Crude Oil

HollyFrontier Refining & Marketing LLC

Revision date : 2019-05-24

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GHS02 GHS07 GHS08
Health risk rating 5
Safety risk rating 3
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

8002-05-9

Name of the chemical

Petroleum Crude Oil

Concentration

N/A

Listed in

EC/CAS

91-20-3

Name of the chemical

Naphthalene,3

Concentration

N/A

General Information

Revision date

2019-05-24

Product name

Crude Oil

Product Synonyms

Sweet Crude Oil, Light Crude Oil, Heavy Crude Oil, Petroleum, Desalted Oil, Black Wax, Yellow wax

Manufacturer Name

HollyFrontier Refining & Marketing LLC

Emergency telephone

(800) 424-9300

Icons in SDS

Company Information

company name

HollyFrontier Refining & Marketing LLC

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H304, H319, H336, H350, H373

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

29 CFR 1910.1200) OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the : H225 FLAMMABLE LIQUIDS - Category 2 substance or mixture H319 EYE IRRITATION - Category 2A H350 CARCINOGENICITY - Category 1B H336 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 H373 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (blood system, liver, spleen, thymus) (oral) - Category 2 H373 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (blood system, liver, spleen, thymus) (dermal) - Category 2 H304

Aspiration hazard

Category 1

Ingredient(s) with unknown acute toxicity

3% toxicity: 100%

Signal word

Danger

Hazard statements

H225 - Highly flammable liquid and vapor. H319 - Causes serious eye irritation. H350 - May cause cancer. H304 - May be fatal if swallowed and enters airways. H336 - May cause drowsiness or dizziness. H373 - May cause damage to organs through prolonged or repeated exposure if swallowed. (blood system, liver, spleen, thymus) May cause damage to organs through prolonged or repeated exposure in contact with skin. (blood system, liver, spleen, thymus)

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Wash hands thoroughly after handling. Product may release hydrogen sulfide: a specific assessment of inhalation risks from the presence of hydrogen sulfide in tank headspaces, confined spaces, product residue, tank waste and waste water and unintentional releases should be made to help determine controls appropriate to local circumstances.

Response

Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

Storage

Store in a well-ventilated place. Keep cool.

Disposal

Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and elements receiving equipment. These alone may be insufficient to remove static electricity. Avoid contact with skin and clothing. Wash thoroughly after handling.

2.3 Other hazards

Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor may cause flash fire or explosion. Prolonged or repeated contact may dry skin and cause irritation.

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