Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
14-27%
General Information
Revision date
2024-08-28
Product name
PE 45 A
Emergency telephone
+1 (800) 454-5530, 1-800-535-5053, 1-352-323-3500
Icons in SDS
Company Information
company name
HTS Chemical
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
GHS08 Health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Carc. 2 H351 Suspected of causing cancer. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. GHS07 Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2A H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H335 May cause respiratory irritation.
2.2 Label elements
The product is classified and labeled according to the Globally Harmonized System (GHS)
Hazard pictograms
GHS07 GHS08
Signal word
Danger
Hazardous Ingredients
4,4'-methylenediphenyl diisocyanate
Hazard statements
Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of causing cancer. May cause respiratory irritation. (Contd. of page 1) May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. [In case of inadequate ventilation] wear respiratory protection. If on skin: Wash with plenty of water. IF INHALED: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Call a poison center/doctor if you feel unwell. Specific treatment (see on this label). Get medical advice/attention if you feel unwell. Take off contaminated clothing and wash it before reuse. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. If experiencing respiratory symptoms: Call a poison center/doctor. Wash contaminated clothing before reuse. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system
NFPA ratings (scale 0 - 4) Health = 2 1 Fire = 1 2 0 Reactivity = 0 · HMIS-ratings (scale 0 - 4) HEALTH *2 Health = *2 FIRE 1 Fire = 1 REACTIVITY 0 Reactivity = 0
PBT Substances
Not applicable
vPvB Substances
Not applicable