TH-78 Make-up Ink

Hitachi America, Ltd

Revision date : 2013-11-08

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GHS02 GHS05 GHS07
Health risk rating 2
Safety risk rating 3
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

64-17-5

Name of the chemical

Ethanol

Concentration

N/A

EC/CAS

67-64-1

Name of the chemical

acetone

Concentration

N/A

EC/CAS

1336-21-6

Name of the chemical

ammonium hydroxide

Concentration

N/A

EC/CAS

215-647-6

Name of the chemical

Ammonia

Concentration

N/A

General Information

Revision date

2013-11-08

Product name

TH-78 Make-up Ink

Icons in SDS

Company Information

company name

Hitachi America, Ltd

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H305, H314, H319, H335

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

CLP CLASSIFICATION

2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP]:]] Flammable Liquids, Category 2 Serious Eye Damage/Eye Irritation, Category 2A Target Organ Systemic Toxicity (single exposure), Category 3

2.2 Label elements

2.2.1 Labeling according to Regulation (EC) No 1272/2008 [CLP]:

Signal word

Danger

Hazard statements

H225 - Highly flammable liquid and vapor. H319 - Causes serious eye irritation. H335 - May cause respiratory irritation. H314 - Causes severe skin burns and eye damage. H305 - May be harmful if swallowed and enters airways.

Precautionary statements

P233 - Keep container tightly closed. P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting/.../ equipment. P243 - Take precautionary measures against static discharge. P242 - Use only non-sparking tools. P264 - Wash hands thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P260 - Do not breathe dust/fume/gas/mist/vapours/spray.

Response

P370+378 - In case of fire, use ... to extinguish. P303+361+353 - IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P305+351+338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+313 - If eye irritation persists, get medical advice/attention. P309+311 - Call a POISON CENTER or doctor/physician if exposed or you feel unwell. P304+340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P363 - Wash contaminated clothing before reuse. P301+330+331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P310 - Immediately call a POISON CENTER/doctor/.... P321 - Specific treatment see ... on this label. P301+310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331 - Do NOT induce vomiting.

Storage

P403+235 - Store in cool/well-ventilated place. P501 - Dispose of contents/container to .... P405 - Store locked up. P403+233 - Store container tightly closed in well-ventilated place - if product is as volatile as to generate hazardous atmosphere.

Potential health effects

Chronic: May cause reproductive and fetal effects. Laboratory experiments have shown mutagenic effects. Animal studies have reported the development of tumors. Prolonged exposure may cause liver, kidney, and heart damage. Prolonged or repeated skin contact may cause dermatitis. Chronic inhalation may cause effects similar to those of acute inhalation. Matsushita et al. exposed human volunteers 6 hours/day for 6 days at 500 ppm acetone and found hematologic changes including significantly increased leukocyte and eosinophil counts and decreased neutrophil phagocytic activity. 2.3.1 Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation. May cause narcotic effects in high concentration. Vapors may cause dizziness or suffocation. May cause motor incoordination and speech abnormalities. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May be harmful if inhaled. 2.3.2 Skin Contact: Causes moderate skin irritation. May cause cyanosis of the extremities. May be absorbed through the skin. Repeated or prolonged exposure may cause drying and cracking of the skin. Causes burns. Skin Absorption: May be harmful if absorbed through the skin. 2.3.3 Eye Contact: Causes severe eye irritation. May cause painful sensitization to light. May cause chemical conjunctivitis and corneal damage. Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury. Vapors may cause eye irritation. Causes burns. Lachrymator. 2.3.4 Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause systemic toxicity with acidosis. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. May cause irritation of the digestive tract. Aspiration of material into the lungs may cause chemical pneumonitis, which may be fatal. May be harmful if swallowed.

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