HIT-RE 500, B

Hazard statements (CLP)

H314, H317, H318, H402, H412

Code

Statements

H314

Causes severe skin burns and eye damage

SECTION 2: Hazards identification

Classification of the substance or mixture GHS-US classification Skin Corr. 1A H314 - Causes severe skin burns and eye damage Eye Dam. 1 H318 - Causes serious eye damage Skin Sens. 1 H317 - May cause an allergic skin reaction Aquatic Acute 3 H402 - Harmful to aquatic life Aquatic Chronic 3 H412 - Harmful to aquatic life with long lasting effects Full text of H statements see section 16

2.2 Label elements

GHS US labelling

Hazard pictograms

GHS05 GHS07

Signal word

Danger

Hazard statements

H314 - Causes severe skin burns and eye damage. H317 - May cause an allergic skin reaction. H318 - Causes serious eye damage. H402 - Harmful to aquatic life H412 - Harmful to aquatic life with long lasting effects.

Precautionary statements

P280 - Wear eye protection, protective clothing, protective gloves. P262 - Do not get in eyes, on skin, or on clothing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P302+P352 - If on skin: Wash with plenty of water

2.3 Other hazards

No additional information available

Ingredient(s) with unknown acute toxicity

Not applicable

2.1 Classification of the substance or mixture

GHS-US classification Skin Corr. 1A H314 - Causes severe skin burns and eye damage. Eye Dam. 1 H318 - Causes serious eye damage. Skin Sens. 1 H317 - May cause an allergic skin reaction. Aquatic Acute 3 H402 - Harmful to aquatic life Aquatic Chronic 3 H412 - Harmful to aquatic life with long lasting effects. Full text of H statements : see section 16 2.2. Label elements GHS US labelling Hazard pictograms (GHS US) GHS05 GHS07 Signal word (GHS US) Danger Hazard statements (GHS US) H314 - Causes severe skin burns and eye damage. H317 - May cause an allergic skin reaction. H318 - Causes serious eye damage. H402 - Harmful to aquatic life H412 - Harmful to aquatic life with long lasting effects. Precautionary statements (GHS US) P280 - Wear eye protection, protective clothing, protective gloves. P262 - Do not get in eyes, on skin, or on clothing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P302+P352 - If on skin: Wash with plenty of water 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % GHS-US classification m-Xylylenediamine (CAS-No.) 1477-55-0 35 - 45 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Inhalation:dust,mist), H332 Skin Corr. 1B, H314 Skin Sens. 1, H317 Quartz (SiO2) (CAS-No.) 14808-60-7 10 - 25 Carc. 1A, H350 Full text of H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation Remove person to fresh air and keep comfortable for breathing. First-aid measures after skin contact Wash with plenty of water/…. Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get immediate medical advice/attention. First-aid measures after eye contact Get immediate medical advice/attention. Immediately rinse with water for a prolonged period while holding the eyelids wide open. Remove contact lenses, if present and easy to do. Continue rinsing. Consult an eye specialist. First-aid measures after ingestion Drink plenty of water. Do not induce vomiting. Rinse mouth. Immediately call a POISON CENTER/doctor. 4.2. Most important symptoms and effects (acute and delayed) Potential adverse human health effects and Based on available data, the classification criteria are not met. symptoms Symptoms/effects Causes severe skin burns and eye damage. Symptoms/effects after inhalation May cause an allergic skin reaction. Symptoms/effects after eye contact Causes serious eye damage. 4.3. Immediate medical attention and special treatment, if necessary SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Reactivity Corrosive vapours. 5.3. Advice for firefighters Firefighting instructions Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. Protection during firefighting Self-contained breathing apparatus. Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures Spilled material may present a slipping hazard. 6.1.1. For non-emergency personnel Emergency procedures Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment Use personal protective equipment as required. Equip cleanup crew with proper protection. Emergency procedures Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment. Full or only partially emptied cartridges must be disposed of as special waste in accordance with official regulations. After curing, the product can be disposed of with household waste. 6.3. Methods and material for containment and cleaning up For containment Collect spillage. Methods for cleaning up This material and its container must be disposed of in a safe way, and as per local legislation. Mechanically recover the product. On land, sweep or shovel into suitable containers. Store away from other materials. Other information Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections For further information refer to section 8: "Exposure controls/personal protection". For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Wear personal protective equipment. Avoid contact with skin and eyes. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Avoid contact during pregnancy/while nursing. Hygiene measures Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage, including any incompatibilities Technical measures Comply with applicable regulations. Storage conditions Protect from sunlight. Store in a well-ventilated place. Incompatible products Strong bases. Strong acids. Incompatible materials Sources of ignition. Direct sunlight. Storage temperature 41 - 77 °F Heat and ignition sources Keep away from heat and direct sunlight. SECTION 8: Exposure controls/personal protection 8.1. Control parameters m-Xylylenediamine (1477-55-0) ACGIH ACGIH Ceiling (ppm) 0.018 ppm ACGIH Remark (ACGIH) Eye, skin, & GI irr Quartz (SiO2) (14808-60-7) ACGIH ACGIH TWA (mg/m³) 0.025 mg/m³ (Respirable fraction) ACGIH Remark (ACGIH) TLV® Basis: Pulm fibrosis; lung cancer. Notations: A2 (Suspected Human Carcinogen) OSHA Remark (OSHA) (3) See Table Z-3. Additional information The product has a pasty consistency. Exposure limit values for respirable dusts are not relevant for this product. 8.2. Exposure controls Personal protective equipment Safety glasses. Gloves. Protective clothing. Avoid all unnecessary exposure. Hand protection Wear protective gloves. The permeation time is not the maximum wearing time! Generally speaking, it must be reduced. Contact with either mixtures of substances or different substances may shorten the protective function’s effective duration.