Technovit 4004 liquid

Classification system

The classification is in line with current EC lists. It ig expanded, however, by information from technical literature and by information furnished by supplier companies. , afar inhalation Supply resh air; consult doctor ine case of. symploms. a * After skin contact Instantly wash with water and soap and rinse thoroughly. + After eye contact ‘ Rinse opened eye for several minutes under running water. Ifsymptoms persist, consult doctor. + After swallowing Do not induce vomiting; instantly cal for medical help. a (Contd. on page 2) FTPRTITeTTS Rabe Farther. 23/88/2061 11:14 4137892786 PACE 7 Page 2/6 _ Material Safety Data Sheet my According to 91/155 EC Printing date 20.09.2001 Reviewed On 26.04.2001 Trade name: Technovit 4004 liquid (Contd. of page 3) . ‘Sudtable extinguishing agents C02, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. fon sand, extinguishing powder. Do not use water. - For safety reasons unsultable extinguishing agents Water. Water with a full water jet. - Special hazards caused by the material, its products of combustion ar flue gasest Formation of toxic gases ts possible during heating or in case of fire, "Protective equipment: No special measures required, + Person-related safety precautions: Wear ‘proteciive equipment, Keep unprotected persons away. + Measures for environmental protection: Prevent matertal from reaching sewage system, holes and cellars, + Measures for cleaning/collecting: Absorb with liquid-binding material diatomite, universal binders, sawdust, for small amounts tissues), Do Meo ash with water or aqueous cleansing agents

Additional information

No dangerous materials are released Handling - Information for safe handling: Keep containers tightly sealed, ‘Information about protection against explosions and fires: Keep ignition sourceg away - Do not smoke, Protect against electrostatic charges. about design of vechnlcal systems $ No further data; see item 7. + Components with critical values that require monitoring at the workplace: 40-62-6 methyl methacrylate (> 90%) OES) Short-term value: 416 mg/m’, [00 ppm Long-term value: 208 mg/m’, 50 ppm CAS No, Designation of material” % Tyne Value Unit Not required. The lisis that were valid during the compilation were used as basis ‘ Personal protective equipment ' Genaral protective and hygienic measures | Keep away from foodstuffs, beverages and food, Instantly remove any soiled and impregnated garmenis. Wash hands during breaks and at the end of the work. (Contd. on page 3) ape 89/86/2001 41:14 4137992786 PAGE 48 Page 3/6 - Material Safety Data Sheet . According to 91/155 EC Reviewed On 26.04.2001 Printing date 10.09.2001 Trade name: Technovit 4004 liquid (Contd, of page 2) Avoid contact with the eyes and skin. . + Breathing equipment: Not neccessary with efficient local exhaust. If exposition to vapours #8 possible, use breathing protective mask (filter A). - > Protection of handst Uf skin contact cannot be avolded, protective gloves are recommended to avoid possible sensitization, - ow PVA gloves Solvent resistant gloves Eye protection: Protective goggles are recommended. » Body protection: Light weight protective clothing + Form: Fluid « Colour: Colourless « Smell: Characteristic + Change in condition + Melting point/Melting vange: Not determined - Boiling point/Boiling range: 100°C Flash point: 40°C + Ignition temperature: 430,0°C - Self-inflamamability: Product is not selfigniting. » Danger of explosion: Product is not explosive, However, formation of explosive qir/| vapour mixtures is possible. + Critical values for explasion: » Lower: 21 Vol% + Upper: 12.5 Val % + Steam pressure at 20°C? 47,0 hPa ‘Density at 20°C 0.940 gicem! + Solubility in / Miscibility with + Waters Not miselble or difficult to mix ' Visnosity: + dynamedle at 20°C: i mPas + Solvent content: + Organic solveris: 97.5% + Solide concent? 1.0% ~ eg u us woth. + Conditions to be aveldedt No decomposition if used and stored according to speaifications. + Dangerous reactions No dangerous reactions known - Dangerous products of composition: None (Contd. on page 4) ob — a9/ae/20a1 11:14 4137892786, PAGE 9 Page 4/6 ~ — Material Safety Data Sheet _ According to 91/155 EC Reviewed On 26.04.2001 Printing date 10.09.2001 |_ Trade name: Technovit 4004 liquid Coutd. of page 3) + Additional information: Uf stored longer than recommended and/or above recommended temperature, product may polymerize generating heat. ti herecriey a is + Acute toxicity: + Primary irritant effect: . -on the skin: Irritant for skin and mucous membranes, + on the aye: Jrvitant effect. » Sensitization: Sensitization possible by skin contact. - Additional taxicological information: The product shows the following dangers according to the calculation method of the General EC - Classification Guidelines for Preparations as issued in the latest version: drritant + General notes: Water hazard class 2 (calculated according to VwVwS): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system, Danger to drinking water ifeven small quantities leak into soil. + Product: + Recommendation Must not be disposed of together with household garbage. De not allow product to reach sewage system, Small quantities can be palymerized with the matching system components) and the cured solid matertal can be disposed af with the regular garbage. Larger quantities must be disposed of following the regulations of the local authorities. - Waste disposal key number: 55512 European waste catalogue ‘ 16 03 0s other waste containing organic chemicals, ey. fab chemicals not otherwise Specified + Uncleaned packagings: + Recommendation: Disposal must be made according to official regulations. __ *| ier informally fs ' Land transport ADR/RID and GGVS/GGVE (cross-border/domestic) - ADR/RID-GGVSVE Class: J Flammable liquids. + Numbee/Latter: gb -Kemler Number: 33 ' UN-Number: 1993 Label a (Contd, on page 5) ca 49/88/2081 iiiid 4137892786 PACE 18 Page 5/6 a Material Safety Data Sheet According to FIALSS EC Printing date 10.09.2001 Reviewed on 26.04.2001 Trade name: Technovit 4004 liquid (Contd, of page 4) + Designation of goods: — Flammable liquid, 1.0.8. (contains methyl methacrylate monomer, stabilized) + Maritime transport MDG/GGVSea: a Sd - IMDG/GGVSea Class! + Page: 3230 - UN Number: 1993 + Packaging group: il + EMS Number: 3-07 + MFAG: 340 ' Marine pollutant: No ' Correct technical name: Flammable liquid, n.0.s,, containy methyl methacrylate monomer, inhibited Air transport ICAQ-T2 and IATA-BGR: o ICAO/IATA Class: 3 * UNAD Number: 1993 - Packaging group: ris ‘ Correct technical name: Flammable liquid, n.o.s., contains methyl methacrylate monomer, inhibited "4 Designation according to EC guidelines: The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Matertals (GefStoffV) Code letter and hazard designation of product: Xi Irritant F Highly flammable + Hazard-determining components af labelling: mathyl methacrylate 2-(2H-Benzotriazol-2-yl)-4-methylphenoal _ ‘ Risk phrases: il Highly flammable. 36/37/38 Irritating to eyes, respiratory system and skin, 43 May cause sensitization by skin contact. > Safety phrases: 9 Keep container in a well-ventilated place, 16 Keep away from sources of ignition - No smoking. 24 Avold contact with skin. 37 Wear suitable gloves. 60 This material and its container must be disposed of as hazardous waste. . (Contd. on page 6) cat 99/08/2081 11:14 4137892786 PAGE 11 a Page 6/6 Materlal Safety Data Sheet According to 91/155 EC Reviewed on 26.04.2001 Printing date 10.09.2001 Trade name: Technovit 4004 liquid (Contd. of page 5)

Storage

+ Requirements to be met by storerooms and containers: Store in cool location. Information about storage in one common storage facility: Not required.

Further information

about storage conditions Keep cool, if possible (not above 25 °C), Store in cool, dry conditions in well sealed containers, + Storage class ‘ Class according to regulation on inflammabte liquids: AI