CQ123Series

Hazard statements (CLP)

H315, H317, H319, H360, H361, H361fd, H372, H411

Code

Statements

H315

Causes skin irritation

EU Classification

Regulation (EC) No 1272/2008 as amended

Health hazards

Skin corrosion/irritation Category 2 H315 - Causes skin irritation. Serious eye damage/eye irritation Category 2 H319 - Causes serious eye irritation. Skin sensitization Category 1 H317 - May cause an allergic skin reaction. Reproductive toxicity (fertility, the unborn Category 2 H361fd - Suspected of damaging child) fertility. Suspected of damaging the unborn child. Specific target organ toxicity - repeated Category 1 (liver, respiratory system) H372 - Causes damage to organs exposure (liver, respiratory system) through prolonged or repeated exposure.

Environmental hazards

Hazardous to the aquatic environment, Category 2 H411 - Toxic to aquatic life with long-term aquatic hazard long lasting effects.

2.2 Label elements

Label according to Regulation (EC) No. 1272/2008 as amended

Contains

1-vinylhexahydro-2H-azepin-2-one, 2-phenoxyethyl acrylate, 2-propenoic Acid, (5-ethyl-1,3-dioxan-5-yl)methyl ester, Diphenyl (2,4,6-trimethylbenzoyl) phosphine oxide

Signal word

Danger

Hazard statements

H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H361fd Suspected of damaging fertility. Suspected of damaging the unborn child. H372 Causes damage to organs (liver, respiratory system) through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects.

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection. P260 Do not breathe dust/fume/gas/mist/vapors/spray. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P270 Do not eat, drink or smoke when using this product. P264 Wash hands thoroughly after handling.

Response

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/attention. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P308 + P313 IF exposed or concerned: Get medical attention/advice. P312 Call a poison center/doctor if you feel unwell. P391 Collect spillage. P362 Take off contaminated clothing and wash before reuse.

Storage

P405 Store locked up.

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

Supplemental label elements

None

2.3 Other hazards

The classification of this mixture as a reproductive category 2 (H361) is based on the harmonized classification of diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide as mentioned in Annex VI of Regulation (EC) No.1272/2008. Recent test data for diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide presented on the EU REACH Dossier suggest that classification as reproductive category 1B (H360) is more suitable. This would lead to mixture classification of the product as reproductive category 1B (H360). The lead registrant has updated the REACH dossier and requested that the Swedish authority start the process of amending the harmonized classification. This SDS was updated according to guidance of the Swedish Chemicals Agency. Titanium dioxide is classified by IARC as a Group 2B carcinogen, meaning there is inadequate evidence in humans for the carcinogenicity of titanium dioxide, but there is sufficient evidence in experimental animals for the carcinogenicity of titanium dioxide. Exposure to titanium dioxide in this product is unlikely because it is a component of a liquid ink and is bound to other ink components. Potential routes of exposure to this product are skin and eye contact, ingestion, and inhalation.