HEADLAND STAFF 500

Hazard statements (CLP)

H302, H318

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Lesser celandine, Procumbent pearlwort, from one application but often

2.1 Classification of the substance or mixture

Self-heal, Silverweed, Yarrow requires further applications to EEC/99/45 : Xn R22 - Harmful if swallowed. give adequate control. Xi R41 - Risk of serious damage to eyes. 1 treatment will normally kill plants at all stages of growth up to the early bud stage. For best N R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. levels of control, treat in April - June when rosettes are growing strongly but before flower EG_1272/08 : AcuteTox.4 H302 - Harmful if swallowed. buds are well formed. EyeDam.1 H318 - Causes serious eye damage.

2.2 Label elements

a Operator Protection according directive 1999/45/EG Engineering control of operator exposure must be used where reasonably practicable in

Hazard pictograms

addition to the following personal protective equipment: SUITABLE PROTECTIVE GLOVES AND FACE PROTECTION (FACE SHIELD) when handling the concentrate. WEAR SUITABLE PROTECTIVE GLOVES when handling contaminated surfaces. WEAR SUITABLE PROTECTIVE CLOTHING (IMPERMEABLE COVERALLS) AND SUITABLE PROTECTIVE GLOVES when applying by hand-held equipment. Xn N R22 - Harmful if swallowed. and plenty of water. If symptoms persist, call a physician. Wash contaminated clothing R41 - Risk of serious damage to eyes. before re-use. R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the Inhalation: Move to fresh air. If symptoms persist, call a physician. aquatic environment. Ingestion: Rinse mouth. Do NOT induce vomiting. If swallowed, seek medical advice S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. immediately and show this container or label. S35 - This material and its container must be disposed of in a safe way. 4.2. Most important symptoms and effects, both acute and delayed S39 - Wear eye/face protection. Symptoms: No information available. S57 - Use appropriate container to avoid environmental contamination. 4.3. Indication of any immediate medical attention and special treatment needed REGULATION (EC) No 1272/2008 Treatment: Treat symptomatically. 5. FIREFIGHTING MEASURES 5.1. Extinguishing media Suitable extinguishing media: Water spray, Dry powder, Sand, Foam, Carbon dioxide (CO2) Extinguishing media which shall not be used for safety reasons: High volume water jet 5.2. Special hazards arising from the substance or mixture GHS05 GHS07 Specific hazards during firefighting: In the event of fire (HCl,Cl2,NOx,CO) may be formed.

Signal word

Danger 5.3. Advice for firefighters H302 - Harmful if swallowed. Special protective equipment for firefighters: Use personal protective equipment. In the event H318 - Causes serious eye damage. of fire, wear self-contained breathing apparatus. P264 - Wash hands thoroughly after handling.

Further information

Standard procedure for chemical fires. Collect contaminated fire P270 - Do not eat, drink or smoke when using this product. extinguishing water separately. This must not be discharged into drains. P280 - Wear protective gloves/ protective clothing/ eye protection/ face protection. 6. ACCIDENTAL RELEASE MEASURES P301 + 6.1. Personal precautions, protective equipment and emergency procedures P312 - IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel Use personal protective equipment. (see Chapter 8) unwell. 6.2. Environmental precautions P330 - Rinse mouth. Do not flush into surface water or sanitary sewer system. P305 + - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact 6.3. Methods and materials for containment and cleaning up P351 + lenses, if present and easy to do. Continue rinsing. Methods for cleaning up: Soak up with inert absorbent material (e.g. sand, silica gel, acid P338 binder, universal binder, sawdust). Shovel into suitable container for disposal.

2.3 Other hazards

Additional advice: Never return spills in original containers for re-use. This mixture contains no substance considered to be very persistent nor very 6.4. Reference to other sections bioaccumulating (vPvB). see Chapter 13