HIT-HY 70, B

Hazard statements (CLP)

H317, H400, H410

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

GHS US classification Classification of the substance or mixture GHS-US classification Skin Sens. 1 H317 - May cause an allergic skin reaction Aquatic Acute 1 H400 - Very toxic to aquatic life Aquatic Chronic 1 H410 - Very toxic to aquatic life with long lasting effects Full text of H statements see section 16

2.2 Label elements

GHS US labelling

Hazard pictograms

GHS07 GHS09

Signal word

Warning

Hazard statements

H317 - May cause an allergic skin reaction. H410 - Very toxic to aquatic life with long lasting effects.

Precautionary statements

P280 - Wear eye protection, protective clothing, protective gloves. P262 - Do not get in eyes, on skin, or on clothing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P302+P352 - If on skin: Wash with plenty of water

2.3 Other hazards

No additional information available

Ingredient(s) with unknown acute toxicity

Not applicable

2.1 Classification of the substance or mixture

GHS-US classification Skin Sens. 1 H317 - May cause an allergic skin reaction. Aquatic Acute 1 H400 - Very toxic to aquatic life. Aquatic Chronic 1 H410 - Very toxic to aquatic life with long lasting effects. Full text of H statements : see section 16 2.2. Label elements GHS US labelling Hazard pictograms (GHS US) GHS07 GHS09 Signal word (GHS US) Warning Hazard statements (GHS US) H317 - May cause an allergic skin reaction. H410 - Very toxic to aquatic life with long lasting effects. Precautionary statements (GHS US) P280 - Wear eye protection, protective clothing, protective gloves. P262 - Do not get in eyes, on skin, or on clothing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P302+P352 - If on skin: Wash with plenty of water 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % GHS-US classification Quartz (SiO2) (CAS-No.) 14808-60-7 40 - 60 Carc. 1A, H350 dibenzoyl peroxide (CAS-No.) 94-36-0 5 - 10 Org. Perox. B, H241 Eye Irrit. 2A, H319 Skin Sens. 1, H317 Full text of H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general Take off immediately all contaminated clothing. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation Remove person to fresh air and keep comfortable for breathing. Assure fresh air breathing. Allow the victim to rest. First-aid measures after skin contact Wash contaminated clothing before reuse. Wash with plenty of water/…. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if pain, blinking or redness persists. First-aid measures after ingestion Rinse mouth. Drink plenty of water. Get medical advice/attention. Do not induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects (acute and delayed) Potential adverse human health effects and Based on available data, the classification criteria are not met. symptoms Symptoms/effects after skin contact May cause an allergic skin reaction. Symptoms/effects after eye contact May cause severe irritation. 4.3. Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Water spray. Carbon dioxide. Dry powder. Foam. Sand. Unsuitable extinguishing media Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. Protection during firefighting Self-contained breathing apparatus. Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures Spilled material may present a slipping hazard. 6.1.1. For non-emergency personnel Emergency procedures Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment Use personal protective equipment as required. Equip cleanup crew with proper protection. Emergency procedures Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment Collect spillage. Methods for cleaning up This material and its container must be disposed of in a safe way, and as per local legislation. Mechanically recover the product. Store away from other materials. Other information Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections For further information refer to section 8: "Exposure controls/personal protection". For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Wear personal protective equipment. Avoid contact with skin and eyes. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Hygiene measures Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Keep cool. Protect from sunlight. Incompatible products Strong bases. Strong acids. Incompatible materials Sources of ignition. Direct sunlight. Storage temperature 5 - 25 °C Heat and ignition sources Keep away from heat and direct sunlight. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Quartz (SiO2) (14808-60-7) OSHA Remark (OSHA) (3) See Table Z-3. dibenzoyl peroxide (94-36-0) ACGIH ACGIH TWA (mg/m³) 5 mg/m³ ACGIH Remark (ACGIH) URT & skin irr OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³ Additional information The product has a pasty consistency. Exposure limit values for respirable dusts are not relevant for this product. 8.2. Exposure controls Personal protective equipment Safety glasses. Gloves. Protective clothing. Avoid all unnecessary exposure. Hand protection Wear protective gloves. The permeation time is not the maximum wearing time! Generally speaking, it must be reduced. Contact with either mixtures of substances or different substances may shorten the protective function’s effective duration. Eye protection Wear security glasses which protect from splashes. Skin and body protection Wear suitable protective clothing. Environmental exposure controls Avoid release to the environment. Consumer exposure controls Avoid contact during pregnancy/while nursing. Other information Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Solid Appearance Thixotropic paste. Colour white Odour