BERGAMOT PATCHOULI

Hazard statements (CLP)

H315, H317, H319, H411

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Signal word

Warning

Hazard statements

H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains 2,4-DIMETHYL-3-CYCLOHEXENE CARBOXALDEHYDE, CITRAL, COUMARIN, EUGENOL, GERANIOL, GERANYL ACETATE, LIMONENE, NEROL, NERYL ACETATE. May produce an allergic reaction.

Precautionary statements

P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

Sensitisers declared on a CLP 2,4-DIMETHYL-3-CYCLOHEXENE CARBOXALDEHYDE, Hazard Label: CITRAL, COUMARIN, EUGENOL, GERANIOL, GERANYL ACETATE, LIMONENE, NEROL, NERYL ACETATE Hydrocarbon Concentration %: 0.000%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Skin Corrosion / Irritation Category 2 danger: Eye Damage / Irritation Category 2 Sensitization - Skin Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects. 32 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Warning Hazard statements: H315, Causes skin irritation. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects. Supplemental EUH208, Contains 2,4-DIMETHYL-3-CYCLOHEXENE CARBOXALDEHYDE, CITRAL, Information: COUMARIN, EUGENOL, GERANIOL, GERANYL ACETATE, LIMONENE, NEROL, NERYL ACETATE. May produce an allergic reaction. Precautionary P261, Avoid breathing vapour or dust. statements: P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: 2.3 Other hazards Other hazards: Sensitisers declared on a CLP 2,4-DIMETHYL-3-CYCLOHEXENE CARBOXALDEHYDE, Hazard Label: CITRAL, COUMARIN, EUGENOL, GERANIOL, GERANYL ACETATE, LIMONENE, NEROL, NERYL ACETATE Hydrocarbon Concentration %: 0.000% 32 Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs 259-174-3, 54464-57-2, TETRAMETHYL 54464-59-4, 259-175-9, SCI 2-SS 1B-EH C1; ACETYLOCTAHYDRON 68155-66-8, 268-978-3, 01-2119489989-04-xxxx 5-<10% H315-H317-H410,- APHTHALENES 268-979-9, 68155-67-9 915-730-3 4-TERT- oral: ATE = 3370 BUTYLCYCLOHEXYL 32210-23-4 250-954-9 01-2119976286-24-xxxx 5-<10% SS 1B;H317,- mg/kg bw ACETATE 2-T- EDI 2-EH C2;H319- BUTYLCYCLOHEXYLO 139504-68-0 412-300-2 5-<10% H411,- XYBUTANOL TETRAHYDROLINALO 78-69-3 201-133-9 01-2119454788-21-xxxx 5-<10% SCI 2-EDI 2-SS 1B; OL H315-H317-H319,- 106-22-9, 203-375-0, 1117-61-9, 214-250-5, 26489-01-0, 247-737-6, SCI 2-EDI 2-SS 1B; dermal: ATE = 2650 CITRONELLOL 6812-78-8, 229-887-4, 01-2119453995-23-xxxx 1-<5% H315-H317-H319,- mg/kg bw-oral: ATE = 3450 mg/kg bw 141-25-3, 205-473-9, 7540-51-4 231-415-7 GERANIOL 106-24-1 203-377-1 01-2119552430-49-xxxx 1-<5% SCI 2-EDI 1-SS 1; oral: ATE = 3600 H315-H317-H318,- mg/kg bw EUGENOL 97-53-0 202-589-1 1-<5% EDI 2-SS 1B;H317- oral: ATE = 2500 H319,- mg/kg bw ETHYL 106185-75-5, 701-122-3, EDI 2-EH C2;H319- TRIMETHYLCYCLOPE 28219-61-6 248-908-8 01-2119529224-45-xxxx 1-<5% H411,- NTENE BUTENOL NERYL ACETATE 141-12-8 205-459-2 0.1-<1% SS 1B;H317,- CITRAL 5392-40-5 226-394-6 01-2119462829-23-xxxx 0.1-<1% SCI 2-EDI 2-SS 1; H315-H317-H319,- COUMARIN 91-64-5 202-086-7 0.1-<1% ATO 4-SS 1B-EH C3; oral: ATE = 500 mg/kg H302-H317-H412,- bw FL 3-SCI 2-SS 1B-AH LIMONENE 5989-27-5 227-813-5 0.1-<1% 1-EH A1-EH C3;H226- H304-H315-H317- H400-H412,- 2,4-DIMETHYL-3- SCI 2-SS 1B-EH C2; oral: ATE = 2330 CYCLOHEXENE 68039-49-6 268-264-1 0.1-<1% H315-H317-H411,- mg/kg bw CARBOXALDEHYDE GERANYL ACETATE 105-87-3 203-341-5 01-2119973480-35-xxxx 0.1-<1% SCI 2-SS 1B-EH C3; H315-H317-H412,- NEROL 106-25-2 203-378-7 0.1-<1% SCI 2-EDI 2-SS 1B; oral: ATE = 4500 H315-H317-H319,- mg/kg bw Substances with Community workplace exposure limits: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs DIETHYL PHTHALATE 84-66-2 201-550-6 01-2119486682-27-xxxx 20-<50% -;-,- 32 Substances that are endocrine disruptors according to Regulation (EU) 2017/2100 or Regulation (EU) 2018/605, greater than 0.1%: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin exposure: IF ON SKIN: Wash with plenty of soap and water. Ingestion: Rinse mouth with water and obtain medical attention. 4.2 Most important symptoms and effects, both acute and delayed Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. Section 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 32 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation Do not eat, drink or smoke when using this product. 7.2 Conditions for safe storage, including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s): Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: Ingredient CAS EC Description Value UK Long-term exposure limit (8-hour TWA) 5 mg/m³ (mg/m3) DIETHYL PHTHALATE 84-66-2 201-550-6 UK Short-term exposure limit (15-minute) 10 mg/m³ (mg/m3) 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Ensure adequate and ongoing ventilation is maintained in order to prevent build up of excessive vapour and to ensure occupational exposure limits are adhered to. If appropriate, and depending on your patterns and volumes of use, the following engineering controls may be required as additional protective measures: a) Isolate mixing rooms and other 32 areas where this material is used or openly handled. Maintain these areas under negative air pressure relative to the rest of the plant. b) Employ the use of Personal protective equipment - an approved, properly fitted respirator with organic vapour cartridges or canisters and particulate filters. c) Use local exhaust ventilation around open tanks and other open sources of potential exposures in order to avoid excessive inhalation, including places where this material is openly weighed or measured. In addition, use general dilution ventilation of the work area to eliminate or reduce possible worker exposures. d) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. Section 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Physical State/Colour: Clear pale yellow to yellow liquid Odour: Not determined Odour threshold