1 MILLION FRAGRANCE

Hazard statements (CLP)

H317, H411

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

Signal word

Warning

Hazard statements

H317, May cause an allergic skin reaction. H411, Toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains (E)-1-(2,6,6-TRIMETHYL-1,3-CYCLOHEXADIEN-1-YL)-2-BUTEN-1-ONE, 3-(2H-1,3-BENZODIOXOL-5-YL)-2-METHYLPROPANAL, ALPHA-ISOMETHYL IONONE, ALPHA-PINENES, BETA-PINENES, CINNAMAL, GERANIOL, HEXYL CINNAMAL, ISOEUGENOL, LINALOOL, LINALYL ACETATE. May produce an allergic reaction.

Precautionary statements

P261, Avoid breathing vapour or dust. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

Sensitisers declared on a CLP (E)-1-(2,6,6-TRIMETHYL-1,3-CYCLOHEXADIEN-1-YL)-2- Hazard Label: BUTEN-1-ONE, 3-(2H-1,3-BENZODIOXOL-5-YL)-2- METHYLPROPANAL, ALPHA-ISOMETHYL IONONE, ALPHA-PINENES, BETA-PINENES, CINNAMAL, GERANIOL, HEXYL CINNAMAL, ISOEUGENOL, LINALOOL, LINALYL ACETATE Hydrocarbon Concentration %: 1.718%

2.1 Classification of the substance or mixture

Classification under Regulation (EC) No 1272/2008 Class and category of Sensitization - Skin Category 1 danger: Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H317, May cause an allergic skin reaction. H411, Toxic to aquatic life with long lasting effects. 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Warning Hazard statements: H317, May cause an allergic skin reaction. 44 H411, Toxic to aquatic life with long lasting effects. Supplemental EUH208, Contains (E)-1-(2,6,6-TRIMETHYL-1,3-CYCLOHEXADIEN-1-YL)-2-BUTEN-1-ONE, Information: 3-(2H-1,3-BENZODIOXOL-5-YL)-2-METHYLPROPANAL, ALPHA-ISOMETHYL IONONE, ALPHA-PINENES, BETA-PINENES, CINNAMAL, GERANIOL, HEXYL CINNAMAL, ISOEUGENOL, LINALOOL, LINALYL ACETATE. May produce an allergic reaction. Precautionary P261, Avoid breathing vapour or dust. statements: P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: 2.3 Other hazards Other hazards: Sensitisers declared on a CLP (E)-1-(2,6,6-TRIMETHYL-1,3-CYCLOHEXADIEN-1-YL)-2- Hazard Label: BUTEN-1-ONE, 3-(2H-1,3-BENZODIOXOL-5-YL)-2- METHYLPROPANAL, ALPHA-ISOMETHYL IONONE, ALPHA-PINENES, BETA-PINENES, CINNAMAL, GERANIOL, HEXYL CINNAMAL, ISOEUGENOL, LINALOOL, LINALYL ACETATE Hydrocarbon Concentration %: 1.718% Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs 259-174-3, 54464-57-2, TETRAMETHYL 54464-59-4, 259-175-9, SCI 2-SS 1B-EH C2; ACETYLOCTAHYDRON 68155-66-8, 268-978-3, 01-2119489989-04-xxxx 1-<5% H315-H317-H411,- APHTHALENES 268-979-9, 68155-67-9 915-730-3 44 ACETYL HEXAMETHYL 21145-77-7, 244-240-6, 1-<5% ATO 4-EH A1-EH C1; oral: ATE = 1000 TETRALIN (AHTN) 1506-02-1 216-133-4 H302-H410,- mg/kg bw 1,3,4,6,7,8- HEXAHYDRO- 4,6,6,7,8,8- 1222-05-5 214-946-9 01-2119488227-29-xxxx 1-<5% EH A1-EH C1;H410,- HEXAMETHYLINDENO [5,6-C]PYRAN (1S,2R,5S,7R,8R)-8- METHOXY-2,6,6,8- SS 1B-EH A1-EH C1; TETRAMETHYLTRICY 67874-81-1 267-510-5 1-<5% H317-H410,- CLO[5.3.1.0^{1,5}] UNDECANE 2,6-DIMETHYL-7- 18479-58-8 242-362-4 1-<5% SCI 2-EDI 2;H315- oral: ATE = 3600 OCTEN-2-OL H319,- mg/kg bw TETRAHYDRO- METHYL- 63500-71-0 405-040-6 01-0000015458-64-xxxx 1-<5% EDI 2;H319,- (METHYLPROPYL)- PYRAN-4-OL COUMARIN 91-64-5 202-086-7 1-<5% ATO 4-SS 1B-EH C3; oral: ATE = 500 mg/kg H302-H317-H412,- bw FL 3-SCI 2-SS 1B-AH LIMONENE 5989-27-5 227-813-5 1-<5% 1-EH A1-EH C3;H226- H304-H315-H317- H400-H412,- 5,5,6- EDI 2-REP 2-EH A1- TRIMETHYLBICYCLOH 3407-42-9 222-294-1 01-2119979583-21-xxxx 1-<5% EH C2;H319-H361- EPT-2- H400-H411,- YLCYCLOHEXANOL LINALOOL 78-70-6 201-134-4 01-2119474016-42-xxxx 0.1-<1% SCI 2-EDI 2-SS 1B; oral: ATE = 2790 H315-H317-H319,- mg/kg bw HEXYL CINNAMAL 101-86-0 202-983-3 0.1-<1% SS 1B-EH A1-EH C2; oral: ATE = 3100 H317-H400-H411,- mg/kg bw 3-(2H-1,3- SS 1B-REP 2-EH C2; oral: ATE = 3562 BENZODIOXOL-5-YL) 1205-17-0 214-881-6 01-2120740119-58-xxxx 0.1-<1% H317-H361-H411,- mg/kg bw -2-METHYLPROPANAL ALPHA-ISOMETHYL 127-51-5 204-846-3 0.1-<1% SS 1B-EH C2;H317- IONONE H411,- LINALYL ACETATE 115-95-7 204-116-4 01-2119454789-19-xxxx 0.1-<1% SCI 2-EDI 2-SS 1B; H315-H317-H319,- ALLYL ATO 4-EH A1-EH C1; oral: ATE = 682 mg/kg CYCLOHEXYLOXYACE 68901-15-5 272-657-3 0.1-<1% H302-H410,- bw TATE FL 3-SCI 2-SS 1B-AH BETA-PINENES 127-91-3 204-872-5 0.1-<1% 1-EH A1-EH C1;H226- H304-H315-H317- H410,- FL 3-ATO 4-SCI 2-SS ALPHA-PINENES 80-56-8 201-291-9 0.1-<1% 1B-AH 1-EH A1-EH oral: ATE = 500 mg/kg C1;H226-H302-H304- bw H315-H317-H410,- GERANIOL 106-24-1 203-377-1 01-2119552430-49-xxxx 0.1-<1% SCI 2-EDI 1-SS 1; oral: ATE = 3600 H315-H317-H318,- mg/kg bw ATD 4-SCI 2-EDI 2-SS dermal: ATE = 1100 CINNAMAL 104-55-2 203-213-9 0.1-<1% 1A-EH C3;H312-H315- mg/kg bw-oral: ATE = H317-H319-H412,- 2200 mg/kg bw (E)-1-(2,6,6- TRIMETHYL-1,3- 23726-93-4 245-844-2 01-2120105798-49-xxxx <0.1% SCI 2-SS 1A-EH C2; dermal: ATE = 2900 CYCLOHEXADIEN-1- H315-H317-H411,- mg/kg bw YL)-2-BUTEN-1-ONE ATO 4-ATD 4-ATI 4- Skin Sens. 1; H317; C ≥ 0.01%-inhalation: 97-54-1, 202-590-7, SCI 2-EDI 2-SS 1A- ATE = 1.5 mg/l (dusts ISOEUGENOL 5932-68-3, 227-678-2, <0.1% STO-SE 3(RI);H302- or mists)-dermal: ATE 5912-86-7 227-633-7 H312-H315-H317- H319-H332-H335,- = 1912 mg/kg bw-oral: ATE = 1500 mg/kg bw 44 Substances with Community workplace exposure limits: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs DIETHYL PHTHALATE 84-66-2 201-550-6 01-2119486682-27-xxxx 20-<50% -;-,- Substances that are endocrine disruptors according to Regulation (EU) 2017/2100 or Regulation (EU) 2018/605, greater than 0.1%: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: Flush immediately with water for at least 15 minutes. Contact physician if symptoms persist. Skin exposure: IF ON SKIN: Wash with plenty of soap and water. Ingestion: Rinse mouth with water and obtain medical attention. 4.2 Most important symptoms and effects, both acute and delayed May cause an allergic skin reaction. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. Section 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment.