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Hazard statements (CLP)

H228, H302, H319

Code

Statements

H228

Flammable solid

SECTION 2: Hazards identification

GHS Ratings Health studies have shown that individual sensitivities vary from person to person. As a precaution, exposure to vapors, liquids, mists, or fumes should be minimized IARC: In March 1987, the International Agency for Research on Cancer (IARC) classified extracts of steam and air refined bitumens (such as cutback asphalts) as possibly carcinogenic to humans (Group 2B). This classification was based on a combined evaluation of published human and animal studies. IARC concluded that the human studies did not provide adequate evidence that extracts of steam and air-refined bitumens caused cancer in humans. No epidemiological study of workers exposed only to bitumens is avail- able. The 2B classification was substantially based on experimental animal studies. ACGIH, NTP, OSHA: No components listed as carcinogens hydrocarbons, which have been shown. WARNING Hydrogen sulfide (H2S), an extremely flammable, colorless, highly toxic gas, is emitted from heated (above 450ºF) as- phalt and may accumulate in storage tanks and bulk transport compartments. Prolonged breathing (greater than 1 hour) of concen- trations of H2S around 50 ppm can produce eye and respiratory tract (mouth, nose and throat) irritation, and at high concentration (around 100 ppm) can result in rapid unconsciousness and death. Since the sense of smell becomes rapidly insensitive to H2S, its odor cannot be relied upon as an indicator of its concentration. Always use caution when working around closed bulk containers of asphalt. Use ventilation or work upwind from sources of fumes or vapors. Use supplied air respirators or self-contained breathing ap- paratus if the PEL or TLV for H2S is exceeded. Hazardous Material National Fire Protection Information System (HMIS) Association (NFPA) Flammability HMIS & NFPA Hazard Rating Legend Health 1

Health hazards

Flammability 2 1 0 = INSIGNIFICANT Health

Physical hazards

Instability 0 1 = SLIGHT 0 2 = MODERATE Personal Protection X 3 = HIGH Special

Potential health effects

Eyes: Asphalt components, fibers and fillers can cause severe irritation, redness, tearing and blurred vision. Skin: Possible mechanical irritant. Inhalation: Possible respiratory irritant. Ingestion: An irritant. Carcinogenicity: IARC classifies extracts of steam and air refined bitumens (such as cutback asphalts) as possibly carcinogenic to humans (Group 2B).

Classifications

Flammable solid: 2 Oral Toxicity: Acute 4 Serious eye irritation: 2

Hazard statements

H228 Flammable solid H302 Harmful if swallowed H319 Causes serious eye irritation

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking P240 Ground/bond container and receiving equipment P241 Use explosion-proof electrical/ventilating/lighting/…/equipment P264 Wash hands thoroughly after handling P270 Do not eat, drink or smoke when using this product P280 Wear protective gloves/protective clothing/eye protection/face protection P330 Rinse mouth P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 IF eye irritation persists: Get medical advice/attention P370+P378 In case of fire: Use foam, carbon dioxide, dry chemical or water for extinction P501 Dispose of contents/container to local regulations