HIT-HY 200-R V3, A

Hazard statements (CLP)

H317

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

Classification according to the model Work Health and Safety Regulations (WHS Regulations) Classification of the hazardous chemical

Hazard pictograms

Exclamation mark

Signal word

Warning

Contains

2-Propenoic acid, 2-methyl-, 1,4-butanediyl ester (10 – 25 %); 2-Propenoic acid, 2-methyl-, monoester with 1,2-propanediol (5 – 10 %); 1,1'-(p-tolylimino)dipropan-2-ol (0.1 – 1 %); 2,2'- (m-tolylimino)diethanol (0.1 – 1 %)

Hazard statements

H317 - May cause an allergic skin reaction

Precautionary statements

P280 - Wear eye protection, protective clothing, protective gloves. P262 - Do not get in eyes, on skin, or on clothing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302+P352 - IF ON SKIN: Wash with plenty of water. P337+P313 - If eye irritation persists: Get medical advice/attention. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.

Other hazards which do not result in classification

No additional information available

2.1 Classification of the substance or mixture

Classification according to the model Work Health and Safety Regulations (WHS Regulations) Skin sensitisation, Category 1 H317 2.2. GHS Label elements, including precautionary statements Hazard pictograms (GHS AU) Exclamation mark Signal word (GHS AU) Warning Contains 2-Propenoic acid, 2-methyl-, 1,4-butanediyl ester (10 – 25 %); 2-Propenoic acid, 2-methyl-, monoester with 1,2-propanediol (5 – 10 %); 1,1'-(p-tolylimino)dipropan-2-ol (0.1 – 1 %); 2,2'- (m-tolylimino)diethanol (0.1 – 1 %) Hazard statements (GHS AU) H317 - May cause an allergic skin reaction Precautionary statements (GHS AU) P280 - Wear eye protection, protective clothing, protective gloves. P262 - Do not get in eyes, on skin, or on clothing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302+P352 - IF ON SKIN: Wash with plenty of water. P337+P313 - If eye irritation persists: Get medical advice/attention. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. 2.3. Other hazards which do not result in classification No additional information available SECTION 3: Composition and information on ingredients Name CAS-No. % Classification according to the model Work Health and Safety Regulations (WHS Regulations) 2-Propenoic acid, 2-methyl-, 1,4-butanediyl ester 2082-81-7 10 – 25 Skin Sens. 1B, H317 2-Propenoic acid, 2-methyl-, monoester with 1,2- 27813-02-1 5 – 10 Eye Irrit. 2A, H319 propanediol Skin Sens. 1, H317 1,1'-(p-tolylimino)dipropan-2-ol 38668-48-3 0.1 – 1 Acute Tox. 2 (Oral), H300 Eye Irrit. 2A, H319 2,2'-(m-tolylimino)diethanol 91-99-6 0.1 – 1 Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Dam. 1, H318 Skin Sens. 1B, H317 STOT RE 2, H373 SECTION 4: First aid measures 4.1. Description of necessary first-aid measures First-aid measures general Take off immediately all contaminated clothing. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation Remove person to fresh air and keep comfortable for breathing. Allow affected person to breathe fresh air. Allow the victim to rest. 4.2. Symptoms caused by exposure Symptoms/effects after skin contact May cause an allergic skin reaction. Symptoms/effects after eye contact May cause severe irritation. 4.3. Medical attention and special treatment No additional information available SECTION 5: Fire-fighting measures 5.1. Extinguishing media Suitable extinguishing media Water spray. Carbon dioxide. Dry powder. Foam. Sand. Unsuitable extinguishing media Do not use a heavy water stream. 5.2. Specific hazards arising from the chemical General measures Spilled material may present a slipping hazard. Hazardous decomposition products in case of fire Thermal decomposition generates : Carbon dioxide. Carbon monoxide. 5.3. Special protective equipment and precautions for fire-fighters Firefighting instructions Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. Protection during firefighting Self-contained breathing apparatus. Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures Spilled material may present a slipping hazard. 6.1.1. For non-emergency personnel Emergency procedures Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment Use personal protective equipment as required. Equip cleanup crew with proper protection. Emergency procedures Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and materials for containment and cleaning up For containment Collect spillage. Methods for cleaning up This material and its container must be disposed of in a safe way, and as per local legislation. Mechanically recover the product. Store away from other materials. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Wear personal protective equipment. Avoid contact with skin and eyes. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Hygiene measures Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Keep cool. Protect from sunlight. Incompatible products Strong bases. Strong acids. Incompatible materials Sources of ignition. Direct sunlight. Storage temperature 5 – 25 °C Heat and ignition sources Keep away from heat and direct sunlight. SECTION 8: Exposure controls and personal protection 8.1. Control parameters - exposure standards Additional information The product has a pasty consistency. Exposure limit values for respirable dusts are not relevant for this product. 8.2. Biological Monitoring No additional information available 8.3. Engineering controls Appropriate engineering controls Ensure good ventilation of the work station. 8.4. Individual protection measures, such as personal protective equipment (PPE) Personal protective equipment Safety glasses. Gloves. Protective clothing. Avoid all unnecessary exposure. Hand protection Wear protective gloves. The permeation time is not the maximum wearing time! Generally speaking, it must be reduced. Contact with either mixtures of substances or different substances may shorten the protective function’s effective duration. Type Material