DETOL

Hazard statements (CLP)

H304, H315, H317, H319, H411

Code

Statements

H304

May be fatal if swallowed and enters airways

SECTION 2: Hazards identification

Signal word

Danger

Hazard statements

H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains (1S,5S)-6,6-DIMETHYL-2-METHYLIDENEBICYCLO[3.1.1]HEPTANE, BETA-CARYOPHYLLENE, BETA-PINENES, CITRONELLAL, DIMETHYL-3-CYCLOHEXENE- 1-CARBALDEHYDE, DL-LIMONENE, LAURALDEHYDE, LINALOOL, METHYL ATRATATE, METHYLUNDECANAL, TERPINOLENE. May produce an allergic reaction.

Precautionary statements

P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331, Do not induce vomiting. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P391, Collect spillage. P405, Store locked up. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

Sensitisers declared on a CLP (1S,5S)-6,6-DIMETHYL-2-METHYLIDENEBICYCLO[3.1.1] Hazard Label: HEPTANE, BETA-CARYOPHYLLENE, BETA-PINENES,

2.3 Other hazards

CITRONELLAL, DIMETHYL-3-CYCLOHEXENE-1- CARBALDEHYDE, DL-LIMONENE, LAURALDEHYDE, LINALOOL, METHYL ATRATATE, METHYLUNDECANAL, TERPINOLENE Hydrocarbon Concentration %: 11.100%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Skin Corrosion / Irritation Category 2 danger: Eye Damage / Irritation Category 2 Sensitization - Skin Category 1 Aspiration Hazard Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects. 24 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Danger Hazard statements: H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects. Supplemental EUH208, Contains (1S,5S)-6,6-DIMETHYL-2-METHYLIDENEBICYCLO[3.1.1]HEPTANE, Information: BETA-CARYOPHYLLENE, BETA-PINENES, CITRONELLAL, DIMETHYL-3-CYCLOHEXENE- 1-CARBALDEHYDE, DL-LIMONENE, LAURALDEHYDE, LINALOOL, METHYL ATRATATE, METHYLUNDECANAL, TERPINOLENE. May produce an allergic reaction. Precautionary P261, Avoid breathing vapour or dust. statements: P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331, Do not induce vomiting. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P391, Collect spillage. P405, Store locked up. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: 2.3 Other hazards Other hazards: Sensitisers declared on a CLP (1S,5S)-6,6-DIMETHYL-2-METHYLIDENEBICYCLO[3.1.1] Hazard Label: HEPTANE, BETA-CARYOPHYLLENE, BETA-PINENES, 24 Other hazards: CITRONELLAL, DIMETHYL-3-CYCLOHEXENE-1- CARBALDEHYDE, DL-LIMONENE, LAURALDEHYDE, LINALOOL, METHYL ATRATATE, METHYLUNDECANAL, TERPINOLENE Hydrocarbon Concentration %: 11.100% Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs TRIMETHYLHEXYL 58430-94-7 261-245-9 01-2119972325-34-xxxx 10-<20% EH C2;H411,- oral: ATE = 4250 ACETATE mg/kg bw 2,6-DIMETHYL-7- SCI 2-EDI 2-STO-SE 3 oral: ATE = 3020 OCTEN-2-OL 18479-58-8 242-362-4 5-<10% (NE);H315-H319-H336, mg/kg bw - FL 3-ATO 4-SCI 2-SS ALPHA-PINENES 80-56-8 201-291-9 1-<5% 1B-AH 1-EH A1-EH oral: ATE = 500 mg/kg C1;H226-H302-H304- bw H315-H317-H410,- ALPHA-TERPINEOL 98-55-5 202-680-6 01-2119980717-23-xxxx 1-<5% SCI 2-EDI 2;H315- oral: ATE = 4300 H319,- mg/kg bw CITRAL 5392-40-5 226-394-6 01-2119462829-23-xxxx 1-<5% SCI 2-EDI 2-SS 1; H315-H317-H319,- FL 3-SCI 2-SS 1B-AH LIMONENE 5989-27-5 227-813-5 1-<5% 1-EH A1-EH C3;H226- H304-H315-H317- H400-H412,- EUCALYPTOL 470-82-6 207-431-5 1-<5% FL 3-SS 1B;H226- oral: ATE = 2480 H317,- mg/kg bw (1S,5S)-6,6-DIMETHYL- FL 3-SCI 2-SS 1B-AH 2- 18172-67-3 242-060-2 1-<5% 1-EH A1-EH C1;H226- METHYLIDENEBICYCL H304-H315-H317- O[3.1.1]HEPTANE H410,- SCI 2-SS 1B-EH A1- METHYLUNDECANAL 110-41-8 203-765-0 1-<5% EH C1;H315-H317- H410,- DIMETHYL-3- SCI 2-EDI 2-SS 1B-EH oral: ATE = 3900 CYCLOHEXENE-1- 27939-60-2 248-742-6 01-2120766006-57-xxxx 1-<5% C2;H315-H317-H319- mg/kg bw CARBALDEHYDE H411,- AMYL SALICYLATE 2050-08-0 218-080-2 1-<5% ATO 4-EH A1-EH C1; oral: ATE = 2000 H302-H410,- mg/kg bw TERPINEOL 8000-41-7 232-268-1 01-2119553062-49-xxxx 1-<5% SCI 2-EDI 2;H315- oral: ATE = 4300 H319,- mg/kg bw TERPINOLENE 586-62-9 209-578-0 1-<5% SS 1B-AH 1-EH A1-EH oral: ATE = 3775 C1;H304-H317-H410,- mg/kg bw LINALOOL 78-70-6 201-134-4 01-2119474016-42-xxxx 1-<5% SCI 2-EDI 2-SS 1B; oral: ATE = 2790 H315-H317-H319,- mg/kg bw HEXAHYDROMETHOX 53018-24-9, 258-296-4, 01-2120795903-40-xxxx 1-<5% EDI 2;H319,- oral: ATE = 2500 Y-METHANOINDENE 27135-90-6 248-247-5 mg/kg bw 24 FL 3-SCI 2-SS 1B-AH BETA-PINENES 127-91-3 204-872-5 0.1-<1% 1-EH A1-EH C1;H226- H304-H315-H317- H410,- SCI 2-EDI 2-SS 1B; dermal: ATE = 2500 CITRONELLAL 106-23-0 203-376-6 0.1-<1% H315-H317-H319,- mg/kg bw-oral: ATE = 2500 mg/kg bw BETA- 87-44-5 201-746-1 0.1-<1% SS 1B-AH 1;H304- CARYOPHYLLENE H317,- FL 3-REP 2-AH 1-EH oral: ATE = 3650 GAMMA-TERPINENE 99-85-4 202-794-6 0.1-<1% C2;H226-H304-H361- mg/kg bw H411,- FL 3-ATI 3-REP 2-AH inhalation: ATE = 9.7 P-CYMENE 99-87-6 202-796-7 0.1-<1% 1-EH C2;H226-H304- mg/l (vapour)-oral: ATE H331-H361-H411,- = 4750 mg/kg bw LAURALDEHYDE 112-54-9 203-983-6 01-2119969441-33-xxxx 0.1-<1% SCI 2-EDI 2-SS 1B; H315-H317-H319,- FL 3-SCI 2-SS 1B-AH DL-LIMONENE 138-86-3, 205-341-0, 0.1-<1% 1-EH A1-EH C3;H226- 7705-14-8 231-732-0 H304-H315-H317- H400-H412,- CAMPHENE 79-92-5 201-234-8 01-2119446293-40-xxxx 0.1-<1% FS 2-EH A1-EH C1; H228-H410,- METHYL ATRATATE 4707-47-5 225-193-0 0.1-<1% SS 1B;H317,- Substances with Community workplace exposure limits: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs DIETHYL PHTHALATE 84-66-2 201-550-6 01-2119486682-27-xxxx 1-<5% -;-,- 8006-64-2, 232-350-7, TURPENTINE 9005-90-7, 232-688-5 1-<5% -;-,- 8052-14-0 Substances that are endocrine disruptors according to Regulation (EU) 2017/2100 or Regulation (EU) 2018/605, greater than 0.1%: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin exposure: IF ON SKIN: Wash with plenty of soap and water. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. 4.2 Most important symptoms and effects, both acute and delayed May be fatal if swallowed and enters airways. 24 Causes skin irritation. May cause an allergic skin reaction.