HIT-HY 200-A V3, B

Hazard statements (CLP)

H317, H319, H400, H410

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

Classification of the substance or mixture Classification according to the United Nations GHS Serious eye damage/eye irritation, Category 2 Skin sensitisation, Category 1 H319 Calculation method H317 Calculation method Hazardous to the aquatic environment – Acute Hazard, Category 1 H400 Calculation method Hazardous to the aquatic environment – Chronic Hazard, Category 1 H410 Calculation method Full text of H-statements: see section 16

2.2 Label elements

Labelling according to the United Nations GHS

Signal word

Warning

Hazardous Ingredients

dibenzoyl peroxide

Hazard statements

H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H410 - Very toxic to aquatic life with long lasting effects

Precautionary statements

P280 - Wear eye protection, protective clothing, protective gloves. P262 - Do not get in eyes, on skin, or on clothing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 - If skin irritation or rash occurs: Get medical advice, medical attention. P337+P313 - If eye irritation persists: Get medical advice, medical attention. P302+P352 - IF ON SKIN: Wash with plenty of water.

Other hazards which do not result in classification

No additional information available

2.1 Classification of the substance or mixture

Classification according to the United Nations GHS Serious eye damage/eye irritation, Category 2 H319 Calculation method Skin sensitisation, Category 1 H317 Calculation method Hazardous to the aquatic environment – Acute Hazard, Category 1 H400 Calculation method Hazardous to the aquatic environment – Chronic Hazard, Category 1 H410 Calculation method Full text of H-statements: see section 16 2.2. GHS Label elements, including precautionary statements Labelling according to the United Nations GHS Hazard pictograms (GHS UN) Signal word (GHS UN) Warning Hazardous ingredients dibenzoyl peroxide Hazard statements (GHS UN) H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H410 - Very toxic to aquatic life with long lasting effects Precautionary statements (GHS UN) P280 - Wear eye protection, protective clothing, protective gloves. P262 - Do not get in eyes, on skin, or on clothing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 - If skin irritation or rash occurs: Get medical advice, medical attention. P337+P313 - If eye irritation persists: Get medical advice, medical attention. P302+P352 - IF ON SKIN: Wash with plenty of water. 2.3. Other hazards which do not result in classification No additional information available SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to the United Nations GHS dibenzoyl peroxide CAS-No.: 94-36-0 10 - 15 Organic Peroxides, Type B, H241 Serious eye damage/eye irritation, Category 2, H319 Skin sensitisation, Category 1, H317 Hazardous to the aquatic environment – Acute Hazard, Category 1, H400 (M=10) Hazardous to the aquatic environment – Chronic Hazard, Category 1, H410 (M=10) Full text of H-statements: see section 16 SECTION 4: First-aid measures 4.1. Description of necessary first-aid measures First-aid measures general Take off immediately all contaminated clothing. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation Remove person to fresh air and keep comfortable for breathing. Allow affected person to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact Wash contaminated clothing before reuse. Wash with plenty of water/…. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if pain, blinking or redness persists. First-aid measures after ingestion Rinse mouth. Get medical advice/attention. Do not induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms/effects, acute and delayed Symptoms/effects after skin contact May cause an allergic skin reaction. Symptoms/effects after eye contact May cause severe irritation. 4.3. Indication of immediate medical attention and special treatment needed, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Suitable extinguishing media Water spray. Carbon dioxide. Dry powder. Foam. Sand. Unsuitable extinguishing media Do not use a heavy water stream. 5.2. Specific hazards arising from the chemical Hazardous decomposition products in case of fire Thermal decomposition generates : Carbon dioxide. Carbon monoxide. 5.3. Special protective actions for fire-fighters Firefighting instructions Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. Protection during firefighting Self-contained breathing apparatus. Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures Spilled material may present a slipping hazard. 6.1.1. For non-emergency personnel Emergency procedures Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment Use personal protective equipment as required. Equip cleanup crew with proper protection. Emergency procedures Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and materials for containment and cleaning up For containment Collect spillage. Methods for cleaning up This material and its container must be disposed of in a safe way, and as per local legislation. Mechanically recover the product. Store away from other materials. Other information Dispose of materials or solid residues at an authorized site. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Wear personal protective equipment. Avoid contact with skin and eyes. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Hygiene measures Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Keep cool. Protect from sunlight. Incompatible products Strong bases. Strong acids. Incompatible materials Sources of ignition. Direct sunlight. Heat and ignition sources Keep away from heat and direct sunlight. Storage temperature 5 – 25 °C SECTION 8: Exposure controls/personal protection 8.1. Control parameters No additional information available 8.2. Appropriate engineering controls Appropriate engineering controls Ensure adequate ventilation. Environmental exposure controls Not applicable. Consumer exposure controls Avoid contact during pregnancy/while nursing. Other information Do not eat, drink or smoke during use. 8.3. Individual protection measures, such as personal protective equipment (PPE)