PHENYLARSENE OXIDE SOLUTION 0.00564N

Hazard statements (CLP)

H301, H315, H319, H331, H335, H351, H401, H413

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

OSHA 5. FIRE FIGHTING MEASURES

2.1 Classification of the substance or mixture

Health: 5.1 Suitable Extinguishing Media: Acute Toxicity (Oral & Inhalation): Category 3 Dry chemical, carbon dioxide, water spray or regular foam. Skin Corrosion/Irritation: Category 2 5.2 Specific hazards arising from the chemical Eye Damage/Irritation: Category 2A None Carcinogenicity: Category 2 5.3 Special protective actions for fire-fighters Specific target organ toxicity (single exposure): Category 3 Fire Fighting Procedures: Move containers from fire area if possible. Avoid Environmental breathing vapors or dusts; keep upwind. Hazardous to the aquatic environment (Acute hazard): Category 2

NFPA Ratings

HEALTH 3 FLAMMABLE 1 REACTIVITY 0 Hazardous to the aquatic environment (Chronic hazard): Category 4 6. ACCIDENTAL RELEASE MEASURES

2.2 Label elements

6.1 Personal precautions, protective equipment and emergency procedures: Cover with soda ash. Scoop up and place in a suitable container. 6.2 Environmental precautions

Hazard pictograms

Keep away from drains, surface and ground water

Signal word

DANGER 6.3 Methods and materials for containment and cleaning up

Hazard statements

Cover with soda ash. Scoop up and place in a suitable container. H301 – Toxic if swallowed H331 – Toxic if inhaled 7. HANDLING AND STORAGE H315 – Causes skin irritation H319 – Causes serious eye irritation 7.1 Precautions for safe handling: H351 – Suspected of causing cancer Wash well after handling. Avoid breathing vapors. H335 – May cause respiratory irritation 7.2 Conditions for safe storage, including any incompatibilities H401 – Toxic to aquatic life Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect H413 – May cause long lasting harmful effects to aquatic life against physical damage.

Precautionary statements

P201 – Obtain special instructions before use. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION P202 – Do not handle until all safety precautions have been read and understood. 8.1 Control parameters: P261 – Avoid breathing fume/gas/mist/vapours/spray OSHA Permissible Exposure Limit (PEL): 0.5 mg/m3 (TWA) P264 – Wash hands thoroughly after handling ACGIH Threshold Limit Value (TLV): 0.2 mg/m3 (TWA) P270 – Do not eat, drink or smoke when using this product NIOSH/ 15 min. Ceiling: 0.002 mg/m3 P271 – use only outdoors or in a well-ventilated area. 8.2 Appropriate Engineering Controls P273 – Avoid release to the environment Not expected to require any special ventilation. P280 – Wear protective gloves 8.3 Personal Protective Equipment: P301+P310 – IF SWALLOWED immediately call a POISON CENTER or Eyes: Use safety glasses. doctor Skin: Wear protective gloves and clean body-covering clothing. P302+P352 – IF ON SKIN wash with plenty water. Respiratory: Not expected to require personal respirator usage. P304+P340 – IF INHALED remove person to fresh air and keep comfortable for breathing. 9. PHYSICAL AND CHEMICAL PROPERTIES P305+P351+P338 – IF IN EYES rinse cautiously with water for several minutes. Remove contact lenses, if presentand easy to do. Continue 9.1 Information on basic physical and chemical properties rinsing. Apprearance: Colorless liquid P308+P313 – IF exposed or concerned, get medical advice/attention Odor: Odorless P311+P312 – Call a POISON CENTER or doctor if you feel unwell Odor threshold: Not determined P330 – Rinse mouth pH: Not determined P332 – If skin irritation occus, get medical advice/attention Melting point/freezing point: 32ºC P337+P313 – If eye irritation persists, get medical advice/attention Initial boiling point and boiling range: 212ºC P362+P364 – Take off contaminated clothing and wash it before reuse. P403+P233 – Store in a well-ventilated place. Keep container tightly Flashpoint: Not determined closed. Evaporation Rate (Water=1): Not determined P405 – Store locked up Flammability: Not determined P501 – Dispose of contents/container in accordance with local, regional, Lower Flammability Limit: Not determined national and international regulations. Upper Flammability Limit: Not determined Vapor Pressure: 0.7 (water)