0.1% SS 1A-EH A1-EH C3; OCTYNOATE H317-H400-H412,- Substances with Community workplace exposure limits: Not Applicable Substances that are endocrine disruptors according to Regulation (EU) 2017/2100 or Regulation (EU) 2018/605, greater than 0.1%: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure