Note: Ingredients listed on restricted chemical lists
EC/CAS
618-498-9/9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
50 - 100
General Information
Version
8.2
Revision date
2025-10-15
Product name
Hranipur 15
1.2.1 Relevant identified uses
Industrial/Professional use spec
supplier name
Hranipex Czech Republic k.s
Emergency telephone
0344 892 0111, +44 20 7188 7188
Icons in SDS
Company Information
company name
Hranipex Ltd
e-mail address of the competent person responsible for the Safety Data Sheet
cz-hranipex@hranipex.com, uk-hranipex@hranipex.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
According to Regulation (EC) No. 1272/2008 (CLP) Classification of the substance or mixture
Adverse physicochemical, human health and environmental effects
Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of causing cancer. May cause respiratory irritation. May cause damage to the respiratory system through prolonged or repeated exposure. Route of exposure: Inhalation
Hazard pictograms
GHS07 GHS08
Signal word
Danger
Contains
Diphenylmethanediisocyanate, isomers and homologues
Hazard statements
H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H332 - Harmful if inhaled. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H351 - Suspected of causing cancer. H373 - May cause damage to the respiratory system through prolonged or repeated exposure. Route of exposure: Inhalation.
Precautionary statements
P261 - Avoid breathing dust, fume, gas, mist, vapours, spray. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P302+P352 - IF ON SKIN: Wash with plenty of water. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 - Call a doctor if you feel unwell.
Supplemental label elements
EUH204 - Contains isocyanates. May produce an allergic reaction.
Additional information
As from 24 August 2023 adequate training is required before industrial or professional use.
Other hazards which do not result in classification
Persons suffering from asthma or eczema and persons who have chronic lung diseases, skin or respiratory allergies to isocyanates should not work with the material. Symptoms of excessive exposure to the respiratory tract to the product may persist for several hours. Dust, fumes and aerosols form a fundamental threat to the respiratory tract. This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute toxicity (inhalation:dust,mist) Category 4 H332 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Respiratory sensitisation, Category 1 H334 Skin sensitisation, Category 1 H317 Carcinogenicity, Category 2 H351 Specific target organ toxicity – Single exposure, Category 3, H335 Respiratory tract irritation Specific target organ toxicity – Repeated exposure, Category 2 H373 Full text of H- and EUH-statements: see section 16 Adverse physicochemical, human health and environmental effects Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of causing cancer. May cause respiratory irritation. May cause damage to the respiratory system through prolonged or repeated exposure. Route of exposure: Inhalation.