Contains

Hazard statements (CLP)

H319, H335, H412

Code

Statements

H319

Causes serious eye irritation

SECTION 2: Hazards identification

Classification (CLP) Classification of the substance or mixture

2.2 Label elements

(CLP)

Signal word

Warning

Hazard statements

H319 Causes serious eye irritation. H335 May cause respiratory irritation. H412 Harmful to aquatic life with long lasting effects.

Contains

Methyl methacrylate. May produce an allergic reaction

Precautionary statements

***" ***For consumer use only: P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P501 Dispose of waste and residues in accordance with local authority requirements*** P261 Avoid breathing vapours. P337+P313 If eye irritation persists: Get medical advice/attention.

Prevention

P273 Avoid release to the environment.

Other hazards

None if used properly. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria

2.1 Classification of the substance or mixture

Classification (CLP): Serious eye irritation Category 2 H319 Causes serious eye irritation. Specific target organ toxicity - single exposure Category 3 H335 May cause respiratory irritation. Target organ: respiratory tract irritation Chronic hazards to the aquatic environment Category 3 H412 Harmful to aquatic life with long lasting effects. 2.2. Label elements Label elements (CLP): Hazard pictogram: SDS No.: 173044 V004.1 LOCTITE 275 known as Loctite 275 250ML TOTTLE EGFD. Signal word: Warning Hazard statement: H319 Causes serious eye irritation. H335 May cause respiratory irritation. H412 Harmful to aquatic life with long lasting effects. Supplemental information Contains Methyl methacrylate. May produce an allergic reaction. Precautionary statement: "***" ***For consumer use only: P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P501 Dispose of waste and residues in accordance with local authority requirements*** Precautionary statement: P261 Avoid breathing vapours. Prevention P273 Avoid release to the environment. Precautionary statement: P337+P313 If eye irritation persists: Get medical advice/attention. Response 2.3. Other hazards None if used properly. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vPvB) criteria. SECTION 3: Composition/information on ingredients 3.2. Mixtures General chemical description: Methacrylate resin based threadlocker SDS No.: 173044 V004.1 LOCTITE 275 known as Loctite 275 250ML TOTTLE EGFD. Declaration of the ingredients according to CLP (EC) No 1272/2008: Hazardous components EC Number content Classification CAS-No. REACH-Reg No. Cumene hydroperoxide 201-254-7 1- < 3 % Acute Tox. 4; Dermal 80-15-9 H312 STOT RE 2 H373 Acute Tox. 4; Oral H302 Org. Perox. E H242 Acute Tox. 3; Inhalation H331 Aquatic Chronic 2 H411 Skin Corr. 1B H314 N,N-Diethyl-p-toluidine 210-345-0 0,1- < 1 % Acute Tox. 3; Oral 613-48-9 H301 Acute Tox. 3; Dermal H311 Acute Tox. 3; Inhalation H331 STOT RE 2 H373 Aquatic Chronic 3 H412 N,N-dimethyl-o-toluidine 210-199-8 0,1- < 1 % Acute Tox. 3; Inhalation 609-72-3 H331 Acute Tox. 3; Dermal H311 Acute Tox. 3; Oral H301 STOT RE 2 H373 Aquatic Chronic 3 H412 Methyl methacrylate 201-297-1 0,1- < 1 % Flam. Liq. 2 80-62-6 01-2119452498-28 H225 STOT SE 3 H335 Skin Irrit. 2 H315 Skin Sens. 1 H317 1,4-Naphthalenedione 204-977-6 0,01- < 0,1 % Acute Tox. 3; Oral 130-15-4 H301 Skin Irrit. 2; Dermal H315 Skin Sens. 1; Dermal H317 Eye Irrit. 2 H319 Acute Tox. 1; Inhalation H330 STOT SE 3; Inhalation H335 Aquatic Acute 1 H400 Aquatic Chronic 1 H410 M factor (Acute Aquat Tox): 10 M factor (Chron Aquat Tox): 10 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available. SECTION 4: First aid measures 4.1. Description of first aid measures SDS No.: 173044 V004.1 LOCTITE 275 known as Loctite 275 250ML TOTTLE EGFD. Inhalation: Move to fresh air. If symptoms persist, seek medical advice. Skin contact: Rinse with running water and soap. Obtain medical attention if irritation persists. Eye contact: Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. 4.2. Most important symptoms and effects, both acute and delayed EYE: Irritation, conjunctivitis. RESPIRATORY: Irritation, coughing, shortness of breath, chest tightness. Prolonged or repeated contact may cause skin irritation. 4.3. Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: Foam, extinguishing powder, carbon dioxide. Extinguishing media which must not be used for safety reasons: None known 5.2. Special hazards arising from the substance or mixture In the event of a fire, carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx) can be released. Trace amounts of toxic and/or irritating fumes may be released and the use of breathing apparatus is recommended. 5.3. Advice for firefighters Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA). Additional information: In case of fire, keep containers cool with water spray. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid skin and eye contact. Ensure adequate ventilation. Wear protective equipment. 6.2. Environmental precautions Do not empty into drains / surface water / ground water. 6.3. Methods and material for containment and cleaning up For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Dispose of contaminated material as waste according to Section 13. 6.4. Reference to other sections See advice in section 8 SECTION 7: Handling and storage SDS No.: 173044 V004.1 LOCTITE 275 known as Loctite 275 250ML TOTTLE EGFD. 7.1. Precautions for safe handling Use only in well-ventilated areas. Prolonged or repeated skin contact should be avoided to minimise any risk of sensitisation. Avoid skin and eye contact. See advice in section 8 Hygiene measures: Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Good industrial hygiene practices should be observed. 7.2. Conditions for safe storage, including any incompatibilities Refer to Technical Data Sheet 7.3. Specific end use(s) Adhesive SDS No.: 173044 V004.1 LOCTITE 275 known as Loctite 275 250ML TOTTLE EGFD. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational Exposure Limits Valid for Great Britain Ingredient [Regulated substance] ppm mg/m3 Silicon dioxide 6 112945-52-5 [SILICA, AMORPHOUS, INHALABLE DUST] Silicon dioxide 2,4 112945-52-5 [SILICA, AMORPHOUS, RESPIRABLE DUST] Methyl methacrylate 100 416 80-62-6 [METHYL METHACRYLATE] Methyl methacrylate 50 208 80-62-6 [METHYL METHACRYLATE] Methyl methacrylate 100 80-62-6 [METHYL METHACRYLATE] Methyl methacrylate 50 80-62-6 [METHYL METHACRYLATE] Occupational Exposure Limits Valid for Ireland Ingredient [Regulated substance] ppm mg/m3 Silicon dioxide 6 112945-52-5 [SILICA, AMORPHOUS, TOTAL INHALABLE DUST] Silicon dioxide 2,4 112945-52-5 [SILICA, AMORPHOUS, RESPIRABLE DUST] Methyl methacrylate 50 80-62-6 [METHYL METHACRYLATE] Methyl methacrylate 100 80-62-6 [METHYL METHACRYLATE] Methyl methacrylate 100 80-62-6 [METHYL METHACRYLATE] Methyl methacrylate 50 80-62-6 [METHYL METHACRYLATE] Value type Short term exposure limit Regulatory list category / Remarks Time Weighted Average EH40 WEL (TWA): Time Weighted Average EH40 WEL (TWA): Short Term Exposure EH40 WEL Limit (STEL): Time Weighted Average EH40 WEL (TWA): Short Term Exposure Indicative ECTLV Limit (STEL): Time Weighted Average Indicative ECTLV (TWA): Value type Short term exposure limit Regulatory list category / Remarks Time Weighted Average IR_OEL (TWA): Time Weighted Average IR_OEL (TWA): Time Weighted Average Indicative OELV IR_OEL (TWA): Short Term Exposure Indicative OELV IR_OEL Limit (STEL): Short Term Exposure Indicative ECTLV Limit (STEL): Time Weighted Average Indicative ECTLV (TWA): SDS No.: 173044 V004.1 LOCTITE 275 known as Loctite 275 250ML TOTTLE EGFD. Predicted No-Effect Concentration (PNEC): Name on list Environmental Exposure Compartment