PMMA Adhesive

Hazard statements (CLP)

H225, H315, H317, H335

Code

Statements

H225

Highly Flammable liquid and vapour

2.1 Classification of the substance or mixture

Under the Regulation (WE) no 1272/2008 Flammable liquids, Hazard Category 2; with assigned phrase stating the type of hazard H225 Highly flammable liquid and vapour Skin irritation, Hazard Category 2; with assigned phrase stating the type of hazard H315 Causes skin irritation Sensitisation – Skin, Hazard Category 1; with assigned phrase stating the type of hazard H317 May cause an allergic skin reaction Specific target organ toxicity – Single exposure, Hazard Category 3, Respiratory tract irritation; with assigned phrase stating the type of hazard H335 May cause respiratory irritation According to the Directive 67/548/EEC (as amended) F – Highly flammable with assigned phrase R: R 11 – Highly flammable Xi – Irritating with assigned phrases R: R 37/38 – Irritating to respiratory system and skin Xi – Sensitizing with assigned phrase R: R 43 – may cause sensitisation by skin contact Health: irritating to skin and respiratory system, prolonged or repeated contact with product may cause allergic skin reaction

Environmental hazards

potentially hazardous for environment

Other physicochemical hazards

can polymerize with large exothermic effect Fire hazards: highly flammable liquid. Product vapours form flammable/explosive mixtures with air -

2.2 Label elements

Under the Regulation (WE) no 1272/2008

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour H315 Causes skin irritation. H317 May cause an allergic skin reaction H335 May cause respiratory irritation R R 11 – Highly flammable R 37/38 – Irritating to respiratory system and skin R 43 – may cause sensitisation by skin contact

Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking P233 Keep container tightly closed P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting equipment P242 Use only non-sparking tools P243 Take precautionary measures against static discharge P261 Avoid breathing dust/fume/gas/mist/vapours/spray P264 Wash hand and face thoroughly after handling. P270 Do not eat, drink or smoke when using this product P271 Use only outdoors or in a well-ventilated area P272 Contaminated work clothing should not be allowed out of the workplace P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P370 + P378 In case of fire: Light, middle-weight and heavy fire-fighting foam, dry chemicals, carbon dioxide to extinguish P304 + P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. P312 Call a POISON CENTER/doctor/physician if you feel unwell P333 + P313 If skin irritation or rash occurs: Get medical advice/attention P362 + P364 Take off contaminated clothing and wash it before reuse

Storage

P403 + P235 + P233 Store in a well-ventilated, cool place. Keep container tightly closed. P405 Store locked up.

Disposal

P501 Dispose of contents/container in accordance with local/regional/national/international regulation

Hazardous Ingredients

Methyl methacrylate - According to the Directive 67/548/EEC (as amended) Methyl methacrylate

Hazard pictograms

F – Highly flammable Xi – Irritant

Precautionary statements

S S 1/2 – Keep locked up and out of the reach of children S 16 – Keep away from sources of ignition - No smoking S 23 – Do not breathe gas/vapour/spray S 24 – Avoid contact with skin S 36/37 – Wear suitable protective clothing and suitable gloves S 45 – In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)

2.3 Other hazards

The product doesn’t meet the criteria for PBT or vPvB in accordance with Annex XIII of REACH Regulation.