HIT-HY 10 PLUS, A

Hazard statements (CLP)

H300, H301, H314, H315, H317, H318, H319, H332, H412

Code

Statements

H300

Fatal if swallowed

SECTION 2: Hazards identification

OSHA GHS-US classification Eye Irrit. 24 H319~ Causes serious eye irritation Skin Sens _H317 - May cause an allergic skin reaction Full text of H-statements: see section 16 GHS-US labelling

Hazard pictograms

GHSO7

Signal word

Warning

Hazard statements

H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation

Precautionary statements

P280 - Wear eye protection, protective clothing, pratective gloves P262 - Do not get in eyes, on skin, or an clothing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P302+P362 - If on skin: Wash with plenty of water Safety Data Sheet

Further information

Dispose of materials or solid residues at an authorized site. For further information refer to section xposure controls/personal protection". For further information refer to section +3. SECTION 7: ee and storage Z ae oe Precautions for safe handling Wear personal protective equipment. Avoid contact with skin and eyes. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Hygiene measures Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Storage conditions Keep cool. Protect from sunlight. Incompatible products Strong bases. Strong acids. Incompatible materials Sources of ignition. Direct sunlight. Storage temperature 5-25°C SECTION 8: Exposure controls/personal protection

2.1 Classification of the substance or mixture

Eye Irrit. 24 H319~ Causes serious eye irritation Skin Sens. 1 _H317 - May cause an allergic skin reaction Full text of H-statements: see section 16 GHS-US labelling Hazard pictograms (GHS-US) GHSO7 Signal word (GHS-US) Warning Hazard statements (GHS-US) H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation Precautionary statements (GHS-US) P280 - Wear eye protection, protective clothing, pratective gloves P262 - Do not get in eyes, on skin, or an clothing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P302+P362 - If on skin: Wash with plenty of water Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations ards No additional information available Not applicable Mixidtery identifi Quartz (CAS No) 14808-60-7 2-Hydroxypropyl methacrylate (CAS No) 27813-02-4 10-25 Eye Innit. 24, H319 Skin Sens. 1, H317 41,4-Butanediol dimethacrylate (CAS No) 2082-81-7 1-25 Skin Sens. 1B, H317 1,1'-(p-talylimino)dipropan-2-ol {CAS No) 38668-48-3 O.1-1 Acute Tox, 2 (Oral), H300 Eye Irsit. 2A, H319 Aquatic Chronic 3, H412 1,2-dihydroxybenzene, pyrocatechot (CAS No) 120-80-9 04-4 Acute Tox, 3 (Oral), H301 Acute Tox. 3 (Dermal), H314 Acute Tox. 4 (Inhalation:dust,mist), H332 Skin Init, 2, H315 Eye Dam. 1, H318 Skin Sens, 1,H317 Muta. 2, 344 Fut text of H-statements: see section 16 SECTION test eee Mitre et kes) First-aid measures general Remove/Take off immediately all contaminated clothing. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the labei where possible), First-aid measures after inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Allow breathing of fresh air. Allow the victim to rest. First-aid measures after skin contact Wash contaminated clothing before reuse. Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Firstaid measures after eye contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do, Continue rinsing. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion Ringe mouth. Drink plenty of water. Get medical advice/attention. Do not induce vomiting. Obtain emergency medical attention. Suitable extinguishing media Water spray. Carbon dioxide. Dry powder. Foam. Sand. Unsuitable extinguishing media Do not use a heavy water stream. No additional information available . Firefighting instructions Use water spray or fog for cooling ¢ exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting Self-contained breathing apparatus. Do not enter fire area without proper protective equipment, including respiratory protection. Soe 6.1.1. For non-emergency personnel Emergency procedures Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment Use personal protective equipment as required. Equip cleanup crew with proper protection. Emergency procedures Ventilate area. Prevent entry to se sewers and public waters. Notify authori s if fiquid enters sewers or public waters. ria) (or conta iment and clear For containment Collect spitlage. Methods for cleaning up This material and its container must be disposed of in a safe way, and as per local legislation. Recover mechanically the product. Store away from other materials. Other information Dispose of materials or solid residues at an authorized site. For further information refer to section xposure controls/personal protection". For further information refer to section +3. SECTION 7: ee and storage Z ae oe Precautions for safe handling Wear personal protective equipment. Avoid contact with skin and eyes. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Hygiene measures Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Storage conditions Keep cool. Protect from sunlight. Incompatible products Strong bases. Strong acids. Incompatible materials Sources of ignition. Direct sunlight. Storage temperature 5-25°C SECTION 8: Exposure controls/personal protection Rematk (OSHA) ~ | (3) See Table Z-3. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations | ACGIH TWA (ppm) Remark (ACGIH) Eye & URT irr; dermatitis Additional information The product has a pasty consistency. Exposure limit values for respirable dusts ar not relevant for this product. oe Personal protective equipment Avoid all unnecessary exposure. Safety glasses. Gloves. Protective clothing. Hand protection Wear protective gloves. Eye protection Chemical gaggles or safety glasses. Skin and bady protection Wear suitable protective clothing. Environmental exposure controls Avoid release to the environment. Consumer exposure controls Avoid contact during pregnancy/while nursing. Other information Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties Physical state Appearance Thixotropic paste. Colour Light grey Odour characteristic Odour threshold Not determined pH No data available Melting point No data available Freezing point No data available Boiling point No data available Flash point > 109 °C DIN EN ISO 1523 Relative evaporation rate (butylacetate=1) No data available Flammability (solid, gas) No data available Explosive limits No data available Explosive properties Product is not explosive. Oxidising properties No data available Vapour pressure No data available Relative density No data available Relative vapour density at 20 °C No data available Density 1.65 gi! AW 4.3.23 Solubility No data available Log Pow No data available Auto-ignition temperature Not self-igniting Decomposition temperature No data available Viscosity No data available Viscosity, kinematic No data available Viscosity, dynamic 100 Pa.s HN-0333 NANDI2NAB, FN (Enalish) No additional information available SECTION 10: Stability and reactivity HOT Reactly oe... No additional information available bili No additional information available LD50 oral rat 25 mg/kg LDS5¢ dermal rat > 2000 mg/kg ATE US (oral) 25.000 mg/kg bodyweight : LDS50 oral rat 10066 mg/kg LD50 dermal rat > 3000 mg/kg ATE US (oral) 10066.000 mg/kg bodyweight = zi ATE US (oral) " ~ | 100.000 mgikg bodyweight ATE US (dermal) 300.000 mg/kg bodyweight ATE US (dust, mist) 1.600 mg//4h is LD50 oral rat > 5000 mg/kg (Rat; OECD 401: Acute Oral Toxicity; Literature stud bodyweight; Rat; Experimental value) LD50 dermal rabbit >= 5000 mg/kg bodyweight (Rabbit; Experimental value) Skin corrosion/irritation Not classified Serious eye damage/irritation Causes serious eye irritation. Respiratory or skin sensitisation May cause an allergic skin reaction. Germ cell mutagenicity Not classified Based on available data, the classification criteria are not met Carcinogenicity Not classified. 03/02/2016 EN (English) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations | 1 - Carcinogenic to humans Reproductive toxicity Not classified Based on available data, the classification criteria are not met Specific target organ toxicity (single exposure) Not classified Specific target organ toxicity (repeated Not classified exposure) Aspiration hazard Not classified Potential adverse human health effects and Based on available data, the classification criteria are not met. symptoms Symptoms/injuries after skin contact May cause an allergic skin reaction. Symptoms/injuries after eye contact May cause severe irritation. ey ie) Persie ure ticelty LC50 fish 1 17 mg/l LC50 other aquatic organisms 1 245 mg/l EC50 Daphnia 1 28.8 mg/l NOEC (acute) 57.8 mg/l miesutanediel aE Bese e ae LC50 fish 1 32.5 mgit LC50 other aquatic organisms 1 9.79 mg/i NOEC (acute) 7.51 mgt NOEC (chronic) 20 mg/l LC650 fish 1 9.22 mg/l LC50 other aquatic organisms 1 22 mail [A yaroxvarenyl miethacry! C50 fish 1 493 mg/l (48 h; Leuciscus idus; GLP’ EC50 Daphnia 1 > 143 mg/l {48 h; Daphnia magna, GLP) Threshold limit algae 1 > 97.2 mg/l (72 h, Pseudokirchneriella subcapitata; GLP) Threshold fimit algae 2 > 97.2 mg/l (72 h; Pseudokirchneriella subcapitata; GLP) Biodegradation Readily biodegradable in water. naiNg!on1e EN (Enalish) en ane ceeakele i 5 sori “BCF fish 1 <= BCF fish 2 3.2 (Pisces; QSAR) Log Pow 0.97 (OECD 102: Melting Point/Meiting Range) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). ee No additional information available sone eee Effect on the global warming No known ecological damage caused by this product. Other information Avoid release to the environment. isposal-considerations No additional information available SECTION 14: Transport informat F In accordance with ADR / RID / IMDG / IATA / ADN Proper Shipping Name (ADR) Not applicable Proper Shipping Name (IMDG) Not applicable Proper Shipping Name (IATA) Not applicable Praper Shipping Name (ADN) Not applicable Proper Shipping Name (RID} Not applicable Transport hazard class(es) (ADR) Not applicable IMDG Transport hazard class(es) (IMDG) Not applicable IATA Transport hazard class(és) (IATA) Not applicable 03/02/2016 EN (English) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations ADN Transport hazard class(es) (ADN) Not applicable RID Transport hazard class(es) (R!D) Not applicable namebae nen Packing group (ADR) Not applicable Packing group (IMDG) Not applicable Packing group (IATA) Not applicable Packing group (ADN) Not applicable Packing group (RID) Not applicable Dangerous for the environment No Marine poflutant No Other information No supplementary information available - Overland transport - Transport by sea No data available - Alr transport No data available - Inland waterway transport Carriage prohibited (ADN) No Not subject to ADN No - Rail transport Carriage prohibited (RID) No All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory Lae i Subject to reporting requirements of United States SARA Section 313 EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. RQ (Reportable quantity, section 304 of EPA's 100 ib List of Lists) 03/02/2016 EN (English) CANADA No additional information available EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Eye Irrit.2 H319 Skin Sens. 1 H317 Full text of hazard classes and H-statements : see section 16 National regulations US. California - 8. - California - U.S. - California - U.S. - California - Non-significant risk Proposition 65 - Proposition 65 - Proposition 65 - Proposition 65 - level (NSRL) Carcinogens List Developmental Toxicity Reproductive Toxicity - Reproductive Toxicity - Female Male Yes No OHIO ANE OLE Revision date 01/20/2016 Other information None. 03/02/2016 EN (English) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Full text of H-statements: Acute Tox. 2 (Oral) Acute toxicity (oral), Category 2 Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3 Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3 Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4 Aquatic Chronic 3 Hazardous to the aquatic environment — Chronic Hazard, Category 3 Care. 1A Carcinogenicity, Category 1A Eye Dam. t Serious eye damage/eye irritation, Category 1 Eye trrit. 2A. Serious eye damage/eye iritation, Category 2A Muta. 2 Germ cell mutagenicity, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Sensitisation — Skin, Category 1 Skin Sens. 1B Sensitisation — Skin, category 18 H300 Fatal if swallowed H301 Toxic if swallowed H314 Toxic in contact with skin H315 Causes skin iritation H317 May cause an allergic skin reaction H318 Causes serious eye damage H319 Causes serious eye irritation H332 Harmful if inhaled H341 Suspected of causing genetic defects 350 May cause cancer H412 Harmful to aquatic life with long lasting effects SDS_US_Hilti This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 03/02/2016 EN (English)