W3S83Series

Physical hazards

Not classified.

Health hazards

Reproductive toxicity (fertility, the unborn Category 1B child)

Environmental hazards

Not classified.

Signal word

Danger

Hazard statements

May damage fertility or the unborn child.

Prevention

Wear protective gloves/protective clothing/eye protection. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.

Response

IF exposed or concerned: Get medical advice/attention.

Storage

Store locked up.

Disposal

Dispose of contents/container in accordance with local/regional/national/international regulations.

2.3 Other hazards

Complete toxicity data are not available for this specific formulation. Potential routes of overexposure to this product are skin and eye contact. Inhalation of vapor and ingestion are not expected to be significant routes of exposure for this product under normal use conditions.

Additional information

2-pyrrolidone: Specific Concentration Limits, Reproductive toxicity Category 1B, fertility or the unborn child 3%. Mixture classification threshold based on data related to developmental toxicity in animals. No adverse effects on sexual function or damage to fertility have been observed in an animal study. See Section 11. 4. First aid instructions First aid measures for different exposure routes Inhalation Move to fresh air. If symptoms persist, get medical attention. Skin contact Wash affected areas thoroughly with mild soap and water. Get medical attention if irritation develops or persists. Eye contact Do not rub eyes. Immediately flush with large amounts of clean, warm water (low pressure) for at least 15 minutes or until particles are removed. If irritation persists get medical attention. Ingestion If ingestion of a large amount does occur, seek medical attention. Main symptoms Not available. Personal protection for first-aid Not available. responders Notes to physician Not available. Special first aid equipment Not available. 5. Firefighting procedure Extinguishing media Suitable extinguishing CO2, water, dry chemical, or foam media Extinguishing media which None known. must not be used for safety reasons Specific hazards during fire Not available. fighting Special fire fighting Not available. procedures Protection of fire-fighters Not available. Specific methods None established.

Precautionary statements

Containment procedures Dike the spilled material, where this is possible. Absorb with inert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recover using pumps. Environmental precautions Do not let product enter drains. Do not flush into surface water or sanitary sewer system. Methods for cleaning up Soak up with inert absorbent material.

Further information

Soak up with inert absorbent material. Slowly vacuum or sweep the material into a bag or other sealed container. Dispose of in compliance with federal, state, and local regulations. See also section 13 Disposal considerations. Personal precautions Wear appropriate personal protective equipment. 7. Handling and storage Precautions for safe handling Avoid contact with skin, eyes and clothing. Conditions for safe storage, Keep out of the reach of children. Keep away from excessive heat or cold. including any incompatibilities 8. Means of reducing exposure and personal protection Engineering measures to Use in a well ventilated area. reduce exposure Provide adequate ventilation. Occupational exposure limits No exposure limits noted for ingredient(s). Biological limit values No biological exposure limits noted for the ingredient(s). Exposure guidelines Exposure limits have not been established for this product. Personal protective equipment Respiratory protection For use other than intended use (such as in the event of a large spill), goggles and respirators may be required. Hand protection Not available. Eye protection Not available. Skin and body protection Use personal protective equipment to minimize exposure to skin and eye. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Appearance Physical state Liquid. Form Liquid. Color Black. Odor Not available. pH 7.5 - 8 Melting point/freezing point Not available. Initial boiling point and boiling Not determined range Decomposition temperature Not available. Flash point > 230.0 °F (> 110.0 °C) Pensky-Martens Closed Cup Flammability Not available. Auto-ignition temperature Not available. Upper/lower flammability or explosive limits Flammability limit - lower Not determined (%) Flammability limit - upper Not available. (%) Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Oxidizing properties Not determined Vapor pressure Not determined Density 1.03 g/cm3 Solubility(ies) Solubility (water) Soluble in water Partition coefficient Not available. (n-octanol/water) Evaporation rate Not determined Percent volatile 8 % estimated Vapor density >= 1 (air = 1.0) VOC < 86 g/l 10. Stability and reactivity Reactivity Not available. Chemical stability Stable under recommended storage conditions. Conditions to avoid Not available. Possibility of hazardous Will not occur. reactions Incompatibility Incompatible with strong bases and oxidizing agents. Hazardous decomposition Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon products dioxide and/or low molecular weight hydrocarbons. Materials to avoid Not available. 11. Toxicological information Information on likely routes of exposure Inhalation Under normal conditions of intended use, this material is not expected to be an inhalation hazard. Skin contact Contact with skin may result in mild irritation. Eye contact Contact with eyes may result in mild irritation. Ingestion Health injuries are not known or expected under normal use. Toxicological data Not available. Acute toxicity Based on available data, the classification criteria are not met. Components Species Test Results 2-pyrrolidone (CAS 616-45-5) Acute Oral LD50 Rat > 5000 mg/kg Skin corrosion/irritation Based on available data, the classification criteria are not met. Serious eye damage/eye Based on available data, the classification criteria are not met. irritation Not classified as an irritant according to, OECD 405. Respiratory or skin sensitization Respiratory sensitization Based on available data, the classification criteria are not met. Skin sensitization Based on available data, the classification criteria are not met. Germ cell mutagenicity Based on available data, the classification criteria are not met. Carcinogenicity Based on available data, the classification criteria are not met. Reproductive toxicity May damage fertility or the unborn child. 2-pyrrolidone: This component showed developmental effects only at high doses that were toxic to pregnant test animals (OECD Testing Guideline 414: Prenatal Developmental Toxicity Study). Uptake by people of small doses is not expected to cause developmental toxicity. This component has not caused adverse effects on sexual function or damage to fertility in an animal study (OECD Testing Guideline 443: Extended One-Generation Reproductive Toxicity Study). Specific target organ toxicity - Based on available data, the classification criteria are not met. single exposure Specific target organ toxicity - Based on available data, the classification criteria are not met. repeated exposure Aspiration hazard Based on available data, the classification criteria are not met. Chronic effects Not available. Other information Complete toxicity data are not available for this specific formulation 12. Environmental information Aquatic toxicity LC50/96h/Fathead minnows =>750mg/l EC50/48h/daphnia => 100mg/l, OECD 202 EC50/72h/algae => 100 mg/l , OECD 201 Ecotoxicity LC50/96h/Fathead minnows =>750mg/l EC50/48h/daphnia => 100mg/l, OECD 202 EC50/72h/algae => 100 mg/l , OECD 201 Components Species Test Results 2-pyrrolidone (CAS 616-45-5) Aquatic Crustacea EC50 Water flea (Daphnia pulex) 13.21 mg/l, 48 hours Trimethylolpropane (CAS 77-99-6) Aquatic Crustacea EC50 Daphnia 102, 48 Hours Fish LC50 Fish 1000, 96 Hours Environmental effects Not available. Persistence and degradability Mobility in soil Not available. Other information Not available. 13. Dangerous substance disposal methods Disposal instructions Do not allow this material to drain into sewers/water supplies. Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations. Dispose of in compliance with Israeli Ministry of the Environment and local regulations. Waste from residues / unused Not available. products Contaminated packaging Not available. Special precautions Not available. 14. Transport information DOT UN number Not available. UN proper shipping name Not Regulated Transport hazard class(es) Class Not available. Subsidiary risk - Packing group Not available. Environmental hazards Marine pollutant No Special precautions for user Not available. IATA UN number Not available. UN proper shipping name Not Regulated Transport hazard class(es) Class Not available. Subsidiary risk - Packing group Not available. Environmental hazards No Special precautions for user Not available. IMDG UN number Not available. UN proper shipping name Not Regulated Transport hazard class(es) Class Not available. Subsidiary risk - Packing group Not available. Transport hazard class(es) Marine pollutant No EmS Not available. Special precautions for user Not available. ADR UN number Not available. UN proper shipping name Not Regulated Transport hazard class(es) Class Not available. Subsidiary risk - Hazard No. (ADR) Not available. Tunnel restriction code Not available. Packing group Not available. Environmental hazards No Special precautions for user Not available.