BLISS UNSTOPPABLE FRAGRANCE

Hazard statements (CLP)

H226, H304, H315, H317, H319, H400, H411

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Signal word

Danger

Hazard statements

H226, Flammable liquid and vapour. H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H400, Very toxic to aquatic life. H411, Toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains 2,4-DIMETHYL-3-CYCLOHEXENE CARBOXALDEHYDE, 4-TERT- BUTYLCYCLOHEXYL ACETATE, ACETYL CEDRENE, ALPHA-ISOMETHYL IONONE, ALPHA-PINENES, CITRONELLOL, EUGENOL, GERANIOL, METHYL CINNAMATE, NEROL. May produce an allergic reaction.

Precautionary statements

P210, Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P233, Keep container tightly closed. P240, Ground/bond container and receiving equipment. P241, Use explosion-proof electrical, ventilating and lighting equipment. P242, Use only non-sparking tools. P243, Take precautionary measures against static discharge. P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331, Do not induce vomiting. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P370/378, In case of fire: Use carbon dioxide, dry chemical, foam for extinction. P391, Collect spillage. P403/235, Store in a well-ventilated place. Keep cool. P405, Store locked up. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

Sensitisers declared on a CLP 2,4-DIMETHYL-3-CYCLOHEXENE CARBOXALDEHYDE, 4- Hazard Label: TERT-BUTYLCYCLOHEXYL ACETATE, ACETYL CEDRENE, ALPHA-ISOMETHYL IONONE, ALPHA- PINENES, CITRONELLOL, EUGENOL, GERANIOL, METHYL CINNAMATE, NEROL Hydrocarbon Concentration %: 31.453%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Flammable Liquid, Hazard Category 3 danger: Skin Corrosion / Irritation Category 2 Eye Damage / Irritation Category 2 Sensitization - Skin Category 1 Aspiration Hazard Category 1 Hazardous to the Aquatic Environment - Acute Hazard Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H226, Flammable liquid and vapour. H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H400, Very toxic to aquatic life. 30 H411, Toxic to aquatic life with long lasting effects. 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Danger Hazard statements: H226, Flammable liquid and vapour. H304, May be fatal if swallowed and enters airways. H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H400, Very toxic to aquatic life. H411, Toxic to aquatic life with long lasting effects. Supplemental EUH208, Contains 2,4-DIMETHYL-3-CYCLOHEXENE CARBOXALDEHYDE, 4-TERT- Information: BUTYLCYCLOHEXYL ACETATE, ACETYL CEDRENE, ALPHA-ISOMETHYL IONONE, ALPHA-PINENES, CITRONELLOL, EUGENOL, GERANIOL, METHYL CINNAMATE, NEROL. May produce an allergic reaction. Precautionary P210, Keep away from heat, sparks, open flames and hot surfaces. - No smoking. statements: P233, Keep container tightly closed. P240, Ground/bond container and receiving equipment. P241, Use explosion-proof electrical, ventilating and lighting equipment. P242, Use only non-sparking tools. P243, Take precautionary measures against static discharge. P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/310, IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P331, Do not induce vomiting. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P370/378, In case of fire: Use carbon dioxide, dry chemical, foam for extinction. P391, Collect spillage. P403/235, Store in a well-ventilated place. Keep cool. P405, Store locked up. P501, Dispose of contents/container to approved disposal site, in accordance with local 30 regulations. Pictograms: 2.3 Other hazards Other hazards: Sensitisers declared on a CLP 2,4-DIMETHYL-3-CYCLOHEXENE CARBOXALDEHYDE, 4- Hazard Label: TERT-BUTYLCYCLOHEXYL ACETATE, ACETYL CEDRENE, ALPHA-ISOMETHYL IONONE, ALPHA- PINENES, CITRONELLOL, EUGENOL, GERANIOL, METHYL CINNAMATE, NEROL Hydrocarbon Concentration %: 31.453% Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs FL 3-SCI 2-SS 1B-AH LIMONENE 5989-27-5 227-813-5 20-<50% 1-EH A1-EH C3;H226- H304-H315-H317- H400-H412,- LINALOOL 78-70-6 201-134-4 01-2119474016-42-xxxx 1-<5% SCI 2-EDI 2-SS 1B; oral: ATE = 2790 H315-H317-H319,- mg/kg bw AMYL CINNAMAL 122-40-7 204-541-5 1-<5% SS 1B-EH C2;H317- oral: ATE = 3730 H411,- mg/kg bw HEXYL CINNAMAL 101-86-0 202-983-3 1-<5% SS 1B-EH A1-EH C2; oral: ATE = 3100 H317-H400-H411,- mg/kg bw GAMMA 104-67-6 203-225-4 1-<5% EH C3;H412,- UNDECALACTONE CIS-2-TERT- oral: ATE = 4600 BUTYLCYCLOHEXYL 20298-69-5 243-718-1 01-2119970713-33-xxxx 1-<5% EH C2;H411,- mg/kg bw ACETATE ACETYL CEDRENE 32388-55-9 251-020-3 1-<5% SS 1B-EH A1-EH C1; oral: ATE = 4500 H317-H410,- mg/kg bw GERANIOL 106-24-1 203-377-1 01-2119552430-49-xxxx 0.1-<1% SCI 2-EDI 1-SS 1; oral: ATE = 3600 H315-H317-H318,- mg/kg bw 4-TERT- oral: ATE = 3370 BUTYLCYCLOHEXYL 32210-23-4 250-954-9 01-2119976286-24-xxxx 0.1-<1% SS 1B;H317,- mg/kg bw ACETATE 106-22-9, 203-375-0, 1117-61-9, 214-250-5, 26489-01-0, 247-737-6, SCI 2-EDI 2-SS 1B; dermal: ATE = 2650 CITRONELLOL 6812-78-8, 229-887-4, 01-2119453995-23-xxxx 0.1-<1% H315-H317-H319,- mg/kg bw-oral: ATE = 3450 mg/kg bw 141-25-3, 205-473-9, 7540-51-4 231-415-7 30 1,3,4,6,7,8- HEXAHYDRO- 4,6,6,7,8,8- 1222-05-5 214-946-9 01-2119488227-29-xxxx 0.1-<1% EH A1-EH C1;H410,- HEXAMETHYLINDENO [5,6-C]PYRAN FL 3-SCI 2-EDI 2-AH MYRCENE 123-35-3 204-622-5 0.1-<1% 1-EH A1-EH C2;H226- H304-H315-H319- H400-H411,- ALPHA-ISOMETHYL 127-51-5 204-846-3 0.1-<1% SS 1B-EH C2;H317- IONONE H411,- NEROL 106-25-2 203-378-7 0.1-<1% SCI 2-EDI 2-SS 1B; oral: ATE = 4500 H315-H317-H319,- mg/kg bw 2,4-DIMETHYL-3- SCI 2-SS 1B-EH C2; oral: ATE = 2330 CYCLOHEXENE 68039-49-6 268-264-1 0.1-<1% H315-H317-H411,- mg/kg bw CARBOXALDEHYDE ACETYL HEXAMETHYL 21145-77-7, 244-240-6, 0.1-<1% ATO 4-EH A1-EH C1; oral: ATE = 1000 TETRALIN (AHTN) 1506-02-1 216-133-4 H302-H410,- mg/kg bw OXACYCLOHEXADEC 34902-57-3, 422-320-3 01-0000016883-62-xxxx 0.1-<1% EH A1-EH C1;H410,- EN-2-ONE 111879-80-2 EUGENOL 97-53-0 202-589-1 0.1-<1% EDI 2-SS 1B;H317- oral: ATE = 2500 H319,- mg/kg bw METHYL CINNAMATE 103-26-4 203-093-8 0.1-<1% SS 1B;H317,- oral: ATE = 2610 mg/kg bw FL 3-ATO 4-SCI 2-SS ALPHA-PINENES 80-56-8 201-291-9 0.1-<1% 1B-AH 1-EH A1-EH oral: ATE = 500 mg/kg C1;H226-H302-H304- bw H315-H317-H410,- Substances with Community workplace exposure limits: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs DIETHYL PHTHALATE 84-66-2 201-550-6 01-2119486682-27-xxxx 20-<50% -;-,- Substances that are endocrine disruptors according to Regulation (EU) 2017/2100 or Regulation (EU) 2018/605, greater than 0.1%: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin exposure: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. Ingestion: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. 4.2 Most important symptoms and effects, both acute and delayed 30 May be fatal if swallowed and enters airways. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. Section 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage