Sista PU Foam TR

Henkel South Africa (PTY) Ltd

Revision date : 2018-08-13

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GHS02 GHS08 GHS07
Health risk rating 5
Safety risk rating 4
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

EC/CAS

202-966-0/101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

10-30%

EC/CAS

287-477-0/9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

10-20%

EC/CAS

287-477-0/85535-85-9

Name of the chemical

Alkanes, C14-17, chloro

Concentration

10-20%

EC/CAS

227-534-9/5873-54-1

Name of the chemical

2,4’-Methylenediphenyl diisocyanate

Concentration

5-<15%

EC/CAS

270-704-2/68476-85-7

Name of the chemical

Petroleum gases, liquefied

Concentration

5-<10%

EC/CAS

200-857-2/75-28-5

Name of the chemical

iso-Butan, enthält  0,1% Butadien

Concentration

5-<10%

EC/CAS

500-039-8/25322-69-4

Name of the chemical

polypropyleneglycol

Concentration

1-<5%

General Information

Revision date

2018-08-13

Product name

Sista PU Foam TR

1.2.1 Relevant identified uses

Foam, 1-component with propellant gas

Icons in SDS

GHS02 GHS07 GHS08 M004 M009 M010 M011 M017

Company Information

company name

Henkel South Africa (PTY) Ltd

e-mail address of the competent person responsible for the Safety Data Sheet

ua-productsafety_za@henkel.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H222, H229, H315, H317, H319, H334, H335, H351, H362, H373, H413

Hazard statements

Code

Statements

H222

Extremely flammable aerosol

Section 2

SECTION 2: Hazards identification

Classification (CLP) Classification of the substance or mixture

2.2 Label elements

CLP) Hazard pictogram: (DPD) F+ - Extremely flammable Xn - Harmful

Contains

Diphenylmethane diisocyanate, isomers and homologues Alkanes, C14-17, chloro Diphenylmethane diisocyanate, isomers and homologues

Signal word

Danger

Hazard statements

H222 Extremely flammable aerosol. H229 Pressurised container: May burst if heated. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H362 May cause harm to breast-fed children. H373 May cause damage to organs through prolonged or repeated exposure. H413 May cause long lasting harmful effects to aquatic life. R12 Extremely flammable. R40 Limited evidence of a carcinogenic effect. R42/43 May cause sensitization by inhalation and skin contact. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R20 Harmful by inhalation. R36/37/38 Irritating to eyes, respiratory system and skin. R64 May cause harm to breastfed babies. R53 May cause long-term adverse effects in the aquatic environment.

Precautionary statements

P102 Keep out of reach of children. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. P501 Dispose of contents/container in accordance with national regulation. S2 Keep out of the reach of children. S23 Do not breathe vapour. S24/25 Avoid contact with skin and eyes. S29/56 Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S46 If swallowed, seek medical advice immediately and show this container or label. S51 Use only in well-ventilated areas.

Prevention

No smoking. P211 Do not spray on an open flame or other ignition source. P251 Do not pierce or burn, even after use. P260 Do not breathe mist/vapours. P263 Avoid contact during pregnancy and while nursing. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/eye protection.

Additional information

Contains isocyanates. See information supplied by the manufacturer. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 °C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Keep out of the reach of children

2.3 Other hazards

Information according to XVII. 56 REACH Persons already sensitised to diisocyanates may develop allergic reactions when using this product. Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used. Solvents contained in the product evaporate during processing and their vapors can form explosive/highly inflammable air/vapor mixtures. Pregnant women should absolutely avoid inhalation and skin contact. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria.

2.1 Classification of the substance or mixture

Classification (CLP): Flammable aerosols Category 1 H222 Extremely flammable aerosol. H229 Pressurised container: May burst if heated. Skin irritation Category 2 H315 Causes skin irritation. Skin sensitizer Category 1 H317 May cause an allergic skin reaction. Serious eye irritation Category 2 H319 Causes serious eye irritation. Respiratory sensitizer Category 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Specific target organ toxicity - single exposure Category 3 H335 May cause respiratory irritation. Target organ: respiratory tract irritation Carcinogenicity Category 2 H351 Suspected of causing cancer. Effects on or via lactation H362 May cause harm to breast-fed children. Specific target organ toxicity - repeated exposure Category 2 H373 May cause damage to organs through prolonged or repeated exposure. Chronic hazards to the aquatic environment Category 4 H413 May cause long lasting harmful effects to aquatic life. Classification (DPD): F+ - Extremely flammable R12 Extremely flammable. Xn - Harmful carcinogenic, category 3 R40 Limited evidence of a carcinogenic effect. Xn - Harmful R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R20 Harmful by inhalation. Xi - Irritant R36/37/38 Irritating to eyes, respiratory system and skin. Sensitizing R42/43 May cause sensitization by inhalation and skin contact. Dangerous for the environment R53 May cause long-term adverse effects in the aquatic environment. R64 May cause harm to breastfed babies.

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