HIT-HY 200-A V3, A

Hazard statements (CLP)

H317

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

According to Regulation (EC) No. 1272/2008 (CLP) Classification of the substance or mixture

Adverse physicochemical, human health and environmental effects

No additional information available

Hazard pictograms

GHS07

Signal word

Warning

Contains

2-Propenoic acid, 2-methyl-, 1,4-butanediyl ester, 2-Propenoic acid, 2-methyl-, monoester with 1,2-propanediol

Hazard statements

H317 - May cause an allergic skin reaction.

Precautionary statements

P280 - Wear eye protection, protective clothing, protective gloves. P262 - Do not get in eyes, on skin, or on clothing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302+P352 - IF ON SKIN: Wash with plenty of water. P337+P313 - If eye irritation persists: Get medical advice/attention. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.

Other hazards

This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII Component 2-Propenoic acid, 2-methyl-, 1,4-butanediyl ester (2082-81-7) 2-Propenoic acid, 2-methyl-, monoester with 1,2- propanediol (27813-02-1) 1,1'-(p-tolylimino)dipropan-2-ol (38668-48-3) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 % Component 2-Propenoic acid, 2-methyl-, 1,4-butanediyl ester(2082-81-7) The substance is not included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 2-Propenoic acid, 2-methyl-, monoester with 1,2- propanediol(27813-02-1) The substance is not included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 1,1'-(p-tolylimino)dipropan-2-ol(38668-48-3) The substance is not included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605

2.1 Classification of the substance or mixture

H317 Full text of H- and EUH-statements: see section 16 Adverse physicochemical, human health and environmental effects No additional information available 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) GHS07 Signal word (CLP) Warning Contains 2-Propenoic acid, 2-methyl-, 1,4-butanediyl ester, 2-Propenoic acid, 2-methyl-, monoester with 1,2-propanediol Hazard statements (CLP) H317 - May cause an allergic skin reaction. Precautionary statements (CLP) P280 - Wear eye protection, protective clothing, protective gloves. P262 - Do not get in eyes, on skin, or on clothing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302+P352 - IF ON SKIN: Wash with plenty of water. P337+P313 - If eye irritation persists: Get medical advice/attention. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. 2.3. Other hazards This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII Component 2-Propenoic acid, 2-methyl-, 1,4-butanediyl ester This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII (2082-81-7) This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII 2-Propenoic acid, 2-methyl-, monoester with 1,2- This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII propanediol (27813-02-1) This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII 1,1'-(p-tolylimino)dipropan-2-ol (38668-48-3) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 % Component 2-Propenoic acid, 2-methyl-, 1,4-butanediyl The substance is not included in the list established in accordance with Article 59(1) of ester(2082-81-7) REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 2-Propenoic acid, 2-methyl-, monoester with 1,2- The substance is not included in the list established in accordance with Article 59(1) of propanediol(27813-02-1) REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 1,1'-(p-tolylimino)dipropan-2-ol(38668-48-3) The substance is not included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] 2-Propenoic acid, 2-methyl-, 1,4-butanediyl ester CAS-No.: 2082-81-7 10 – 25 Skin Sens. 1B, H317 EC-No.: 218-218-1 REACH-no: 01-2119967415- 30 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] 2-Propenoic acid, 2-methyl-, monoester with 1,2- CAS-No.: 27813-02-1 5 - 8 Eye Irrit. 2, H319 propanediol EC-No.: 248-666-3 Skin Sens. 1, H317 EC Index-No.: 607-125-00-5 REACH-no: 01-2119490226- 37 1,1'-(p-tolylimino)dipropan-2-ol CAS-No.: 38668-48-3 0,1 – 1 Acute Tox. 2 (Oral), H300 (ATE=25 mg/kg EC-No.: 254-075-1 bodyweight) REACH-no: 01-2119980937- Eye Irrit. 2, H319 17 Aquatic Chronic 3, H412 Full text of H- and EUH-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general Take off immediately all contaminated clothing. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation Remove person to fresh air and keep comfortable for breathing. Allow affected person to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact Wash contaminated clothing before reuse. Wash with plenty of water/…. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if pain, blinking or redness persists. First-aid measures after ingestion Rinse mouth. Get medical advice/attention. Do not induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects after skin contact May cause an allergic skin reaction. Symptoms/effects after eye contact May cause severe irritation. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Water spray. Carbon dioxide. Dry powder. Foam. Sand. Unsuitable extinguishing media Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire Thermal decomposition generates : Carbon dioxide. Carbon monoxide. 5.3. Advice for firefighters Firefighting instructions Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. Protection during firefighting Self-contained breathing apparatus. Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures Spilled material may present a slipping hazard. 6.1.1. For non-emergency personnel Emergency procedures Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment Use personal protective equipment as required. Equip cleanup crew with proper protection. Emergency procedures Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up