ARY FRAGRANCE

Hazard statements (CLP)

H317, H319, H411

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

Signal word

Warning

Hazard statements

H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains 4-TERT-BUTYLCYCLOHEXYL ACETATE, CIS-3-HEXENYL METHYL CARBONATE, CITRONELLOL, COUMARIN, GERANYL ACETATE, HEXYL SALICYLATE, LIMONENE, LINALYL ACETATE, NERYL ACETATE, TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENES. May produce an allergic reaction.

Precautionary statements

P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

2.3 Other hazards

Hydrocarbon Concentration %: 0.498%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Eye Damage / Irritation Category 2 danger: Sensitization - Skin Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects. 2.2 Label elements Signal word: Warning Hazard statements: H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. 3 H411, Toxic to aquatic life with long lasting effects. Supplemental EUH208, Contains 4-TERT-BUTYLCYCLOHEXYL ACETATE, CIS-3-HEXENYL METHYL Information: CARBONATE, CITRONELLOL, COUMARIN, GERANYL ACETATE, HEXYL SALICYLATE, LIMONENE, LINALYL ACETATE, NERYL ACETATE, TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENES. May produce an allergic reaction. Precautionary P261, Avoid breathing vapour or dust. statements: P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: Other hazards: Hydrocarbon Concentration %: 0.498% Section 3. Composition / information on ingredients 3.2 Mixtures Contains: REACH Registration Classification for Name CAS EC % No. (CLP) 1272/2008 HEXAMETHYLINDANO 1222-05-5 214-946-9 01-2119488227-29-xxxx 5-<10% EH A1-EH C1;H410,- PYRAN TETRAHYDRO- METHYL- 63500-71-0 405-040-6 01-0000015458-64-xxxx 5-<10% EDI 2;H319,- (METHYLPROPYL)- PYRAN-4-OL BENZYL SALICYLATE 118-58-1 204-262-9 1-<5% SS 1B-EH C3;H317- H412,- ETHYL EDI 2-EH C2;H319- TRIMETHYLCYCLOPE 28219-61-6 248-908-8 01-2119529224-45-xxxx 1-<5% H411,- NTENE BUTENOL 3 LINALOOL 78-70-6 201-134-4 01-2119474016-42-xxxx 1-<5% SCI 2-EDI 2-SS 1B; H315-H317-H319,- BENZYL ACETATE 140-11-4 205-399-7 1-<5% EH C3;H412,- CITRONELLYL 150-84-5 205-775-0 01-2119959860-27-xxxx 1-<5% SCI 2-EH C2;H315- ACETATE H411,- (ETHOXYMETHYL) 58567-11-6 261-332-1 01-2119971571-34 1-<5% SCI 2-SS 1B-EH C2; CYCLODODECANE H315-H317-H411,- ACETYL HEXAMETHYL 21145-77-7, 244-240-6, 1-<5% ATO 4-EH A1-EH C1; TETRALIN (AHTN) 1506-02-1 216-133-4 H302-H410,- 259-174-3, TETRAMETHYL 54464-57-2, ACETYLOCTAHYDRON 68155-66-8, 268-978-3, 01-2119489989-04-xxxx 1-<5% SCI 2-SS 1B-EH C1; APHTHALENES 68155-67-9 268-979-9, H315-H317-H410,- 915-730-3 4-TERT- BUTYLCYCLOHEXYL 32210-23-4 250-954-9 01-2119976286-24-xxxx 1-<5% SS 1B;H317,- ACETATE ETHYL 4940-11-8 225-582-5 1-<5% ATO 4;H302,- HYDROXYPYRONE GERANYL ACETATE 105-87-3 203-341-5 01-2119973480-35-xxxx 0.1-<1% SCI 2-SS 1-EH C3; H315-H317-H412,- LINALYL ACETATE 115-95-7 204-116-4 01-2119454789-19-xxxx 0.1-<1% SCI 2-SS 1B;H315- H317,- NERYL ACETATE 141-12-8 205-459-2 0.1-<1% SCI 2-SS 1B;H315- H317,- FL 3-SCI 2-SS 1B-AH LIMONENE 5989-27-5 227-813-5 0.1-<1% 1-EH A1-EH C1;H226- H304-H315-H317- H410,- CITRONELLOL 106-22-9 203-375-0 01-2119453995-23-xxxx 0.1-<1% SCI 2-EDI 2-SS 1B; H315-H317-H319,- COUMARIN 91-64-5 202-086-7 0.1-<1% ATO 4-SS 1B;H302- H317,- HEXYL SALICYLATE 6259-76-3 228-408-6 01-2119638275-36-xxxx 0.1-<1% SCI 2-SS 1-EH A1-EH C1;H315-H317-H410,- ALLYL ATO 4-EH A1-EH C2; CYCLOHEXYLOXYACE 68901-15-5 272-657-3 0.1-<1% H302-H400-H411,- TATE CIS-3-HEXENYL 67633-96-9 266-797-4 0.1-<1% SS 1B;H317,- METHYL CARBONATE Substances with Community workplace exposure limits: Name CAS EC % DIETHYL PHTHALATE 84-66-2 201-550-6 50-100% Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 4.2 Most important symptoms and effects, both acute and delayed May cause an allergic skin reaction. 3 Causes serious eye irritation. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation Do not eat, drink or smoke when using this product. 7.2 Conditions for safe storage, including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 3 7.3 Specific end use(s): Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: Ingredient CAS EC Description Value Long-term exposure limit (8-hour 5 TWA) (mg/m3) DIETHYL PHTHALATE 84-66-2 201-550-6 Short-term exposure limit (15- 10 minute) (mg/m3) 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Ensure adequate and ongoing ventilation is maintained in order to prevent build up of excessive vapour and to ensure occupational exposure limits are adhered to. If appropriate, and depending on your patterns and volumes of use, the following engineering controls may be required as additional protective measures: a) Isolate mixing rooms and other areas where this material is used or openly handled. Maintain these areas under negative air pressure relative to the rest of the plant. b) Employ the use of Personal protective equipment - an approved, properly fitted respirator with organic vapour cartridges or canisters and particulate filters. c) Use local exhaust ventilation around open tanks and other open sources of potential exposures in order to avoid excessive inhalation, including places where this material is openly weighed or measured. In addition, use general dilution ventilation of the work area to eliminate or reduce possible worker exposures. d) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. Section 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance: Clear colourless to pale yellow liquid Odour: Not determined Odour threshold: Not determined pH: Not determined Melting point / freezing point: Not determined Initial boiling point / range: Not determined Flash point: > 100 °C Evaporation rate: Not determined Flammability (solid, gas): Not determined Upper/lower flammability or explosive limits: Product does not present an explosion hazard 3 Vapour pressure: 0.03283911 mmHg Vapour density: Not determined Relative density: 1.0490 - 1.0530 Solubility(ies): Not determined Partition coefficient: n-octanol/water: Not determined Auto-ignition temperature: Not determined Decomposition temperature: Not determined Viscosity: Not determined Explosive properties: Not expected Oxidising properties: Not expected 9.2 Other information: None available Section 10. Stability and reactivity 10.1 Reactivity: Presents no significant reactivity hazard, by itself or in contact with water. 10.2 Chemical stability: Good stability under normal storage conditions. 10.3 Possibility of hazardous reactions: Not expected under normal conditions of use. 10.4 Conditions to avoid: Avoid extreme heat. 10.5 Incompatible materials: Avoid contact with strong acids, alkalis or oxidising agents. 10.6 Hazardous decomposition products: Not expected. Section 11. Toxicological information 11.1 Information on toxicological effects This mixture has not been tested as a whole for health effects. The health effects have been calculated using the methods outlined in Regulation (EC) No 1272/2008 (CLP). Acute Toxicity: Based on available data the classification criteria are not met. Acute Toxicity Oral >5000 Acute Toxicity Dermal Not Applicable Acute Toxicity Inhalation Not Available Skin corrosion/irritation: Based on available data the classification criteria are not met. Serious eye damage/irritation: Eye Damage / Irritation Category 2 Respiratory or skin sensitisation: Sensitization - Skin Category 1 3 Germ cell mutagenicity: Based on available data the classification criteria are not met. Carcinogenicity: Based on available data the classification criteria are not met. Reproductive toxicity: Based on available data the classification criteria are not met. STOT-single exposure: Based on available data the classification criteria are not met. STOT-repeated exposure: Based on available data the classification criteria are not met. Aspiration hazard: Based on available data the classification criteria are not met. Information about hazardous ingredients in the mixture Ingredient CAS EC LD50/ATE Oral LD50/ATE LC50/ATE LC50 Dermal Inhalation