InnoviBond Sprayable Insulation Adhesive Part A

Hazard statements (CLP)

H280, H315, H317, H320, H332, H334, H335, H373

Code

Statements

H280

Contains gas under pressure; may explode if heated

SECTION 2: Hazards identification

Hazard pictograms

CLASSIFICATION Acute Toxicity – Category 4 (Inhalation – mist) Eye Damage/Irritation – Category 2B Skin Corrosion/Irritation – Category 2 Skin Sensitization – Category 1B Respiratory Sensitization – Category 1 Specific Target Organ Toxicity, Single Exposure – Cateogry 3 irritating to respiratory system) Specific Target Organ Toxicity, Repeated Exposure – Category 2 (by inhalation) Gases under Pressure – Compressed Gas Simple Asphyxiant HAZARD STATEMENTS H280 Contains gas under pressure; may explode if heated. May displace oxygen and cause rapid suffocation H320 Causes eye irritation H315 Causes skin irritation H332 Harmful if inhaled H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled H317 May cause an allergic skin reaction H335 May cause respiratory irritation H373 May cause damage to organs (Olfactory organs) through prolonged or repeated exposure (inhalation) PRECAUTIONARY P280 Wear protective gloves STATEMENTS P271 Use only outdoors or in a well-ventilated area P260 Do not breathe dust/gas/mist/vapours P261 Avoid breathing mist P284 In case of inadequate ventilation wear respiratory protection P272 Contaminated work clothing should not be allowed out of the workplace P264 Wash with plenty of water and soap thoroughly after handling P312 Call a POISON CENTER or doctor/physician if you feel unwell P305+P351 IF IN EYES: Rinse cautiously with water for several P338 minutes. Remove contact lenses, if present and easy to do. Continue rinsing P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing P314 Get medical advice/attention if you feel unwell P303+P352 IF ON SKIN (or hair): Wash with plenty of soap and water P333+P311 If skin irritation or rash occurs: Call a POISON CENTER or doctor/physician P332+P313 If skin irritation occurs: Get medical advice/attention P362+P364 Take off contaminated clothing and wash it before reuse P337+P311 If eye irritation persists: Call a POISON CENTER or doctor/physician P410+P403 Protect from sunlight. Store in well-ventilated place P403+P233 Store in a well-ventilated place. Keep container tightly closed P405 Store locked up P501 Dispose of contents/container to hazardous or special waste collection point NFPA Health: 2 Flammability: 1 Reactivity: 1 HMIS Health: 2 Flammability: 1 Reactivity: 1 LABELING OF SPECIAL CONTAINS ISOCYANATES. INHALATION OF ISOCYANATE MISTS PREPARATIONS (GHS) OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST DISCOMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM EXPOSURE TO ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE SENSITIZATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPIRATORY REACTIONS INCLUDING WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING. ANIMAL TESTS INDICATE THAT SKIN CONTACT MAY PLAY A ROLE IN CAUSING RESPIRATORY SENSITIZATION. SECTION 3 – CHEMICAL COMPOSITION AND DATA ON COMPONENTS CHEMICAL NAME % (w/w) CAS NUMBER >= 25.0 - < Diphenylmethane-4,4'-diisocyanate (MDI) 101-68-6 50.0% Methylenediphenyl diisocyanate >= 3.0 - < 7.0% 26447-40-5 >= 25.0 - < P-MDI 75.0% 9016-87-9 Isocyanic acid, polymethylenepolyphenylene ester, polymer >= 1.0 - < 3.0% 57636-09-6 with .alpha.-hydro-.omega.-hyroxypoly (oxy-1,2-ethanediyl) 1,3-Diazetidine-2,4-dione, 1,3-bis[4- >= 0.3 - < 1.0% 17589-24-1 [(4isocyanatophenyl)methyl]phenyl] HFC-134A >= 3.0 - < 5.0% 811-97-2 ADDITIONAL INFORMATION: This product contains Nitrogen (>= 0.0 - < 1.0%), used for cylinder pressurization only.

2.1 Classification of the substance or mixture

Acute Toxicity – Category 4 (Inhalation – mist) Eye Damage/Irritation – Category 2B Skin Corrosion/Irritation – Category 2 Skin Sensitization – Category 1B Respiratory Sensitization – Category 1 Specific Target Organ Toxicity, Single Exposure – Cateogry 3 (irritating to respiratory system) Specific Target Organ Toxicity, Repeated Exposure – Category 2 (by inhalation) Gases under Pressure – Compressed Gas Simple Asphyxiant HAZARD STATEMENTS H280 Contains gas under pressure; may explode if heated. May displace oxygen and cause rapid suffocation. H320 Causes eye irritation. H315 Causes skin irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H373 May cause damage to organs (Olfactory organs) through prolonged or repeated exposure (inhalation). PRECAUTIONARY P280 Wear protective gloves. STATEMENTS P271 Use only outdoors or in a well-ventilated area. P260 Do not breathe dust/gas/mist/vapours. P261 Avoid breathing mist. P284 In case of inadequate ventilation wear respiratory protection. P272 Contaminated work clothing should not be allowed out of the workplace. P264 Wash with plenty of water and soap thoroughly after handling. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P305+P351 IF IN EYES: Rinse cautiously with water for several +P338 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing P314 Get medical advice/attention if you feel unwell. P303+P352 IF ON SKIN (or hair): Wash with plenty of soap and water P333+P311 If skin irritation or rash occurs: Call a POISON CENTER or doctor/physician. P332+P313 If skin irritation occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P337+P311 If eye irritation persists: Call a POISON CENTER or doctor/physician. P410+P403 Protect from sunlight. Store in well-ventilated place. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container to hazardous or special waste collection point. NFPA Health: 2 Flammability: 1 Reactivity: 1 HMIS Health: 2 Flammability: 1 Reactivity: 1