HERCULAN SR 320 { B }

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Code

Statements

H315

Causes skin irritation

PBT Substances

08/03/2016 information: aid H317; Sens. H317; Sens. 4,4'-Methylenediphenyldiisocyanate, } measures information: 1, STOT - system: of components: characterization

vPvB Substances

4) HERCULAN first and (scale 0 0 1, - measures Carc. SE H334; 320 SR 3, on H335 2, diphenylmethane-4,4'-diisocyanate H335 2, methylenebis(4-isocyanatobenzene) Mixtures assessment { B H351; STOT oligomeric - doctor. Rinse Immediately Immediately In case Supply fresh Immediately For the RE homopolymer, environment no There ingredients Not Not FIRE 1 HEALTH 1 0 P501 P403+P233 P405 P362+P364 P302+P352 P314 P337+P313 P333+P313 P308+P313 P363 P321 P312 P304+P340 P342+P311 P202 P201 P272 Safety 2, opened wording H373; applicable. applicable. of reaction are REACTIVITY acc. eye rinse wash *3 0 1 of air products and to Fire P305+P351+P338 for with with to observation Symptoms the and Health 1 remove Get Call on in Do

SECTION 2: Hazards identification

if butane-1, need ingredients of 4, irritation irritation or POISON INHALED: experiencing present Rinse handle special Contaminated international locked SKIN: medical Sheet minutes patient a may soiled [(methylethylene)bis(oxy)]dipropanol 3-diol, contaminated rash contaminated (see up. and all or to and be hours by phrases Skin present under rinse stably doctor. after even regulations. well-ventilated with Irrit. persists: concerned: Irrit. Remove respiratory advice/attention Get occurs: clothing safety clothing the on easy cautiously instructions refer to mentioned Get this in to CENTER/doctor person do. with 2, thoroughly. which the section contents/container place. clothing plenty if running in side water. feel you occur Get medical product. if you water H315; precautions be before must use. H315; in are of Keep and medical before label). to symptoms: not after water. this position 16. classified wash symptoms accident. hours; a Eye H319; Eye H319; 2,4'-diisocyanatodiphenylmethane, hazardous reuse. medical advice/attention. reuse. feel fresh Call Continue for minutes. read Reviewed On several 2A, andpropane-1,2-diol as for it before Irrit. advice/attention. Irrit. unwell. section. rinsing. several allowed If accordance container unwell. air have with tightly and POISON been out keep of the transportation. persist, Skin therefore Skin (Contd. closed. and 1,1'- Remove (Contd. to on health on comfortable CENTER/doctor. workplace. Page 25 50 of page consult - 100% understood. page or US 3) a medical the local/regional/national/ for contact 1) Trade · · · · · · · · · 7 · · · · 6 Specific Further storage · · Information ·

Storage

Conditions explosions Information · · 5 protection sections one the 320 conditions: common and any and equipment substance attention both { B } or No Store Store Keep Protect Not No Keep Prevent Open Ensure No See See See Do not Mount Do not Mount During No No If further a from required. special and special Section Section Section with allow Formation further symptoms acc. relevant Safety in in receptacle frost. incompatibilities respiratory formation handle 13 for for adequate Ensure Dispose Absorb respiratory cool respiratory toxic or alcohol CO2, relevant dry inhale heating good to requirements. protective receptacle

Precautionary statements

Handling: Handling · · · · Reference cleaning Methods and Personal Protective for Advice mixture Special Suitable and special Indication and acute Most Information After name: Reviewed On facility: end for receptacles: Requirements and emergency to up: and Accidental any swallowing: Extinguishing of for and use(s) information about Environmental safe about other Fire-fighting important for media delayed 08/03/2016 to fires: material release equipment: firefighters arising extinguishing be treatment doctor: safe storage by procedures from measures immediate symptoms about SR met handling for protective agents: HERCULAN needed and including against measures medical storerooms containment in effects,

Disposal

liquid-binding of gases case fighting consult 8 7 ventilation/exhaustion to information. safe surface device. Use device. possible measures place. conditions. tightly of measures contaminated enter explosion for

Contains

condition Information basic rate density °C pressure: 08/03/2016 limits: density Decomposition 20 igniting: threshold: and on / reactivity with temperature: gaseous): range: (68 physical chemical SR / conditions (n-octanol/water): be reactions chemical properties and 320 { to B } No No No No No 62.7 0.0 0.0 Not Not Not Not Not 1.2 Not 0.0 0.4 Not 520 Not 235 >300 Not Not Fluid further further further relevant relevant further decomposition % % relevant miscible determined. determined. g/cm³ % % determined. or determined. determined. determined. is (10.014 (968 determined. (455 % not determined. °F) According °F) properties determined. Vol Vol acc. Safety Product °C dangerous does not applicable. (>572 Undetermined. Characteristic to reactions difficult product

TOXICOLOGICAL INFORMATION

mg/l listed. Toxicology Agency categories repeated are toxicological decomposition > 200 ingredients (International OECD OECD without OECD LC50/1 LC50/4 LD50 LD50 STOT OECD OECD OECD OECD without OECD 1640 BCF LC50/4 LD50 LD50 that (Occupational toxicological 08/03/2016 effect: 474 406 453 h h 474 405 406 404 453 h HERCULAN is (algae) methylenebis(4-isocyanatobenzene) Safety for guidelines - guidelines methylenebis(4-isocyanatobenzene) SR information Program) diphenylmethane-4,4'-diisocyanate information: positive 2.24 0.31 >9400 >2000 negativ irriterend negativ 0.49 > > 9400 5000 for & effects products: B homopolymer, (Guinea oligomeric (rabbit) (rat) (rabbit) (huit) Health (Guinea years (rabbit) Research (rat) homopolymer, (Mammalian sensitising (EC50) (rat) mg/kg mg/kg 2 irriterend sensibiliserend (rat) (2 (rat) mg/kg mg/kg oligomeric { Sensitising mg/l mg/l diphenylmethane-4,4'-diisocyanate Categorie sensitizing mg/l on } (2 (rat) (rat) (rabbit) reaction Cancer) Irritant Harmful The Irritant Erythrocyte (Guinea pig) 5 pig) 5 reaction classification years products Administration) for preparations product Sensitization Sensitization Irritating effect to skin pig) days per days per products No dangerous acc to Safety possible possible Micronucelus week)

UN Number

Transport in C Persistence hazards class(es) name information methods vPvB potential environmental mg/l mg/l mg/l according user IATA for IATA IMDG, considerations degradability Modified fish) 1000 1000 BCF SR assessment information systems daphnia) LC50) daphnia) { mg/l mg/l to MITI Daphnia Bacterie) fish) daphnia) (Bacterie) 320 Annex Test EC50) II II)) Magna) diphenylmethane-4,4'-diisocyanate NOEC) (EC50) of MARPOL73/78 be applicable. applicable allow hazard to Safety cleaning Empty sewage Must No Not Not sewage Do not Water No No No not further further further further acc and system relevant system class relevant relevant relevant Not Not No Void contaminated disposed undiluted applicable

2.2 Label elements

Occupational toxicity listings): substances): } by P201 P272 P271 P264 P280 P280 P284 P260 H373 H335 H351 H317 H334 H319 H315 H332 Danger GHS07, The Concentration) ACGIH) toxicity: regulations/legislation acc. Safety for May May cause cause Suspected cause cause May May Causes Causes Harmful skin GHS08 product is and males: females: to Safety Obtain Wash Wear Wear not damage allergy if inhaled. classified

2.1 Classification of the substance or mixture

3 7) methods 5) * the UN · · · · · · · · · · · · · 14 · · · · 13 · · · · · · · · · · Trade Special Marine DOT, Class DOT, DOT, Waste Other vPvB: PBT: Results OECD OECD OECD OECD OECD LogPow 101-68-8 OECD OECD OECD OECD OECD OECD IBC Packing General Mobility Behavior name: date Transport ADR, ADR, Transport ADR, proper ADR, Uncleaned Disposal Additional in bulk 302 211 209 203 202 pollutant: IMDG, 471 302 211 209 ADN, hazard ADN, 203 202 ADN, Code Recommendation: precautions Recommendation: Environmental treatment group shipping Bioaccumulative and 0 > > > > packagings: adverse effects 0 PBT and notes: ecological soil % 10 of 100 200 negativ % (static) (static) 10 >100 (static) (static) >1000 >1000 HERCULAN 08/03/2016 in UN-Number Transport C in C Persistence hazards: class(es) name information methods vPvB potential environmental mg/l mg/l mg/l according user ≥ IATA for IATA IMDG, considerations degradability (Modified (fish) 1000 1000 BCF SR assessment information: systems: (daphnia) (LC50) (daphnia) { mg/l mg/l to MITI (Daphnia (Bacterie) (fish) (daphnia) (Bacterie) 320 Annex Test (EC50) B II (II)) Magna) diphenylmethane-4,4'-diisocyanate (NOEC) (EC50) } of MARPOL73/78 be applicable. applicable. allow hazard to Safety cleaning. Empty sewage Must No Not Not sewage Do not Water No No No not further further further further acc. and system. relevant system. class relevant relevant relevant Not Not No Void contaminated disposed undiluted 1 applicable. OSHA packagings Data information product information information information HCS Sheet of together or thoroughly. quantities slightly with available. large (Self-assessment): available. available. available. They household of can it to garbage. reach for be hazardous recycled ground water Do not after allow water, Reviewed (Contd. thorough product water (Contd. on and of page to course Page page US 8) proper reach or 6) 08/02/2016 7/10 43.0.11 * UN Trade Printing · · · · · · · · · · · · · · · · · · · · 15 Hazard Signal Hazard GHS None label the NIOSH-Ca of 101-68-8 MAK None TLV of · 101-68-8 EPA None of None of None of None of 101-68-8 TSCA 101-68-8 Section None of Section Sara Safety, name: date statements Hazard-determining pictograms elements ingredients (National ingredients (Threshold Cancerogenity ingredients known ingredients known is Limit ingredients known (Environmental ingredients known 65 is to is to is to is to ingredient (Specific is 08/03/2016 Precautionary word (German the Chemicals the Chemicals the Chemicals the Chemicals Proposition (Toxic 313 the 355 health Regulatory "Model statements Maximum categories Substances (extremely Regulation": HERCULAN and is components Workplace cancer: Control hazardous environmental 320 listed. Institute listed. Value listed. cause toxic listed. information SR diphenylmethane-4,4'-diisocyanate established diphenylmethane-4,4'-diisocyanate Act): diphenylmethane-4,4'-diisocyanate chemical B for Protection Agency) developmental reproductive of { labeling: Occupational toxicity listings): substances): } by P201 P272 P271 P264 P280 P280 P284 P260 H373 H335 H351 H317 H334 H319 H315 H332 Danger GHS07, The Concentration)