APPLE FRAGRANCE

Hazard statements (CLP)

H317, H319, H411

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

Signal word

Warning

Hazard statements

H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects.

Additional information

None

Precautionary statements

P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

2.3 Other hazards

Hydrocarbon Concentration %: 0.000%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Eye Damage / Irritation Category 2 danger: Sensitization - Skin Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects. 2.2 Label elements Signal word: Warning Hazard statements: H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. H411, Toxic to aquatic life with long lasting effects. 4 Supplemental None Information: Precautionary P261, Avoid breathing vapour or dust. statements: P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: Other hazards: Hydrocarbon Concentration %: 0.000% Section 3. Composition / information on ingredients 3.2 Mixtures Contains: REACH Registration Classification for Name CAS EC % No. (CLP) 1272/2008 ALPHA,3,3- TRIMETHYLCYCLOHE 25225-08-5 246-735-2 20-<50% EH C2;H411,- XYLMETHYL FORMATE CIS-2-TERT- BUTYLCYCLOHEXYL 20298-69-5 243-718-1 01-2119970713-33-xxxx 20-<50% EH C2;H411,- ACETATE GAMMA 104-67-6 203-225-4 10-<20% EH C3;H412,- UNDECALACTONE HEXAMETHYLINDANO 1222-05-5 214-946-9 01-2119488227-29-xxxx 5-<10% EH A1-EH C1;H410,- PYRAN 2,6-DIMETHYL-7- 18479-58-8 242-362-4 5-<10% SCI 2-EDI 2;H315- OCTEN-2-OL H319,- PRENYL ACETATE 1191-16-8 214-730-4 5-<10% FL 3;H226,- DIETHYL MALONATE 105-53-3 203-305-9 1-<5% EDI 2;H319,- 4 ATO 3-ATD 3-EH A1- ALLYL HEPTANOATE 142-19-8 205-527-1 1-<5% EH C3;H301-H311- H400-H412,- 2,4-DIMETHYL-3- SCI 2-EDI 2-SS 1B-EH CYCLOHEXENE 68039-49-6 268-264-1 1-<5% C2;H315-H317-H319- CARBOXALDEHYDE H411,- VANILLIN 121-33-5 204-465-2 1-<5% EDI 2;H319,- Substances with Community workplace exposure limits: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 4.2 Most important symptoms and effects, both acute and delayed May cause an allergic skin reaction. Causes serious eye irritation. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 4 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation Do not eat, drink or smoke when using this product. 7.2 Conditions for safe storage, including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s): Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: Not Applicable 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Under normal conditions of use and where adequate ventilation is available to prevent build up of excessive vapour, this material should not require special engineering controls. However, in conditions of high or prolonged use, or high temperature or other conditions which increase exposure, the following engineering controls can be used to minimise exposure to personnel: a) Increase ventilation of the area with local exhaust ventilation. b) Personnel can use an approved, appropriately fitted respirator with organic vapour cartridge or canisters and particulate filters. c) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. 4 Section 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance: Clear colourless to pale yellow liquid Odour: Not determined Odour threshold: Not determined pH: Not determined Melting point / freezing point: Not determined Initial boiling point / range: Not determined Flash point: 76 °C Evaporation rate: Not determined Flammability (solid, gas): Not determined Upper/lower flammability or explosive limits: Product does not present an explosion hazard Vapour pressure: 0.38215567 mmHg Vapour density: Not determined Relative density: 0.9370 - 0.9410 Solubility(ies): Not determined Partition coefficient: n-octanol/water: Not determined Auto-ignition temperature: Not determined Decomposition temperature: Not determined Viscosity: Not determined Explosive properties: Not expected Oxidising properties: Not expected 9.2 Other information: None available Section 10. Stability and reactivity 10.1 Reactivity: Presents no significant reactivity hazard, by itself or in contact with water. 10.2 Chemical stability: Good stability under normal storage conditions. 10.3 Possibility of hazardous reactions: Not expected under normal conditions of use. 10.4 Conditions to avoid: Avoid extreme heat. 10.5 Incompatible materials: Avoid contact with strong acids, alkalis or oxidising agents. 4 10.6 Hazardous decomposition products: Not expected. Section 11. Toxicological information 11.1 Information on toxicological effects This mixture has not been tested as a whole for health effects. The health effects have been calculated using the methods outlined in Regulation (EC) No 1272/2008 (CLP). Acute Toxicity: Based on available data the classification criteria are not met. Acute Toxicity Oral >5000 Acute Toxicity Dermal >5000 Acute Toxicity Inhalation Not Available Skin corrosion/irritation: Based on available data the classification criteria are not met. Serious eye damage/irritation: Eye Damage / Irritation Category 2 Respiratory or skin sensitisation: Sensitization - Skin Category 1 Germ cell mutagenicity: Based on available data the classification criteria are not met. Carcinogenicity: Based on available data the classification criteria are not met. Reproductive toxicity: Based on available data the classification criteria are not met. STOT-single exposure: Based on available data the classification criteria are not met. STOT-repeated exposure: Based on available data the classification criteria are not met. Aspiration hazard: Based on available data the classification criteria are not met. Information about hazardous ingredients in the mixture Ingredient CAS EC LD50/ATE Oral LD50/ATE LC50/ATE LC50 Dermal Inhalation Route Not ALLYL HEPTANOATE 142-19-8 205-527-1 218 810 Not available available Refer to Sections 2 and 3 for additional information. Section 12. Ecological information 12.1 Toxicity: Toxic to aquatic life with long lasting effects. 12.2 Persistence and degradability: Not available 12.3 Bioaccumulative potential: Not available 12.4 Mobility in soil: Not available 12.5 Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, annex XIII. 12.6 Other adverse effects: Not available 4 Section 13. Disposal considerations 13.1 Waste treatment methods: Dispose of in accordance with local regulations. Avoid disposing into drainage systems and into the environment. Empty containers should be taken to an approved waste handling site for recycling or disposal. Section 14. Transport information 14.1 UN number: UN3082 14.2 UN Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (HEXAMETHYLINDANOPYRAN, ALPHA,3,3- TRIMETHYLCYCLOHEXYLMETHYL FORMATE) 14.3 Transport hazard class(es): 9 Sub Risk: - 14.4. Packing Group: III 14.5 Environmental hazards: This is an environmentally hazardous substance. 14.6 Special precautions for user: None additional 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable Section 15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture None additional 15.2 Chemical Safety Assessment A Chemical Safety Assessment has not been carried out for this product. Section 16. Other information Concentration % Limits: EH C2=16.84% EH C3=1.67% EH C4=33.01% EDI 2=76.34% EDI 2A=76. 34% SS 1=83.33% Total Fractional Values: EH C2=5.94 EH C3=59.86 EH C4=3.03 EDI 2=1.31 EDI 2A=1.31 SS 1=1. 20 Key to revisions: Concentration % Limits Product identifier SECTION 3: Composition/information on ingredients Total Fractional Values Key to abbreviations: Abbreviation Meaning ATD 3 Acute Toxicity - Dermal Category 3 ATO 3 Acute Toxicity - Oral Category 3 EDI 2 Eye Damage / Irritation Category 2 4 EH A1 Hazardous to the Aquatic Environment - Acute Hazard Category 1 EH C1 Hazardous to the Aquatic Environment - Long-term Hazard Category 1 EH C2 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 EH C3 Hazardous to the Aquatic Environment - Long-term Hazard Category 3 FL 3 Flammable Liquid, Hazard Category 3 H226 Flammable liquid and vapour. H301 Toxic if swallowed. H311 Toxic in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. P210