CF 101, B / CF Z 200, B

Hazard statements (CLP)

H315, H317, H319, H332, H335, H351, H373

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

According to Regulation (EC) No. 1272/2008 (CLP) Classification of the substance or mixture

Adverse physicochemical, human health and environmental effects

Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled

Hazard pictograms

GHS07 GHS08

Signal word

Warning

Contains

4,4'-diphenylmethanediisocyanate, isomeres and homologues

Hazard statements

H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H332 - Harmful if inhaled. H335 - May cause respiratory irritation. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure.

Precautionary statements

P260 - Do not breathe vapours. P280 - Wear protective gloves, protective clothing, eye protection. P284 - In case of inadequate ventilation wear respiratory protection. P302+P352 - IF ON SKIN: Wash with plenty of soap and water. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.

Additional information

As from 24 August 2023 adequate training is required before industrial or professional use.

Other hazards

Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII Component 4,4'-diphenylmethanediisocyanate, isomeres and homologues (9016-87-9) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 % Component 4,4'-diphenylmethanediisocyanate, isomeres and homologues (9016-87-9) The substance is not included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute toxicity (inhalation:dust,mist) Category 4 H332 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Skin sensitisation, Category 1 H317 Carcinogenicity, Category 2 H351 Specific target organ toxicity – Single exposure, Category 3, Respiratory H335 tract irritation Specific target organ toxicity – Repeated exposure, Category 2 H373 Full text of H- and EUH-statements: see section 16 Adverse physicochemical, human health and environmental effects Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) GHS07 GHS08 Signal word (CLP) Warning Contains 4,4'-diphenylmethanediisocyanate, isomeres and homologues Hazard statements (CLP) H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H332 - Harmful if inhaled. H335 - May cause respiratory irritation. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure. Precautionary statements (CLP) P260 - Do not breathe vapours. P280 - Wear protective gloves, protective clothing, eye protection. P284 - In case of inadequate ventilation wear respiratory protection. P302+P352 - IF ON SKIN: Wash with plenty of soap and water. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Extra phrases As from 24 August 2023 adequate training is required before industrial or professional use. 2.3. Other hazards Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII Component 4,4'-diphenylmethanediisocyanate, isomeres and This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII homologues (9016-87-9) This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 % Component 4,4'-diphenylmethanediisocyanate, isomeres and The substance is not included in the list established in accordance with Article 59(1) of homologues (9016-87-9) REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier Conc. Classification according to Regulation (EC) No. 1272/2008 [CLP] 4,4'-diphenylmethanediisocyanate, isomeres and CAS-No.: 9016-87-9 100 Acute Tox. 4 (Inhalation), H332 (ATE=1,5 homologues EC-No.: 618-498-9 mg/l/4h) substance with national workplace exposure limit(s) Skin Irrit. 2, H315 (DE) Eye Irrit. 2, H319 Resp. Sens. 1, H334 Skin Sens. 1, H317 Carc. 2, H351 STOT SE 3, H335 STOT RE 2, H373 Specific concentration limits: Name Product identifier Specific concentration limits 4,4'-diphenylmethanediisocyanate, isomeres and CAS-No.: 9016-87-9 (0,1 ≤ C < 100) Resp. Sens. 1; H334 homologues EC-No.: 618-498-9 (5 ≤ C < 100) Skin Irrit. 2; H315 (5 ≤ C < 100) Eye Irrit. 2; H319 (5 ≤ C < 100) STOT SE 3; H335 Full text of H- and EUH-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general IF exposed or concerned: Get medical advice/attention. Call a poison center or a doctor if you feel unwell. First-aid measures after inhalation Remove person to fresh air and keep comfortable for breathing. Call a poison center or a doctor if you feel unwell. First-aid measures after skin contact Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion Call a poison center or a doctor if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects after inhalation May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms/effects after skin contact Irritation. May cause an allergic skin reaction. Symptoms/effects after eye contact Eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Water spray. Dry powder. Foam. Carbon dioxide. 5.2. Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire Toxic fumes may be released. 5.3. Advice for firefighters Protection during firefighting Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures Ventilate spillage area. Do not breathe vapours. Avoid contact with skin and eyes. 6.1.2. For emergency responders Protective equipment Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". 6.2. Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up Mechanically recover the product. Notify authorities if product enters sewers or public waters. Other information Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear personal protective equipment. Do not breathe vapours. Use only outdoors or in a well-ventilated area. Avoid contact with skin and eyes. Hygiene measures Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Keep cool. Protect from sunlight. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool. Storage temperature 5 – 25 °C Storage class (LGK, TRGS 510) LGK 10 - Combustible liquids 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.1.1. National occupational exposure and biological limit values 4,4'-diphenylmethanediisocyanate, isomeres and homologues (9016-87-9) Germany - Occupational Exposure Limits (TRGS 900) Local name pMDI (als MDI berechnet) AGW (OEL TWA) 0,05 mg/m³ (E) 4,4'-diphenylmethanediisocyanate, isomeres and homologues (9016-87-9) Peak exposure limitation factor 1;=2=(I)