TH-83 Make-up Ink

Hazard statements (CLP)

H225, H301, H311, H319, H331, H370

Code

Statements

H225

Highly Flammable liquid and vapour

CLP CLASSIFICATION

2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP]:]] Flammable Liquids, Category 2 Serious Eye Damage/Eye Irritation, Category 2 Specific Target Organ Toxicity (single exposure), Category 1

2.2 Label elements

2.2.1 Labeling according to Regulation (EC) No 1272/2008 [CLP]:

Signal word

Danger

Hazard statements

H225 - Highly flammable liquid and vapor. H331 - Toxic if inhaled. H301 - Toxic if swallowed. H311 - Toxic in contact with skin. H319 - Causes serious eye irritation. H370 - Causes damage to organs

Precautionary statements

P233 - Keep container tightly closed. P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting/.../ equipment. P243 - Take precautionary measures against static discharge. P242 - Use only non-sparking tools. P271 - Use only outdoors or in a well-ventilated area. P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P264 - Wash hands thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P361+364 - Take off immediately all contaminated clothing and wash it before reuse. P260 - Do not breathe dust/fume/gas/mist/vapours/spray.

Response

P370+378 - In case of fire, use ... to extinguish. P303+361+353 - IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P304+340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P311 - Call a POISON CENTER/doctor/.... P322 - Specific measures see ... on this label. P301+310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P330 - Rinse mouth. P321 - Specific treatment see ... on this label. P302+352 - IF ON SKIN: Wash with plenty of soap and water. P312 - Call a POISON CENTER/doctor/... if you feel unwell. P305+351+338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+313 - If eye irritation persists, get medical advice/attention.

Storage

P403+235 - Store in cool/well-ventilated place. P501 - Dispose of contents/container to .... P405 - Store locked up. P403+233 - Store container tightly closed in well-ventilated place - if product is as volatile as to generate hazardous atmosphere.

Potential health effects

Ingredient CAS# 78-93-3, Methyl ethyl ketone: Chronic: Chronic inhalation may cause effects similar to those of acute inhalation. Prolonged or repeated skin contact may cause defatting and dermatitis. Animal studies have reported that fetal effects/abnormalities may occur when maternal toxicity is seen. Chronic overexposure to vapors may cause lung damage. 2.3.1 Inhalation: Ingredient CAS# 78-93-3, Methyl ethyl ketone: Causes respiratory tract irritation. Inhalation of vapors may cause drowsiness and dizziness. May cause central nervous system effects such as nausea and headache. Neurobehavioural effects of exposure to MEK (200 ppm for 4 hrs) were studied with 137 volunteers. There were no statistically significant effects observed in biochemical, psychomotor, sensorimotor and psychological tests. 2.3.2 Skin Contact: Ingredient CAS# 78-93-3, Methyl ethyl ketone: May be absorbed through the skin in harmful amounts. Repeated or prolonged exposure may cause drying and cracking of the skin. Only one human case of skin sensitization was located. Negative results were obtained in an animal test; MEK did not produce skin sensitization in the mouse ear thickness test. 2.3.3 Eye Contact: Ingredient CAS# 78-93-3, Methyl ethyl ketone: Causes eye irritation. Vapors may cause eye irritation. Animal evidence suggests that MEK is a moderate to severe eye irritant. 2.3.4 Ingestion: Ingredient CAS# 78-93-3, Methyl ethyl ketone: May cause irritation of the digestive tract. Possible aspiration hazard. May cause central nervous system depression. Animal evidence suggests that MEK can be aspirated (inhaled) into the lungs during ingestion or vomiting.