HUS4-MAX, B

Hazard statements (CLP)

H242, H317, H319, H400, H410

Code

Statements

H242

Heating may cause a fire

SECTION 2: Hazards identification

Classification of the hazardous chemical Classification according to Industry Code of Practice on chemicals classification and hazard communication (2014) Org. Perox. F H242 Eye Irrit. 2 H319 Skin Sens. 1 H317 Aquatic Acute 1 H400 Aquatic Chronic 1 H410

2.2 Label elements

Labelling according to Industry Code of Practice on chemicals classification and hazard communication (2014)

Hazard pictograms

(GHS MY) GHS02 GHS07 GHS09

Signal word

(GHS MY) Warning

Contains

dibenzoyl peroxide

Hazard statements

(GHS MY) H242 - Heating may cause a fire H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H410 - Very toxic to aquatic life with long lasting effects

Precautionary statements

MY) P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking P280 - Wear eye protection, protective clothing, protective gloves P262 - Do not get in eyes, on skin, or on clothing P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P302+P352 - IF ON SKIN: Wash with plenty of soap and water P337+P313 - If eye irritation persists: Get medical advice/attention P333+P313 - If skin irritation or rash occurs: Get medical advice/attention 0

Other hazards which do not result in classification

No additional information available SECTION 3: Composition and information of the ingredients of the hazardous chemical

2.1 Classification of the substance or mixture

Classification according to Industry Code of Practice on chemicals classification and hazard communication (2014) Org. Perox. F H242 Eye Irrit. 2 H319 Skin Sens. 1 H317 Aquatic Acute 1 H400 Aquatic Chronic 1 H410 2.2. Label elements Labelling according to Industry Code of Practice on chemicals classification and hazard communication (2014) Hazard pictograms (GHS MY) GHS02 GHS07 GHS09 Signal word (GHS MY) Warning Contains dibenzoyl peroxide Hazard statements (GHS MY) H242 - Heating may cause a fire H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H410 - Very toxic to aquatic life with long lasting effects Precautionary statements (GHS MY) P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking P280 - Wear eye protection, protective clothing, protective gloves P262 - Do not get in eyes, on skin, or on clothing P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P302+P352 - IF ON SKIN: Wash with plenty of soap and water P337+P313 - If eye irritation persists: Get medical advice/attention P333+P313 - If skin irritation or rash occurs: Get medical advice/attention 0 2.3. Other hazards not contributing to the classification No additional information available SECTION 3: Composition and information of the ingredients of the hazardous chemical 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % dibenzoyl peroxide (CAS-No.) 94-36-0 10 – 25 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general Take off immediately all contaminated clothing. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation Remove person to fresh air and keep comfortable for breathing. Allow affected person to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact Wash contaminated clothing before reuse. Wash with plenty of water/…. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion If swallowed, seek medical advice immediately and show this container or label. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects after skin contact May cause an allergic skin reaction. Symptoms/effects after eye contact Causes serious eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed Other medical advice or treatment Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Water spray. Carbon dioxide. Dry powder. Alcohol-resistant foam. Unsuitable extinguishing media Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard May form flammable vapour-air mixtures. May decompose violently at elevated temperatures or in a fire. Burns vigorously. Insoluble in water. Contact with alkalis or acids may cause dangerous decomposition. The products of combustion or self-accelerating decomposition may be toxic by inhalation. Will float and can be reignited on water surface. Explosion hazard Vapours may form explosive mixture with air. Reactivity in case of fire Decomposition products may be a hazard to health. Hazardous decomposition products in case of fire Formation of toxic gases is possible during heating or in case of fire. Corrosive vapours. Thermal decomposition can lead to the release of irritating gases and vapours. Firefighting instructions Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. Protection during firefighting Self-contained breathing apparatus. Do not enter fire area without proper protective equipment, including respiratory protection. EAC code 2W SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures Spilled material may present a slipping hazard. 6.1.1. For non-emergency personnel Protective equipment Wear recommended personal protective equipment. Emergency procedures Evacuate unnecessary personnel. No flames, no sparks. Eliminate all sources of ignition. Explosive vapour/air mixtures may be formed. 6.1.2. For emergency responders Protective equipment Use personal protective equipment as required. Equip cleanup crew with proper protection. Emergency procedures Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment Collect spillage. Methods for cleaning up Stop leak without risks if possible. Use non-sparking tools. Absorb and/or contain spill with inert material, then place in suitable container. This material and its container must be disposed of in a safe way, and as per local legislation. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Wear personal protective equipment. Avoid contact with skin and eyes. Avoid breathing dust, vapours. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Prevent the build-up of electrostatic charge. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Hygiene measures Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage, including any incompatibilities Technical measures Comply with applicable regulations. Storage conditions Keep container tightly closed. Keep cool. Protect from sunlight. Avoid contact with : Air. Store away from other materials. Expiry date: See date printed on box and capsule. Do not use if expiry date has been exceeded!. Incompatible materials Strong acids. Strong bases. Activator. reducing agents. solid salts and solutions containing heavy metals. Heat and ignition sources Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Storage temperature -20 – 25 °C SECTION 8: Exposure controls/personal protection 8.1. Control parameters HUS4-MAX, B Malaysia - Occupational Exposure Limits PEL (OEL TWA) [1] 5 mg/m³ dibenzoyl peroxide (94-36-0) Malaysia - Occupational Exposure Limits Local name Benzoil peroksida # Benzoyl peroxide PEL (OEL TWA) [1] 5 mg/m³ Exposure limit values for the other components No additional information available 8.2. Monitoring No additional information available 8.3. Appropriate engineering controls Appropriate engineering controls Ensure adequate ventilation. 8.4. Personal protective equipment Hand protection: Wear protective gloves. The permeation time is not the maximum wearing time! Generally speaking, it must be reduced. Contact with either mixtures of substances or different substances may shorten the protective function’s effective duration. Type