HIT-HY 270, A

Hazard statements (CLP)

H317, H319, H360

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

GHS US classification Classification of the substance or mixture GHS-US classification Serious eye damage/eye irritation, Category 2A Skin sensitisation, Category 1 Reproductive toxicity, Category 1B H319 Causes serious eye irritation H317 May cause an allergic skin reaction H360 May damage fertility or the unborn child Full text of H-statements: see section 16

2.2 Label elements

GHS US labelling

Signal word

Danger

Hazard statements

H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H360 - May damage fertility or the unborn child.

Precautionary statements

P280 - Wear eye protection, protective clothing, protective gloves. P262 - Do not get in eyes, on skin, or on clothing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P302+P352 - If on skin: Wash with plenty of water. 01/21/2022 EN (English) Page 1

Other hazards which do not result in classification

No additional information available

Ingredient(s) with unknown acute toxicity

Not applicable

2.1 Classification of the substance or mixture

GHS-US classification Serious eye damage/eye irritation, Category 2A H319 Causes serious eye irritation. Skin sensitisation, Category 1 H317 May cause an allergic skin reaction. Reproductive toxicity, Category 1B H360 May damage fertility or the unborn child. Full text of H-statements: see section 16 2.2. GHS Label elements, including precautionary statements GHS US labelling Hazard pictograms (GHS US) Signal word (GHS US) Danger Hazard statements (GHS US) H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H360 - May damage fertility or the unborn child. Precautionary statements (GHS US) P280 - Wear eye protection, protective clothing, protective gloves. P262 - Do not get in eyes, on skin, or on clothing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P302+P352 - If on skin: Wash with plenty of water. 01/21/2022 EN (English) Page 1 2.3. Other hazards which do not result in classification No additional information available 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % GHS-US classification Quartz (SiO2) (CAS-No.) 14808-60-7 25 – 40 Carc. 1A, H350 2-Propenoic acid, 2-methyl-, monoester with 1,2-propanediol (CAS-No.) 27813-02-1 10 – 25 Eye Irrit. 2A, H319 Skin Sens. 1, H317 Bisphenol-A-diethoxy-methacrylate (CAS-No.) 24448-20-2 5 – 10 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Tricyclodecane dimethanol dimethacrylate (CAS-No.) 43048-08-4 2,5 - 5 Skin Sens. 1B, H317 1,1,1-Trimethylolpropane trimethacrylate (CAS-No.) 3290-92-4 2,5 - 5 Not classified 1,1'-(p-tolylimino)dipropan-2-ol (CAS-No.) 38668-48-3 0,1 - 1 Acute Tox. 2 (Oral), H300 Eye Irrit. 2A, H319 boric acid (CAS-No.) 10043-35-3 0,1 - 1 Repr. 1B, H360 4-tert-butylpyrocatechol (CAS-No.) 98-29-3 0,1 - 1 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Skin Corr. 1B, H314 Skin Sens. 1, H317 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general Take off immediately all contaminated clothing. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation Remove person to fresh air and keep comfortable for breathing. Allow affected person to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact Wash contaminated clothing before reuse. Wash with plenty of water/…. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if pain, blinking or redness persists. First-aid measures after ingestion Rinse mouth. Get medical advice/attention. Do not induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects (acute and delayed) Potential adverse human health effects and No additional information available. symptoms Symptoms/effects after skin contact May cause an allergic skin reaction. Symptoms/effects after eye contact May cause severe irritation. 4.3. Immediate medical attention and special treatment, if necessary No additional information available 01/21/2022 EN (English) 5/25 SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media Water spray. Carbon dioxide. Dry powder. Foam. Sand. Unsuitable extinguishing media Do not use a heavy water stream. 5.2. Specific hazards arising from the chemical Hazardous decomposition products in case of Thermal decomposition generates : Carbon dioxide. Carbon monoxide. fire 5.3. Special protective equipment and precautions for fire-fighters Firefighting instructions Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. Protection during firefighting Self-contained breathing apparatus. Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures Spilled material may present a slipping hazard. 6.1.1. For non-emergency personnel Emergency procedures Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment Use personal protective equipment as required. Equip cleanup crew with proper protection. Emergency procedures Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment Collect spillage. Methods for cleaning up This material and its container must be disposed of in a safe way, and as per local legislation. Mechanically recover the product. Store away from other materials. Other information Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections For further information refer to section 8: "Exposure controls/personal protection". For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Wear personal protective equipment. Avoid contact with skin and eyes. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.