LOCTITE AA 3321 LC KNOWN AS LOCTITE 3321 HV ADH

Hazard statements (CLP)

H302, H315, H317, H318, H335, H400, H410

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

Classification (CLP) Classification of the substance or mixture

2.2 Label elements

(CLP)

Contains

Isobornyl acrylate 2-Propenamide, N,N-dimethyl- Diphenyl-2,4,6-trimethylbenzoyl phosphine oxide 2-Hydroxyethyl acrylate

Signal word

Danger

Hazard statements

H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects.

Precautionary statements

***" ***For consumer use only: P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P501 Dispose of waste and residues in accordance with local authority requirements*** P261 Avoid breathing vapors. P302+P352 IF ON SKIN: Wash with plenty of soap and water.

Prevention

P273 Avoid release to the environment. P280 Wear protective gloves/eye protection.

Response

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

Other hazards

Care should be taken during the cure of these products by UV radiation to avoid exposure of the skin and especially of the eyes to direct or reflected UV radiation as long term effects could be harmful. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria

2.1 Classification of the substance or mixture

Classification (CLP): Acute toxicity Category 4 H302 Harmful if swallowed. Route of Exposure: Oral Skin irritation Category 2 H315 Causes skin irritation. Serious eye damage Category 1 H318 Causes serious eye damage. Skin sensitizer Category 1 H317 May cause an allergic skin reaction. Specific target organ toxicity - single exposure Category 3 H335 May cause respiratory irritation. Target organ: respiratory tract irritation Acute hazards to the aquatic environment Category 1 H400 Very toxic to aquatic life. Chronic hazards to the aquatic environment Category 1 H410 Very toxic to aquatic life with long lasting effects. 2.2. Label elements Label elements (CLP): SDS No.: 153595 V014.0 LOCTITE AA 3321 LC KNOWN AS LOCTITE 3321 HV ADH Hazard pictogram: Contains Isobornyl acrylate 2-Propenamide, N,N-dimethyl- Diphenyl-2,4,6-trimethylbenzoyl phosphine oxide 2-Hydroxyethyl acrylate Signal word: Danger Hazard statement: H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects. Precautionary statement: "***" ***For consumer use only: P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P501 Dispose of waste and residues in accordance with local authority requirements*** Precautionary statement: P261 Avoid breathing vapors. Prevention P273 Avoid release to the environment. P280 Wear protective gloves/eye protection. Precautionary statement: P302+P352 IF ON SKIN: Wash with plenty of soap and water. Response P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. 2.3. Other hazards Care should be taken during the cure of these products by UV radiation to avoid exposure of the skin and especially of the eyes to direct or reflected UV radiation as long term effects could be harmful. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria. SECTION 3: Composition/information on ingredients 3.2. Mixtures SDS No.: 153595 V014.0 LOCTITE AA 3321 LC KNOWN AS LOCTITE 3321 HV ADH Declaration of the ingredients according to CLP (EC) No 1272/2008: Hazardous components EC Number content Classification CAS-No. REACH-Reg No. Isobornyl acrylate 227-561-6 25- 50 % Skin Irrit. 2 5888-33-5 01-2119957862-25 H315 Eye Irrit. 2 H319 STOT SE 3 H335 Skin Sens. 1B H317 Aquatic Acute 1 H400 Aquatic Chronic 1 H410 2-Propenamide, N,N-dimethyl- 220-237-5 10- 20 % Acute Tox. 3; Oral 2680-03-7 01-2119971262-39 H301 Acute Tox. 3; Dermal H311 Eye Dam. 1 H318 Ethanone, 2,2-dimethoxy-1,2-diphenyl- 246-386-6 1- < 3 % Aquatic Chronic 1 24650-42-8 01-2120000336-73 H410 Aquatic Acute 1 H400 [3-(2,3- 219-784-2 1- < 3 % Eye Dam. 1 Epoxypropoxy)propyl]trimethoxysilane 01-2119513212-58 H318 2530-83-8 Diphenyl-2,4,6-trimethylbenzoyl phosphine 278-355-8 1- < 3 % Repr. 2 oxide 01-2119972295-29 H361f 75980-60-8 Aquatic Chronic 2 H411 Skin Sens. 1B H317 Camphene 201-234-8 0,1- < 1 % Aquatic Acute 1 79-92-5 H400 Aquatic Chronic 1 H410 Flam. Sol. 2 H228 Eye Irrit. 2 H319 1,7,7-Trimethyltricyclo[2.2.1.02,6]heptane 208-083-7, 208- 0,1- < 1 % Eye Irrit. 2 508-32-7 083-7 H319 Aquatic Acute 1 H400 Aquatic Chronic 1 H410 2-Hydroxyethyl acrylate 212-454-9 0,1- < 0,2 % Acute Tox. 4 818-61-1 01-2119459345-34 H302 Acute Tox. 3 H311 Skin Corr. 1B H314 Skin Sens. 1 H317 Aquatic Acute 1 H400 Aquatic Chronic 3 H412 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available. SDS No.: 153595 V014.0 LOCTITE AA 3321 LC KNOWN AS LOCTITE 3321 HV ADH SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Move to fresh air. If symptoms persist, seek medical advice. Consideration should be given to the possible effects of a faulty UV source (Stray radiation, ozone). Skin contact: Rinse with running water and soap. Obtain medical attention if irritation persists. Eye contact: Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. 4.2. Most important symptoms and effects, both acute and delayed INGESTION: Nausea, vomiting, diarrhea, abdominal pain. SKIN: Redness, inflammation. SKIN: Rash, Urticaria. RESPIRATORY: Irritation, coughing, shortness of breath, chest tightness. After eye contact: Corrosive, may cause permanent damage to eyes (impairment of vision). 4.3. Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: Carbon dioxide, foam, powder Extinguishing media which must not be used for safety reasons: None known 5.2. Special hazards arising from the substance or mixture In the event of a fire, carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx) can be released. 5.3. Advice for firefighters Wear self-contained breathing apparatus. Wear protective equipment. Additional information: In case of fire, keep containers cool with water spray. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid skin and eye contact. Ensure adequate ventilation. Wear protective equipment. 6.2. Environmental precautions Do not let product enter drains. SDS No.: 153595 V014.0 LOCTITE AA 3321 LC KNOWN AS LOCTITE 3321 HV ADH 6.3. Methods and material for containment and cleaning up For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Wash spillage site thoroughly with soap and water or detergent solution. Dispose of contaminated material as waste according to Section 13. 6.4. Reference to other sections See advice in section 8 SECTION 7: Handling and storage 7.1. Precautions for safe handling Ventilation will remove any ozone that may be produced by the ultra violet lamp Avoid skin and eye contact. See advice in section 8 Hygiene measures: Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Good industrial hygiene practices should be observed. 7.2. Conditions for safe storage, including any incompatibilities Refer to Technical Data Sheet 7.3. Specific end use(s) Ultraviolet adhesive SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational Exposure Limits Valid for Great Britain Ingredient [Regulated substance] ppm mg/m3 Value type Short term exposure limit Regulatory list category / Remarks Silicon dioxide 6 Time Weighted Average EH40 WEL 112945-52-5 (TWA): [SILICA, AMORPHOUS, INHALABLE DUST] Silicon dioxide 2,4 Time Weighted Average EH40 WEL 112945-52-5 (TWA): [SILICA, AMORPHOUS, RESPIRABLE DUST] Occupational Exposure Limits Valid for Ireland Ingredient [Regulated substance] ppm mg/m3 Value type Short term exposure limit Regulatory list category / Remarks Silicon dioxide 6 Time Weighted Average IR_OEL 112945-52-5 (TWA): [SILICA, AMORPHOUS, TOTAL INHALABLE DUST] Silicon dioxide 2,4 Time Weighted Average IR_OEL 112945-52-5 (TWA): [SILICA, AMORPHOUS, RESPIRABLE DUST] SDS No.: 153595 V014.0 LOCTITE AA 3321 LC KNOWN AS LOCTITE 3321 HV ADH Predicted No-Effect Concentration (PNEC): Name on list Environmental Exposure Compartment period Isobornyl acrylate aqua 5888-33-5 (freshwater) Isobornyl acrylate aqua (marine 5888-33-5 water) Isobornyl acrylate sewage 5888-33-5 treatment plant (STP) Isobornyl acrylate aqua 5888-33-5 (intermittent releases) Isobornyl acrylate sediment 5888-33-5 (freshwater) Isobornyl acrylate sediment 5888-33-5 (marine water) Isobornyl acrylate Soil 5888-33-5 Isobornyl acrylate Air 5888-33-5 Isobornyl acrylate Predator 5888-33-5 N,N-Dimethylacrylamide aqua 2680-03-7 (freshwater) N,N-Dimethylacrylamide aqua (marine 2680-03-7 water) N,N-Dimethylacrylamide aqua 2680-03-7 (intermittent releases) N,N-Dimethylacrylamide sediment 2680-03-7 (freshwater) N,N-Dimethylacrylamide sediment 2680-03-7 (marine water) N,N-Dimethylacrylamide Soil 2680-03-7 N,N-Dimethylacrylamide sewage 2680-03-7 treatment plant (STP) N,N-Dimethylacrylamide Predator 2680-03-7 2,2-Dimethoxy-1,2-diphenylethan-1-one aqua 24650-42-8 (freshwater) 2,2-Dimethoxy-1,2-diphenylethan-1-one aqua 24650-42-8 (intermittent releases) 2,2-Dimethoxy-1,2-diphenylethan-1-one aqua (marine 24650-42-8 water) 2,2-Dimethoxy-1,2-diphenylethan-1-one sewage 24650-42-8 treatment plant (STP) 2,2-Dimethoxy-1,2-diphenylethan-1-one sediment 24650-42-8 (freshwater) 2,2-Dimethoxy-1,2-diphenylethan-1-one sediment 24650-42-8 (marine water) 2,2-Dimethoxy-1,2-diphenylethan-1-one Soil 24650-42-8 [3-(2,3- aqua Epoxypropoxy)propyl]trimethoxysilane (freshwater) 2530-83-8 [3-(2,3- aqua (marine Epoxypropoxy)propyl]trimethoxysilane water) 2530-83-8 [3-(2,3- aqua Epoxypropoxy)propyl]trimethoxysilane (intermittent 2530-83-8 releases) [3-(2,3- Soil Epoxypropoxy)propyl]trimethoxysilane 2530-83-8 [3-(2,3- sewage Epoxypropoxy)propyl]trimethoxysilane treatment plant 2530-83-8 (STP) Value Remarks mg/l ppm mg/kg others 0,00092 mg/l 0,000092 mg/l 2 mg/l 0,00704 mg/l 0,145 mg/kg 0,0145 mg/kg 0,0285 mg/kg 0,12 mg/l 0,012 mg/l 1,2 mg/l 0,509 mg/kg 0,0509 mg/kg 0,0313 mg/kg 18 mg/l 0,229 mg/l 0,184 mg/l 0,0229 mg/l