JP-K72u

Hazard statements (CLP)

H225, H303, H305, H315, H319, H333, H335, H370, H371, H372

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Flammable Liquids, Category 2 Serious Eye Damage/Eye Irritation, Category 2 Acute Toxicity: Oral, Category 5 Acute Toxicity: Inhalation, Category 5 Skin Corrosion/Irritation, Category 2 Target Organ Systemic Toxicity (single exposure), Category 1 Target Organ Systemic Toxicity (single exposure), Category 2 Target Organ Systemic Toxicity (single exposure), Category 3 Target Organ Systemic Toxicity (repeated exposure), Category 1 Aspiration Toxicity, Category 2

Signal word

Danger

Hazard statements

H225: Highly flammable liquid and vapor. H319: Causes serious eye irritation. H303: May be harmful if swallowed. H333: May be harmful if inhaled. H315: Causes skin irritation. H370: Causes damage to organs. H371: May cause damage to organs. H335: May cause respiratory irritation. H372: Causes damage to organs through prolonged or repeated exposure. H305: May be harmful if swallowed and enters airways.

Precautionary statements

P233: Keep container tightly closed. P210: Keep away from {heat/sparks/open flames/hot surfaces}. - No smoking. P280: Wear {protective gloves/protective clothing/eye protection/face protection}. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment. P243: Take precautionary measures against static discharge. P242: Use only non-sparking tools. P264: Wash {hands} thoroughly after handling. P260: Do not breathe {dust/fume/gas/mist/vapours/spray}. P270: Do not eat, drink or smoke when using this product. P261: Avoid breathing {dust/fume/gas/mist/vapours/spray}. P271: Use only outdoors or in a well-ventilated area.

Response

P370+378: In case of fire, use dry chemical, CO2, water splay, fog or form to extinguish. P303+361+353 IF ON SKIN (or hair) Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P305+351+338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+313: If eye irritation persists, get medical advice/attention. P312: Call a {POISON CENTER/doctor} if you feel unwell. P302+352 IF ON SKIN Wash with plenty of soap and water P321: Specific treatment {see Section 4 on this SDS}. P332+313: If skin irritation occurs, get medical advice/attention. P362: Take off contaminated clothing. P307+311 IF exposed Call a POISON CENTER or doctor/physician P309+311: Call a POISON CENTER or doctor/physician if exposed or you feel unwell. P304+340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. P314: Get medical attention/advice if you feel unwell. P301+310 IF SWALLOWED Immediately call a POISON CENTER or doctor/physician P331: Do NOT induce vomiting.

Storage

P403+235: Store in cool/well-ventilated place. P501: Dispose of contents/container listed in 40 CFR Parts 261. P405: Store locked up. P403+233: Store container tightly closed in well-ventilated place - if product is as volatile as to generate hazardous atmosphere. Flammability Hazard Rating System: Instability HEALTH 2 3 FLAMMABILITY 3 2 0 PHYSICAL 0 Health PPE B HMIS: NFPA: Special Hazard

Potential health effects

Chronic: Chronic inhalation may cause effects similar to those of acute inhalation. (Acute and Chronic): Prolonged or repeated skin contact may cause defatting and dermatitis. Animal studies have reported that fetal effects/abnormalities may occur when maternal toxicity is seen. Chronic overexposure to vapors may cause lung damage. Inhalation: Causes respiratory tract irritation. Inhalation of vapors may cause drowsiness and dizziness. May cause central nervous system effects such as nausea and headache. Neurobehavioural effects of exposure to MEK (200 ppm for 4 hrs) were studied with 137 volunteers. There were no statistically significant effects observed in biochemical, psychomotor, sensorimotor and psychological tests. Skin Contact: May be absorbed through the skin in harmful amounts. Repeated or prolonged exposure may cause drying and cracking of the skin. Only one human case of skin sensitization was located. Negative results were obtained in an animal test; MEK did not produce skin sensitization in the mouse ear thickness test. Eye Contact: Causes eye irritation. Vapors may cause eye irritation. Animal evidence suggests that MEK is a moderate to severe eye irritant. Ingestion: May cause irritation of the digestive tract. Possible aspiration hazard. May cause central nervous system depression. Animal evidence suggests that MEK can be aspirated (inhaled) into the lungs during ingestion or vomiting.