Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
General Information
Revision date
2015-05-13
Product name
Trimmer"s Choice A
CAS No.
101-68-8
1.2.1 Relevant identified uses
Polyurethane resin
Manufacturer Name
IBA, Inc
Icons in SDS
Company Information
company name
IBA, Inc
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
2.1 Classification of the substance or mixture
Health: Acute Toxicity (Inhalation), Category 4 Skin Irritation, Category 2 Eye Irritation, Category 2A Respiratory Sensitization, Category 1 Skin Sensitization, Category 1 Carcinogenicity, Category 2 Target Organ Toxicity (Single exposure), Category 3 Target Organ Toxicity (Repeated exposure), Category 2
Health hazards
Exclamation mark
Signal word
DANGER
Hazard statements
H332: Harmful if inhaled. H315: Causes skin irritation. H319: Causes serious eye irritation. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317: May cause an allergic skin reaction. H351: Suspected of causing cancer (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard). H335: May cause respiratory irritation. H373: May cause damage to organs ( state all organs affected, if known) through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard).
Prevention
P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P271: Use only outdoors or in a well-ventilated area. P285: In case of inadequate ventilation wear respiratory protection. P280: Wear protective gloves/protective clothing/eye protection/face protection. P264: Wash ... thoroughly after handling. P272: Contaminated work clothing should not be allowed out of the workplace.
Response
P304+P340 IF INHALED Remove person to fresh air and keep comfortable for breathing P312: Call a POISON CENTER/doctor/...if you feel unwell. P302+P352 IF ON SKIN Wash with plenty of water/ P333+P313 If skin irritation or rash occurs Get medical advice/attention P362: Take off contaminated clothing. P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do Continue rinsing. P337+P313 If eye irritation persists Get medical advice/attention
Storage
P403+P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up.
Disposal
P501: Dispose of contents/container to ... EMERGENCY OVERVIEW PHYSICAL APPEARANCE: Pale yellow liquid with a slight musty odor. IMMEDIATE CONCERNS: Harmful by inhalation. Use in well ventilated areas. Irritating to eyes, skin, and respiratory system. May cause sensitization by inhalation and skin contact. This product is a respiratory irritant and potential respiratory sensitizer. Repeated inhalation of vapour or aerosol at levels above the occupational exposure limit could cause respiratory sensitization. A hyper-reactive response to even minimal concentrations of diisocyanates may develop in sensitized persons. The onset of the respiratory symptoms may be delayed for several hours after exposure. Reacts slowly with water to produce carbon dioxide which may rupture closed containers. This reaction accelerates at higher temperatures. Do not breathe vapor or mist. Do not get on skin or clothing. Avoid contact with eyes. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling.
Potential health effects
EYES: Causes serious eye irritation. SKIN: Causes skin irritation. May cause an allergic skin reaction. INGESTION: May be harmful if swallowed. INHALATION: Harmful if inhaled. Inhalation at levels above the occupational exposure limit could cause respiratory sensitization and risk of serious damage to the respiratory system.
Medical Conditions Generally Aggravated by Exposure
Pre-existing eye, skin, and respiratory conditions may be aggravated by exposure
Principle Routes of Exposure
Eye and skin contact, inhalation of vapors, or accidental ingestion TARGET ORGAN STATEMENT Contains material which causes damage to the following organs upper respiratory tract SENSITIZATION: May cause allergic skin and respiratory reaction.