BIOLOGICAL DEFINITION

Hazard statements (CLP)

H226, H304, H315, H317, H410

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE THE FULL TEXT FOR ALL HAZARD STATEMENTS IS DISPLAYED IN SECTION 16 CLASSIFICATION (67/548/EEC) NO ADDITIONAL DATA AVAILABLE H226 FLAMMABLE LIQUID AND VAPOUR, HAZARD CATEGORY 3 H315 SKIN IRRITATION, CATEGORY 2 CLASSIFICATION (EU1272/2008) H317 SKIN SENSITISATION, CATEGORY 1 H304 ASPIRATION HAZARD, CATEGORY 1 H410 ENVIRONMENTAL HAZARD, CHRONIC, CATEGORY 1

2.2 Label elements

GHS07 GHS08 GHS09 GHS02

Signal word

DANGER.

Contains

ALPHA PINENE, BETA PINENE, LIMONENE, BETA-CARYOPHYLLENE H226 FLAMMABLE LIQUID AND VAPOUR H315 CAUSES SKIN IRRITATION

Hazard statements

H317 MAY CAUSE AN ALLERGIC SKIN REACTION H304 MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS H410 VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS P210, KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES AND HOT SURFACES. - NO SMOKING. P233, KEEP CONTAINER TIGHTLY CLOSED. P240, GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. P241, USE EXPLOSION-PROOF ELECTRICAL, VENTILATING AND LIGHTING EQUIPMENT. P242, USE ONLY NON-SPARKING TOOLS. P243, TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. P261, AVOID BREATHING VAPOUR OR DUST. P264, WASH HANDS AND OTHER CONTACTED SKIN THOROUGHLY AFTER HANDLING. P272, CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. P273, AVOID RELEASE TO THE ENVIRONMENT.

Precautionary statements

P280, WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION. P301/310, IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. P303/361/353, IF ON SKIN (OR HAIR): REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER/SHOWER. P331, DO NOT INDUCE VOMITING. P333/313, IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION. P362, TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE. P370/378, IN CASE OF FIRE: USE CARBON DIOXIDE, DRY CHEMICAL, FOAM FOR EXTINCTION. P391, COLLECT SPILLAGE. P403/235, STORE IN A WELL-VENTILATED PLACE. KEEP COOL. P501, DISPOSE OF CONTENTS/CONTAINER TO APPROVED DISPOSAL SITE, IN ACCORDANCE WITH LOCAL REGULATIONS SUPPLEMENTARY PRECAUTIONARY STATEMENTS NONE SECTION 16 (OTHER INFORMATION): RISK & SAFETY PHRASES IN FULL.

2.3 Other hazards

ADVERSE PHYSIO-CHEMICAL PROPERTIES NONE.

Potential Acute Health Effects

NONE. PBT OR VPVB ACCORDING TO ANNEX XIII NONE

2.1 Classification of the substance or mixture

CLASSIFICATION OF THE SUBSTANCE OR MIXTURE THE FULL TEXT FOR ALL HAZARD STATEMENTS IS DISPLAYED IN SECTION 16. CLASSIFICATION (67/548/EEC) NO ADDITIONAL DATA AVAILABLE. H226 FLAMMABLE LIQUID AND VAPOUR, HAZARD CATEGORY 3 H315 SKIN IRRITATION, CATEGORY 2 CLASSIFICATION (EU1272/2008) H317 SKIN SENSITISATION, CATEGORY 1 H304 ASPIRATION HAZARD, CATEGORY 1 H410 ENVIRONMENTAL HAZARD, CHRONIC, CATEGORY 1 2.2 LABEL ELEMENTS LABEL IN ACCORDANCE WITH REGULATION (EC) NO 1272/2008. GHS LABEL GHS07 GHS08 GHS09 GHS02 SIGNAL WORD DANGER. CONTAINS ALPHA PINENE, BETA PINENE, LIMONENE, BETA-CARYOPHYLLENE H226 FLAMMABLE LIQUID AND VAPOUR H315 CAUSES SKIN IRRITATION HAZARDS STATEMENT H317 MAY CAUSE AN ALLERGIC SKIN REACTION H304 MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS H410 VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS P210, KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES AND HOT SURFACES. - NO SMOKING. P233, KEEP CONTAINER TIGHTLY CLOSED. P240, GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. P241, USE EXPLOSION-PROOF ELECTRICAL, VENTILATING AND LIGHTING EQUIPMENT. P242, USE ONLY NON-SPARKING TOOLS. P243, TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. P261, AVOID BREATHING VAPOUR OR DUST. P264, WASH HANDS AND OTHER CONTACTED SKIN THOROUGHLY AFTER HANDLING. P272, CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. P273, AVOID RELEASE TO THE ENVIRONMENT. PRECAUTIONARY STATEMENTS P280, WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION. P301/310, IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. P303/361/353, IF ON SKIN (OR HAIR): REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER/SHOWER. P331, DO NOT INDUCE VOMITING. P333/313, IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION. P362, TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE. P370/378, IN CASE OF FIRE: USE CARBON DIOXIDE, DRY CHEMICAL, FOAM FOR EXTINCTION. P391, COLLECT SPILLAGE. P403/235, STORE IN A WELL-VENTILATED PLACE. KEEP COOL. P501, DISPOSE OF CONTENTS/CONTAINER TO APPROVED DISPOSAL SITE, IN ACCORDANCE WITH LOCAL REGULATIONS SUPPLEMENTARY PRECAUTIONARY STATEMENTS NONE SECTION 16 (OTHER INFORMATION): RISK & SAFETY PHRASES IN FULL. 2.3 OTHER HAZARDS ADVERSE PHYSIO-CHEMICAL PROPERTIES NONE. ADVERSE EFFECTS ON HUMAN HEALTH NONE. PBT OR VPVB ACCORDING TO ANNEX XIII NONE SECTION 3: COMPOSITION OF INGREDIENTS 25.0 - 50.0% ALPHA-PINENE CAS-NO.: 80-56-8 EC NO.: 201-291-9 CLASSIFICATION (EC 1272/2008) FL 3-SCI 2-SS 1B-AH 1-EH, A1-EH C1; H226-H304-H315-H317-H410 25.0 - 50.0% BETA-PINENE CAS-NO.: 127-91-3 EC NO.: 204-872-5 CLASSIFICATION (EC 1272/2008) FL 3-SCI 2-SS 1B-AH 1-EHA1-EH C1; H226-H304-H315-H317-H410 < 5.0% LIMONENE CAS-NO.: 5989-27-5 EC NO.: 227-813-5CLASSIFICATION (EC 1272/2008) FL 3-SCI 2-SS 1B-AH 1-EH A1-EH C1; H226-H304-H315-H317-H410 <5.0% BETA-CARYOPHYLLENE CAS-NO.: 87-44-5 EC NO.: 201-746-1 CLASSIFICATION (EC 1272/2008) AH 1;H304 <5.0% CAMPHENE CAS-NO.: 79-92-5 EC NO.: 201-243-8 CLASSIFICATION (EC 1272/2008) FS 2-EDI 2-EH A1-EH C1; H228-H319-H410 3.1 MIXTURES < 1.0% TERPINOLENE CAS-NO.: 586-62-9 EC NO.: 209-578-0CLASSIFICATION (EC 1272/2008) SS 1B-AH 1-EH A1-EH C1;H304-H317-H410 < 1.0% MYRCENE CAS-NO.: 123-35-3 EC NO.: 204-622-5 CLASSIFICATION (EC 1272/2008) FL 3-SCI 2-EDI 2-AH 1; H226-H304-H315-H319 < 1.0% PARA-CYMENE CAS-NO.: 99-87-6 EC NO.: 202-796-7 CLASSIFICATION (EC 1272/2008) FL 3-AH 1-EH C2; H226-H304-H411 < 1.0% ALPHA PHELLANDRENE CAS: 99-83-2, EINECS: 202-792-5 CLASSIFICATION (EC 1272/2008) FL 3-AH 1;H226-H304 SECTION 4: FIRST AID MEASURES 4.1 DESCRIPTION OF FIRST AID MEASURES GENERAL INFORMATION ALWAYS REMOVE CONTAMINATED CLOTHING IMMEDIATELY. GET MEDICAL ATTENTION IMMEDIATELY. REMOVE FROM EXPOSURE SITE TO FRESH AIR, KEEP AT REST, AND OBTAIN MEDICAL INHALATION ATTENTION. INGESTION GET MEDICAL ATTENTION IMMEDIATELY. RINSE MOUTH WITH WATER AND OBTAIN MEDICAL ATTENTION. SKIN CONTACT REMOVE CONTAMINATED CLOTHES. WASH THOROUGHLY WITH SOAP AND WATER. CONTACT PHYSICIAN IF IRRITATION PERSISTS. EYE CONTACT FLUSH IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES. CONTACT PHYSICIAN IF SYMPTOMS PERSIST. 4.2 NO DATA. MOST IMPORTANT SYMPTOMS & EFFECTS (ACUTE & DELAYED) 4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION OR NO DATA. SPECIAL TREATMENT REQUIRED SECTION 5: FIRE FIGHTING MEASURES 5.1 EXTINGUISHING MATERIAL FOAM, CO2, DRY CHEMICAL POWDER. 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR NONE. MIXTURE 5.3 SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS: ADVICE FOR FIRE-FIGHTERS WEAR POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA) AND APPROPRIATE PROTECTIVE CLOTHING. SECTION 6: ACCIDENTAL RELEASE MEASURES ENSURE ADEQUATE VENTILATION OF THE WORKING AREA, EVACUATE PERSONNEL TO SAFE AREA, WEAR SUITABLE PROTECTIVE 6.1 EQUIPMENT. NO SMOKING, SPARKS, FLAMES OR OTHER SOURCES OF IGNITION NEAR SPILLAGE. AVOID CONTACT WITH SKIN, PERSONAL PRECAUTIONS EYES AND CLOTHING. 6.2 DO NOT DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND. DISPOSE OF IN LINE WITH LOCAL AUTHORITY ENVIRONMENTAL PRECAUTIONS GUIDELINES. 6.3 REMOVE IGNITION SOURCES. PROVIDE ADEQUATE VENTILATION. AVOID EXCESSIVE INHALATION OF VAPOURS. CONTAIN METHODS & MATERIAL FOR CONTAINMENT AND CLEANING SPILLAGE IMMEDIATELY BY USE OF SAND OR INERT POWDER. DISPOSE OF ACCORDING TO LOCAL REGULATIONS. UP 6.4 REFER & CONSIDER SECTION 8. REFERENCES TO OTHER SECTIONS REFER & CONSIDER SECTION 13. SECTION 7: HANDLING & STORAGE HANDLE IN ACCORDANCE WITH GOOD HYGIENE AND SAFETY PRACTICE. KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES AND 7.1 HOT SURFACES. - NO SMOKING. USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. USE IN ACCORDANCE WITH GOOD PRECAUTIONS FOR SAFE-HANDLING MANUFACTURING AND INDUSTRIAL HYGIENE PRACTICES. USE IN AREAS WITH ADEQUATE VENTILATION DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. 7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY KEEP THE PRODUCT CONTAINER TIGHTLY CLOSED, IN A DRY, VENTILATED AREA. KEEP AWAY FROM POTENTIAL SOURCES OF INCOMPATIBILITIES IGNITION AND PROTECTED FROM LIGHT. MAINTAIN LIMITED CONTACT WITH OXYGEN. 7.3 SPECIFIC END USE(S) NO DATA. SECTION 8: EXPOSURE CONTROLS & PERSONAL PROTECTION 8.1 NONE. CONTROL PARAMETERS 8.2 EXPOSURE CONTROLS EYE PROTECTION WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION. HAND PROTECTION WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION. UNDER NORMAL CONDITIONS OF USE AND WHERE ADEQUATE VENTILATION IS AVAILABLE TO PREVENT BUILD UP OF EXCESSIVE RESPIRATORY EQUIPMENT VAPOUR, THIS MATERIAL SHOULD NOT REQUIRE SPECIAL ENGINEERING CONTROLS. HOWEVER, IN CONDITIONS OF HIGH OR PROLONGED USE, OR HIGH TEMPERATURE OR OTHER CONDITIONS WHICH INCREASE EXPOSURE, THE FOLLOWING ENGINEERING CONTROLS CAN BE USED TO MINIMISE EXPOSURE TO PERSONNEL: A) INCREASE VENTILATION OF THE AREA WITH LOCAL EXHAUST VENTILATION. B) PERSONNEL CAN USE AN APPROVED, APPROPRIATELY FITTED RESPIRATOR WITH ORGANIC VAPOUR CARTRIDGE OR CANISTERS AND PARTICULATE FILTERS. C) USE CLOSED SYSTEMS FOR TRANSFERRING AND PROCESSING THIS MATERIAL. ALSO REFER TO SECTIONS 2 AND 7. HYGIENE MEASURES GOOD PERSONAL HYGIENE PRACTICES ARE ALWAYS ADVISABLE, ESPECIALLY WHEN WORKING WITH CHEMICALS / OILS. ENGINEERING MEASURES PROVIDE ADEQUATE VENTILLATION. SKIN PROTECTION WEAR PROTECTIVE CLOTHING TO REDUCE THE RISK OF SKIN AND EYE CONTACT. PERSONAL PROTECTION AVOID INHALATION OF THE PRODUCT. AVOID CONTACT WITH SKIN AND EYES. OTHER PROTECTION WEAR SUITABLE PROTECTION TO AVOID CONTACT WITH SKIN AND EYES. DO NOT INHALE VAPOURS. PROCESS CONDITIONS ENSURE AREA IS WELL VENTILATED. AVOID VAPOUR INHALATION. SAFETY SHOWER & EYE BATH. ENVIROMENTAL EXPOSURE CONTROLS AVOID DISCHARGING INTO DRAINAGE WATER. SECTION 9: PHYSICAL & CHEMICAL PROPERTIES 9.1 PHYSICAL & CHEMICAL PROPERTIES APPEARANCE LIQUID COLOUR PALE YELLOW - YELLOW ODOUR RICH BALSAMIC WOODY PINEY RELATIVE DENSITY 0.858 - 0.874 @ 20°C FLASH POINT (°C) 41°C. REFRACTIVE INDEX @ 20 °C 1.468 - 1.482 @ 20°C SOLUBILITY IN WATER @ 20 °C INSOLUBLE IN WATER 9.2 OTHER INFORMATION NO DATA. SECTION 10: STABILITY & REACTIVITY 10.1 REACTIVITY STABLE UNDER USUAL STORAGE CONDITIONS. 10.2 CHEMICAL STABILITY STABLE UNDER SUGGESTED STORAGE CONDITIONS (<15°C). 10.3 POSSIBILITY OF HAZARDOUS REACTIONS NO. 10.4 CONDITIONS TO AVOID STORAGE AT HIGH TEMPERATURES. DO NOT STORE ABOVE 15°C. 10.5 INCOMPATIBLE MATERIALS AVOID CONCENTRATED ACIDS, ALKALIS & OXIDISING AGENTS. 10.6 THIS PRODUCT DOES NOT DECOMPOSE UNDER NORMAL CONDITIONS. UNDER FIRE CONDITIONS THE PRODUCT WILL PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS A MIXTURE OF IRRITATING FUMES & SMOKE & CARBON MONOXIDE. SECTION 11: TOXICOLOGICAL INFORMATION 11.1 TOXICOLOGICAL EFFECTS ACUTE TOXICITY