APPLE & CINNAMON FRAGRANCE

Hazard statements (CLP)

H314, H317, H411

Code

Statements

H314

Causes severe skin burns and eye damage

SECTION 2: Hazards identification

Signal word

Danger

Hazard statements

H314, Causes severe skin burns and eye damage. H317, May cause an allergic skin reaction. H411, Toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains CINNAMONITRILE, EUGENOL, METHYL CINNAMATE. May produce an allergic reaction.

Precautionary statements

P260, Do not breathe vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/330/331, If swallowed: Rinse mouth. Do not induce vomiting. P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P304/340, IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310, Immediately call a POISON CENTER or doctor/physician. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P391, Collect spillage. P405, Store locked up. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

Sensitisers declared on a CLP CINNAMONITRILE, EUGENOL, METHYL CINNAMATE Hazard Label: Hydrocarbon Concentration %: 0.000%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Skin Corrosion / Irritation Category 1B danger: Eye Damage / Irritation Category 1 Sensitization - Skin Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H314, Causes severe skin burns and eye damage. H317, May cause an allergic skin reaction. H411, Toxic to aquatic life with long lasting effects. 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Danger 20 Hazard statements: H314, Causes severe skin burns and eye damage. H317, May cause an allergic skin reaction. H411, Toxic to aquatic life with long lasting effects. Supplemental EUH208, Contains CINNAMONITRILE, EUGENOL, METHYL CINNAMATE. May produce an Information: allergic reaction. Precautionary P260, Do not breathe vapour or dust. statements: P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P301/330/331, If swallowed: Rinse mouth. Do not induce vomiting. P303/361/353, IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P304/340, IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310, Immediately call a POISON CENTER or doctor/physician. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P391, Collect spillage. P405, Store locked up. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: 2.3 Other hazards Other hazards: Sensitisers declared on a CLP CINNAMONITRILE, EUGENOL, METHYL CINNAMATE Hazard Label: Hydrocarbon Concentration %: 0.000% Section 3. Composition / information on ingredients 3.2 Mixtures Contains: 20 Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs CIS-2-TERT- oral: ATE = 4600 BUTYLCYCLOHEXYL 20298-69-5 243-718-1 01-2119970713-33-xxxx 20-<50% EH C2;H411,- mg/kg bw ACETATE METHYLCINNAMIC 101-39-3 202-938-8 10-<20% SS 1B-EH A1-EH C2; oral: ATE = 2050 ALDEHYDE H317-H400-H411,- mg/kg bw dermal: ATE = 5000 PHENYLPROPANOL 122-97-4 204-587-6 5-<10% SCI 1B-EDI 1;H314,- mg/kg bw-oral: ATE = 2275 mg/kg bw COUMARIN 91-64-5 202-086-7 5-<10% ATO 4-SS 1B-EH C3; oral: ATE = 500 mg/kg H302-H317-H412,- bw EUGENOL 97-53-0 202-589-1 1-<5% EDI 2-SS 1B;H317- oral: ATE = 2500 H319,- mg/kg bw SCI 2-EDI 2-SS 1A-EH oral: ATE = 2220 CINNAMAL 104-55-2 203-213-9 1-<5% C3;H315-H317-H319- mg/kg bw H412,- METHYL CINNAMATE 103-26-4 203-093-8 1-<5% SS 1B;H317,- oral: ATE = 2610 mg/kg bw DIETHYL MALONATE 105-53-3 203-305-9 1-<5% EDI 2;H319,- inhalation: ATE = 1.5 1885-38-7, 217-552-5, ATO 3-ATD 4-ATI 4-SS mg/l (dusts or mists)- CINNAMONITRILE 4360-47-8 224-441-5 1-<5% 1B;H301-H312-H317- dermal: ATE = 1100 H332,- mg/kg bw-oral: ATE = 100 mg/kg bw dermal: ATE = 2600 VANILLIN 121-33-5 204-465-2 1-<5% EDI 2;H319,- mg/kg bw-oral: ATE = 3300 mg/kg bw GAMMA 104-67-6 203-225-4 1-<5% EH C3;H412,- UNDECALACTONE Substances with Community workplace exposure limits: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs DIETHYL PHTHALATE 84-66-2 201-550-6 01-2119486682-27-xxxx 20-<50% -;-,- Substances that are endocrine disruptors according to Regulation (EU) 2017/2100 or Regulation (EU) 2018/605, greater than 0.1%: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Eye exposure: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin exposure: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with 20 water/shower. Ingestion: If swallowed: Rinse mouth. Do not induce vomiting. 4.2 Most important symptoms and effects, both acute and delayed Causes severe skin burns and eye damage. May cause an allergic skin reaction. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. Section 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation Do not eat, drink or smoke when using this product. 20 7.2 Conditions for safe storage, including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s): Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: Ingredient CAS EC Description Value UK Long-term exposure limit (8-hour TWA) 5 mg/m³ (mg/m3) DIETHYL PHTHALATE 84-66-2 201-550-6 UK Short-term exposure limit (15-minute) 10 mg/m³ (mg/m3) 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Ensure adequate and ongoing ventilation is maintained in order to prevent build up of excessive vapour and to ensure occupational exposure limits are adhered to. If appropriate, and depending on your patterns and volumes of use, the following engineering controls may be required as additional protective measures: a) Isolate mixing rooms and other areas where this material is used or openly handled. Maintain these areas under negative air pressure relative to the rest of the plant. b) Employ the use of Personal protective equipment - an approved, properly fitted respirator with organic vapour cartridges or canisters and particulate filters. c) Use local exhaust ventilation around open tanks and other open sources of potential exposures in order to avoid excessive inhalation, including places where this material is openly weighed or measured. In addition, use general dilution ventilation of the work area to eliminate or reduce possible worker exposures. d) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. Section 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Physical State/Colour: Clear colourless to pale yellow liquid Odour: Not determined Odour threshold: Not determined Melting point / freezing point: Not determined Boiling point or initial boiling point and boiling Not determined range: 20 Flammability: Not determined Lower and upper explosion limit: Not determined Flash point: 85 °C Auto-ignition temperature: Not determined Decomposition temperature: Not relevant pH: Not determined Kinematic viscosity: Not determined Solubility: Not determined Partition coefficient: n-octanol/water (log Not determined value): Vapour pressure: 0.07465028 mmHg Density and/or relative density: 1.0500 Relative vapour density: Not determined Particle characteristics: Not determined 9.2 Other information: None available Section 10. Stability and reactivity 10.1 Reactivity: Presents no significant reactivity hazard, by itself or in contact with water. 10.2 Chemical stability