DARK OPIUM FRAGRANCE OIL

Hazard statements (CLP)

H317, H319, H412

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

Signal word

Warning

Hazard statements

H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H412, Harmful to aquatic life with long lasting effects.

Additional information

EUH208, Contains (E)-1-(2,6,6-TRIMETHYL-1,3-CYCLOHEXADIEN-1-YL)-2-BUTEN-1-ONE, 4-TERT-BUTYLCYCLOHEXYL ACETATE, CITRAL, CYCLAMEN ALDEHYDE, GERANIOL, GERANYL ACETATE, TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENES, TETRAMETHYLTRICYCLOPROPANOL. May produce an allergic reaction.

Precautionary statements

P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

Sensitisers declared on a CLP (E)-1-(2,6,6-TRIMETHYL-1,3-CYCLOHEXADIEN-1-YL)-2- Hazard Label: BUTEN-1-ONE, 4-TERT-BUTYLCYCLOHEXYL ACETATE, CITRAL, CYCLAMEN ALDEHYDE, GERANIOL, GERANYL ACETATE, TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENES, TETRAMETHYLTRICYCLOPROPANOL Hydrocarbon Concentration %: 0.000%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Eye Damage / Irritation Category 2 danger: Sensitization - Skin Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 3 H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H412, Harmful to aquatic life with long lasting effects. 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Warning Hazard statements: H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. 57 H412, Harmful to aquatic life with long lasting effects. Supplemental EUH208, Contains (E)-1-(2,6,6-TRIMETHYL-1,3-CYCLOHEXADIEN-1-YL)-2-BUTEN-1-ONE, Information: 4-TERT-BUTYLCYCLOHEXYL ACETATE, CITRAL, CYCLAMEN ALDEHYDE, GERANIOL, GERANYL ACETATE, TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENES, TETRAMETHYLTRICYCLOPROPANOL. May produce an allergic reaction. Precautionary P261, Avoid breathing vapour or dust. statements: P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: 2.3 Other hazards Other hazards: Sensitisers declared on a CLP (E)-1-(2,6,6-TRIMETHYL-1,3-CYCLOHEXADIEN-1-YL)-2- Hazard Label: BUTEN-1-ONE, 4-TERT-BUTYLCYCLOHEXYL ACETATE, CITRAL, CYCLAMEN ALDEHYDE, GERANIOL, GERANYL ACETATE, TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENES, TETRAMETHYLTRICYCLOPROPANOL Hydrocarbon Concentration %: 0.000% Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs 57 2-T- EDI 2-EH C2;H319- BUTYLCYCLOHEXYLO 139504-68-0 412-300-2 1-<5% H411,- XYBUTANOL LINALOOL 78-70-6 201-134-4 01-2119474016-42-xxxx 1-<5% SCI 2-EDI 2-SS 1B; oral: ATE = 2790 H315-H317-H319,- mg/kg bw TETRAHYDRO- METHYL- 63500-71-0 405-040-6 01-0000015458-64-xxxx 1-<5% EDI 2;H319,- (METHYLPROPYL)- PYRAN-4-OL dermal: ATE = 2600 VANILLIN 121-33-5 204-465-2 1-<5% EDI 2;H319,- mg/kg bw-oral: ATE = 3300 mg/kg bw ETHYL VANILLIN 121-32-4 204-464-7 1-<5% EDI 2;H319,- oral: ATE = 3000 mg/kg bw ANISALDEHYDE 123-11-5 204-602-6 1-<5% EH C3;H412,- oral: ATE = 3210 mg/kg bw ETHYL 106185-75-5, 701-122-3, EDI 2-EH C2;H319- TRIMETHYLCYCLOPE 28219-61-6 248-908-8 01-2119529224-45-xxxx 1-<5% H411,- NTENE BUTENOL 2,6-DIMETHYL-7- SCI 2-EDI 2-STO-SE 3 oral: ATE = 3020 OCTEN-2-OL 18479-58-8 242-362-4 1-<5% (NE);H315-H319-H336, mg/kg bw - 259-174-3, 54464-57-2, TETRAMETHYL 54464-59-4, 259-175-9, SCI 2-SS 1B-EH C1; ACETYLOCTAHYDRON 68155-66-8, 268-978-3, 01-2119489989-04-xxxx 0.1-<1% H315-H317-H410,- APHTHALENES 268-979-9, 68155-67-9 915-730-3 4-TERT- oral: ATE = 3370 BUTYLCYCLOHEXYL 32210-23-4 250-954-9 01-2119976286-24-xxxx 0.1-<1% SS 1B;H317,- mg/kg bw ACETATE GERANIOL 106-24-1 203-377-1 01-2119552430-49-xxxx 0.1-<1% SCI 2-EDI 1-SS 1; oral: ATE = 3600 H315-H317-H318,- mg/kg bw BENZYL BENZOATE 120-51-4 204-402-9 0.1-<1% ATO 4-EH A1-EH C2; oral: ATE = 1160 H302-H400-H411,- mg/kg bw TETRAMETHYLTRICY 929625-08-1, SCI 2-SS 1-EH A1-EH CLOPROPANOL 1001252-30- 482-030-8 0.1-<1% C1;H315-H317-H410,- 7 CITRAL 5392-40-5 226-394-6 01-2119462829-23-xxxx 0.1-<1% SCI 2-EDI 2-SS 1; H315-H317-H319,- GERANYL ACETATE 105-87-3 203-341-5 01-2119973480-35-xxxx 0.1-<1% SCI 2-SS 1B-EH C3; H315-H317-H412,- CYCLAMEN 103-95-7 203-161-7 01-2119970582-32-xxxx 0.1-<1% SCI 2-SS 1B-EH C3; oral: ATE = 3810 ALDEHYDE H315-H317-H412,- mg/kg bw (E)-1-(2,6,6- TRIMETHYL-1,3- 23726-93-4 245-844-2 01-2120105798-49-xxxx <0.1% SCI 2-SS 1A-EH C2; dermal: ATE = 2900 CYCLOHEXADIEN-1- H315-H317-H411,- mg/kg bw YL)-2-BUTEN-1-ONE Substances with Community workplace exposure limits: Not Applicable Substances that are endocrine disruptors according to Regulation (EU) 2017/2100 or Regulation (EU) 2018/605, greater than 0.1%: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable 57 Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin exposure: IF ON SKIN: Wash with plenty of soap and water. Ingestion: Rinse mouth with water and obtain medical attention. 4.2 Most important symptoms and effects, both acute and delayed May cause an allergic skin reaction. Causes serious eye irritation. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. Section 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. 57 Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation Do not eat, drink or smoke when using this product. 7.2 Conditions for safe storage, including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s): Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: Not Applicable 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Under normal conditions of use and where adequate ventilation is available to prevent build up of excessive vapour, this material should not require special engineering controls. However, in conditions of high or prolonged use, or high temperature or other conditions which increase exposure, the following engineering controls can be used to minimise exposure to personnel: a) Increase ventilation of the area with local exhaust ventilation. b) Personnel can use an approved, appropriately fitted respirator with organic vapour cartridge or canisters and particulate filters. c) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. Section 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Physical State/Colour: Not determined Odour: Not determined Odour threshold: Not determined Melting point / freezing point: Not determined Boiling point or initial boiling point and boiling Not determined range: Flammability: Not determined Lower and upper explosion limit: Not determined Flash point: > 100 °C