Note: Ingredients listed on restricted chemical lists
EC/CAS
1336-21-6
Name of the chemical
ammonium hydroxide
Concentration
N/A
EC/CAS
215-647-6
Name of the chemical
Ammonia
Concentration
N/A
General Information
Revision date
2013-11-08
Product name
TH-78 Make-up Ink
Icons in SDS
Company Information
company name
Hitachi America, Ltd
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H305, H314, H319, H335
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
CLP CLASSIFICATION
2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP]:]] Flammable Liquids, Category 2 Serious Eye Damage/Eye Irritation, Category 2A Target Organ Systemic Toxicity (single exposure), Category 3
2.2 Label elements
2.2.1 Labeling according to Regulation (EC) No 1272/2008 [CLP]:
Signal word
Danger
Hazard statements
H225 - Highly flammable liquid and vapor. H319 - Causes serious eye irritation. H335 - May cause respiratory irritation. H314 - Causes severe skin burns and eye damage. H305 - May be harmful if swallowed and enters airways.
Precautionary statements
P233 - Keep container tightly closed. P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting/.../ equipment. P243 - Take precautionary measures against static discharge. P242 - Use only non-sparking tools. P264 - Wash hands thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P260 - Do not breathe dust/fume/gas/mist/vapours/spray.
Response
P370+378 - In case of fire, use ... to extinguish. P303+361+353 - IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P305+351+338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+313 - If eye irritation persists, get medical advice/attention. P309+311 - Call a POISON CENTER or doctor/physician if exposed or you feel unwell. P304+340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P363 - Wash contaminated clothing before reuse. P301+330+331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P310 - Immediately call a POISON CENTER/doctor/.... P321 - Specific treatment see ... on this label. P301+310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331 - Do NOT induce vomiting.
Storage
P403+235 - Store in cool/well-ventilated place. P501 - Dispose of contents/container to .... P405 - Store locked up. P403+233 - Store container tightly closed in well-ventilated place - if product is as volatile as to generate hazardous atmosphere.
Potential health effects
Chronic: May cause reproductive and fetal effects. Laboratory experiments have shown mutagenic effects. Animal studies have reported the development of tumors. Prolonged exposure may cause liver, kidney, and heart damage. Prolonged or repeated skin contact may cause dermatitis. Chronic inhalation may cause effects similar to those of acute inhalation. Matsushita et al. exposed human volunteers 6 hours/day for 6 days at 500 ppm acetone and found hematologic changes including significantly increased leukocyte and eosinophil counts and decreased neutrophil phagocytic activity. 2.3.1 Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation. May cause narcotic effects in high concentration. Vapors may cause dizziness or suffocation. May cause motor incoordination and speech abnormalities. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. 2.3.2 Skin Contact: Causes moderate skin irritation. May cause cyanosis of the extremities. May be absorbed through the skin. Repeated or prolonged exposure may cause drying and cracking of the skin. Causes burns. Skin Absorption: May be harmful if absorbed through the skin. 2.3.3 Eye Contact: Causes severe eye irritation. May cause painful sensitization to light. May cause chemical conjunctivitis and corneal damage. Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury. Vapors may cause eye irritation. Causes burns. Lachrymator. 2.3.4 Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause systemic toxicity with acidosis. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. May cause irritation of the digestive tract. Aspiration of material into the lungs may cause chemical pneumonitis, which may be fatal. May be harmful if swallowed.