TH-TYPE F

Hazard statements (CLP)

H225, H313, H315, H319, H335, H370, H372, H373, H401

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Flammable Liquids, Category 2 Acute Toxicity: Skin, Category 5 Skin Corrosion/Irritation, Category 2 Serious Eye Damage/Eye Irritation, Category 2 Target Organ Systemic Toxicity (single exposure), Category 1 Target Organ Systemic Toxicity (single exposure), Category 3 Target Organ Systemic Toxicity (repeated exposure), Category 1 Target Organ Systemic Toxicity (repeated exposure), Category 2

Signal word

Danger

Hazard statements

H225: Highly flammable liquid and vapor. H313: May be harmful in contact with skin. H315: Causes skin irritation. H319: Causes serious eye irritation. H370: Causes damage to organs. H335: May cause respiratory irritation. H372: Causes damage to organs through prolonged or repeated exposure. H373: May cause damage to {organs} through prolonged or repeated exposure. H401: Toxic to aquatic life. H370: Causes damage to organs .

Precautionary statements

P233: Keep container tightly closed. P210: Keep away from {heat/sparks/open flames/hot surfaces}. - No smoking. P280: Wear {protective gloves/protective clothing/eye protection/face protection}. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting/ equipment. P243: Take precautionary measures against static discharge. P242: Use only non-sparking tools. P264: Wash {hands} thoroughly after handling. P362+364: Take off contaminated clothing and wash it before reuse. P260: Do not breathe {dust/fume/gas/mist/vapours/spray}. P270: Do not eat, drink or smoke when using this product. P261: Avoid breathing {dust/fume/gas/mist/vapours/spray}. P271: Use only outdoors or in a well-ventilated area. P273: Avoid release to the environment. P241: Use explosion-proof electrical/ventilating/lighting/{.../} equipment.

Response

P370+378: In case of fire, use dry chemical, CO2, water splay, fog or form to extinguish. P303+361+353 IF ON SKIN (or hair) Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P312: Call a {POISON CENTER/doctor} if you feel unwell. P302+352 IF ON SKIN Wash with plenty of soap and water P321: Specific treatment {see Section 4 on this label}. P332+313: If skin irritation occurs, get medical advice/attention. P305+351+338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+313: If eye irritation persists, get medical advice/attention. P304+340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. P314: Get medical attention/advice if you feel unwell. P321: Specific treatment {see ... on this label}.

Storage

P403+235: Store in cool/well-ventilated place. P501: Dispose of contents/container to listed in 40 CFR Parts 261. P405: Store locked up. P403+233: Store container tightly closed in well-ventilated place - if product is as volatile as to generate hazardous atmosphere. P501: Dispose of contents/container to {...}. Flammability Hazard Rating System: Instability HEALTH 2 3 FLAMMABILITY 3 2 0 PHYSICAL 0 Health PPE B HMIS: NFPA: Special Hazard

Potential health effects

Chronic: May cause reproductive and fetal effects. Laboratory experiments have shown (Acute and Chronic): mutagenic effects. Animal studies have reported the development of tumors. Prolonged exposure may cause liver, kidney, and heart damage. Chronic: Prolonged or repeated skin contact may cause defatting and dermatitis. Chronic exposure may cause liver damage. Chronic: Prolonged or repeated skin contact may cause defatting and dermatitis. Inhalation: nhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation. May cause narcotic effects in high concentration. Vapors may cause dizziness or suffocation. Inhalation of vapor may cause respiratory tract irritation. May cause effects similar to those described for ingestion. Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. May cause narcotic effects in high concentration. Causes upper respiratory tract irritation. Inhalation of vapors may cause drowsiness and dizziness. Skin Contact: Causes moderate skin irritation. May cause cyanosis of the extremities. May cause moderate skin irritation. Prolonged and/or repeated contact may cause defatting of the skin and dermatitis. May cause irritation with pain and stinging, especially if the skin is abraded. Isopropanol has a low potential to cause allergic skin reactions; however, rare cases of allergic contact dermatitis have been reported. May be absorbed through intact skin. Dermal absorption has been considered toxicologically insignificant. The cases of deep coma associated with skin contact are thought to be a consequence of gross isopropanol vapor inhalation in rooms with inadequate ventilation, rather than being attributable to percutaneous absorption of isopropanol per se. Eye Contact: Causes severe eye irritation. May cause painful sensitization to light. May cause chemical conjunctivitis and corneal damage. May cause moderate eye irritation. May result in corneal injury. Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury. May cause transient corneal injury. In the eyes of a rabbit, 0.1 ml of a rabbit, 0.1 ml of 70% isopropyl alcohol caused conjunctivitis, isopropyl alcohol caused conjun ctivitis, iritis, and corneal opacity. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause systemic toxicity with acidosis. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. Aspiration of material into the lungs may cause chemical pneumonitis, which may be fatal. The probable oral lethal dose in humans is 240 ml (2696 mg/kg), but ingestion of only 20 ml (224 mg/kg) has, but in gestion of only {20 ml (224 mg/kg)} has caused poisoning.