uct identifi

SECTION 2: Hazards identification

Quartz {CAS Ho) 44808-60-7 40 - 60 Care. 1A, H350 dibenzoyl peroxide (CAS No) 94-36-0 10-25 Org. Perox. B, H244 Eye Init, 2A, H319 Skin Sens. 1,H317 Aquatic Acute 1, H400

Hazard statements

see section 16 First-aid measures general Remove/Take off immediately all contaminated clathing. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Alow breathing of fresh air. Allow the victim to rest. First-aid measures after skin contact Wash contaminated clothing before reuse. Wash vath plenty of soap and water, if skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion Rinse mouth. Drink plenty of water, Get medica! advice/atiention. Do not induce vomiting. Obtain emergency medical attention. Mi a Symptoms/injuries after skin contact 3) indicati immeédia No additional information available E xtinguishing media Suitable extinguishing media Water spray. Carbon dioxide. Dry powder. Foam. Sand. Unsuitable extinguishing media Do not use a heavy water stream. Spécial hazards arising: No additional information available Firefighting instructions Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemica! fire. Prevent fire-fighting water fram entering environment. Protection during firefighting Self-contained breathing apparatus. Do not enter fire area without proper protective equipment, including respiratory protection. 08/12/2015 EWN (English) 5/19 ersonal precaution 6.1.1. For non-emergency personnel Emergency procedures Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment Use personal protective equipment as required. Equip cleanup crew with proper protection. Emergency procedures Ventilate area. (6.2; Environmental precaution Prevent entry to sewers and public waters. Nolify authorities if liquid enters sewers or public waters. ind cleaning | j For containment Collect spillage. Methods for cleaning up This material and its container must be disposed of in a safe way, and as per local legislation. Recover mechanically the product. Store away from other matesials.

Further information

Dispose of materials or solid residues at an authorized site. For further information refer to section 8: "Exposure controls/personal protection”, Far further information refer to section 13. “Aa eCa Precautions for safe handting Wear persanal protective equipment. Avoid contact with skin and eyes. Wash hands and other exposed areas with mild soap and water before eating, danking or smoking and when jeaving work. Provide good ventilation in process area to prevent formation of vapour. Hygiene measures Do not eat, drink or smoke when using this product. Akvays wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. i incompatib Storage conditions Keep cool. Protect from sunlight. Incompatible products Strong bases. Strong acids. incompatible materials Sources of ignition. Direct sunlight. Storage temperature 5-25 °C Additional information The product has a pasty consistency. Exposure limit values for respirable dusts ar not relevant for this product. Personal protective equipment Avoid all unnecessary exposure. Safety glasses. Gloves. Protective clothing, Hand protection Wear protective gloves. Eye protection Chemical goggles or safety glasses. 08/42/2015 EN (Engtish) 6/19 / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Skin and body protection Wear suitable protective clothing. Environmental exposure controls Avoid release to the environment. Consumer exposure controls Avoid contact during pregnancyAvhile nursing. Other information Do not eat, drink or smoke during use, Appearance Thixotropic paste, Colour white Odour characteristic Odour threshold Not determined pH No data available Melting point No data available Freezing point No data available Boiling point No data available Flash point No data available Relative evaporation rate (butylacetate=1} No data available Flammability (solid, gas) No data available Explosive limits No data available Explosive properties Product is not explosive. Oxidising properties No data available Vapour pressure No data available Relative density No data available Relative vapour density at 20 °C No data available Density 4.9 giml AW 4.3.23 Solubility No data available Log Pow No data available Auto-ignition temperature Not self-igniting Decomposilion temperature No data available Viscosity No data available Viscosity, kinematic No data available Viscosity, dynamic 40 Pa.s HN-0333 65 °C No additional information available y. Stable under nomaf conditions. azarqdou No additional information available. 40: ik 0 avo) Direct sunlight. Extremely high or low temperatures. 08/12/2015 EN (English) / Vol. 77, No. 58 / Monday, March 26, 2042 / Rules and Regulations Strong acids. Strong bases. Acute toxicity Not classified ‘dibenzoyl peroxide ( 94-36-0) © LD50 oral rat > 5000 mg/kg bodyweight (Rat; Equivalent or similar to OECD 401; Weight of evidence) — Skin corrasionjirritation Not classified Serious eye damagelirritation Causes serious eye irritation. Respiratory or skin sensitisation May cause an allergic skin reaction. Germ cell mutagenicity Not classified Based on available data, the classification criteria are not met Carcinogenicity Not classified ‘Quartz ( 14808-60-7) | IARC group | 1 - Carcinegenic to humans ‘dibenzoyl peroxide (04-46-0) IARC group 3 - Not classifiable Reproductive toxicity Not classified Based on available data, the classification criteria are not met Specific target organ toxicity (single exposure) Not classified Specific target organ toxicity (repeated Not classified exposure) Aspiration hazard Not classified Potential adverse human health effects and Based on available data, the classification criteria are not met. symptoms Symptoms/injuries after skin contact May cause an allergic skin reaction. “dibenzoyi peroxide ( 94-36-0) LC50 fish 7 2 mgf (96 h: Poecilia reticulata) EC50 Daphnia 1 0.07 mg/l LC650 fish 2 0.0602 mg (96h; Oncorhynchus mykiss; ECHA) NOEC {acute} 0.0316 mg/l (96h; Oncorhynchus mykiss; ECHA) Not established. dibenzoyl peroxide ( 94-36-0) Persistence and degradability Readily biodegradable in water. No (test}data on mobility of the substance available. 08/12/2015 EN (English) 8/19 according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Bioaccumulative potential - | Not established. ‘dibenzoy! peroxide ( 94-36-0) Log Pow 3.71 (QSAR; 3.2; Experimental value; OECD 117: Partition Coefficient (n-octanolAvater), HPLC method; 22 °C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Effect on the global warming No known ecological damage caused by this product. Other information Avoid release to the environment. Regional legislation (waste) Disposal must be done according to official regulations, Waste disposal recommendations Refer to manufacturer/supplier for information on recoveryirecycling. Dispose of contents/container to Avoid release to the environment, Refer to manufacturer/supplier for information on recovery/recycling. Ecology - waste materials Avoid release to the environment. [ Not applicable Nat applicable Not applicable 14.3. Transp Not appticable Not applicable Packing group. Not ‘applicable Not applicable Dangerous for the environment Dangerous for the environment Dangerous for the environment Dangerous for the environment Yes Marine pollutant Yes ADR 5.2.1.8.1 derogation applies (quantity of liquids < 5 litres or net mass of solids < 5 kg) No supplementary information available 08/12/2015 EN (English) 9/19 / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations - Overiand transport - Transport by sea No data available - Air transport No data available - Rail transport Carriage prohibited (RID) No deral regulations All components of this product are listed, or excluded from fisting, on {he United States Environmenta! Protection Agency Toxic Substances Control Act (FSCA) inventory Chemical{s) subject to the reporting requirements of Section 313 or Title Hl of the Superfund Amendments and Reauthorization Act (SARA) af 1986 and 40 CFR Part 372. dibenzoyt peroxide CAS No 94-36-0 10-25% Aluminium oxide CAS No 1344-28-1 10 - 25% CANADA No additional information available EU-Regulations No additional information available Classification according to Regulation {EC) No, 1272/2008 [CLP} Eye Irrit. 2 H3719 Skin Sens. 1 H317 Aquatic Acute 1 H400 Full text of hazard classes and H-statements see section 16 National regulations “Quartz ( 14808-60-7) | oe Listed on IARC (International Agency for Research on Cancer) US Sfate regulatic California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm Revision date 12/08/2015 08/12/2015 EN (English) 10/19 according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Other information None. Full text af H-statements: Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1 Care. 1A Carcinogenicity, Category 1A Eye Init. 2A Serious eye damage/eye irritation, Category 2A Org. Perox. B Organic Peroxides, Type B Skin Sens. 1 Sensitisation — Skin, Category 4 H244 Heating may cause a fire or explosion H31i7 May cause an allergic skin reaction H319 Causes serious eye irritation H350 May cause cancer H400 Very toxic to aquatic life SDS_US_ Hilti This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 08/12/2015 EN (English} 11/19 T= according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 12/08/2015 Revision date: 12/08/2015 Supersedes: 05/18/2015 Version: 3.5 Product form