C496 CLEAR HS SR 2 1

Hazard statements (CLP)

H226, H315, H336, H412

Code

Statements

H226

Flammable liquid and vapour

Hazard pictograms

GHS02 GHS07

Hazardous Ingredients

n-butyl ester CAS: 123-86-4 n-butyl ester 25-<30% EINECS: 204-658-1 Flam. Liq. 3, H226 Index number: 607-025-00-1 STOT SE 3, H336 RTECS: AF 7350000 EUH066 Reg.nr.: 01-2119485493-29-007 01-2119485493-29-004 01-2119485493-29-003 01-2119485493-29-005 01-2119485493-29 CAS: 1330-20-7 xylene 10-<15% Index number: 601-022-00-9 Flam. Liq. 3, H226 Acute Tox. 4, H312; Acute Tox. 4, H332; Skin Irrit. 2, H315 ATE DNELs inhalative 11 mg/m3 CAS: 108-65-6 2-methoxy-1-methylethyl acetate 5-<10% EINECS: 203-603-9 Flam. Liq. 3, H226 Index number: 607-195-00-7 Reg.nr.: 01-2119475791-29-0001 01-2119475791-29 CAS: 112-07-2 2-butoxyethyl acetate 5-<10% EINECS: 203-933-3 Acute Tox. 4, H312; Acute Tox. 4, H332 Index number: 607-038-00-2 ATE DNELs inhalative 11 mg/m3 RTECS: KJ 8925000 Reg.nr.: 01-2119475112-47-0002 CAS: 41556-26-7 bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate ≥0.25-<0.9% EINECS: 255-437-1 Aquatic Acute 1, H400 (M=1); Aquatic Chronic 1, H410 (M=1) Skin Sens. 1, H317 CAS: 82919-37-7 methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate ≥0.1-<0.25% EINECS: 280-060-4 Aquatic Acute 1, H400 (M=1); Aquatic Chronic 1, H410 (M=1) Skin Sens. 1, H317

Hazard statements

H226 Flammable liquid and vapour. H315 Causes skin irritation. H336 May cause drowsiness or dizziness. H412 Harmful to aquatic life with long lasting effects.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P241 Use explosion-proof [electrical/ventilating/lighting] equipment. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

Additional information

EUH208 Contains bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate, methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate. May produce an allergic reaction. For the wording of the listed hazard phrases refer to section 16 * SECTION 4: Mere prve pomoæi · 4.1 Description of first aid measures · General information: Immediately remove any clothing soiled by the product. · After inhalation: In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Immediately wash with water and soap and rinse thoroughly. In case of skin contact DO NOT clean effected area with solvents or thinners. Take off all contaminated clothing at once. Wash skin thoroughly with neutral pH soap and water. In any suspicion that skin irritation persists call a doctor. · After eye contact: Rinse opened eye for several minutes under running water. · After swallowing: If symptoms persist consult doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed If the person is unconsious place in recovery position and wait for medical help. Always keep the person at the rest position.If person is concious necessary oxygen respiration treatment. * SECTION 5: Mere za gašenje požara · 5.1 Extinguishing media · Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · For safety reasons unsuitable extinguishing agents: Water with full jet · 5.2 Special hazards arising from the substance or mixture In case of fire, the following can be released: · Hazarous decomposition products When exposed to high temperature or in direct contact with fire it may produce hazarous decomposition products such as Carbon Monoxide, Carbon Dioxide, black dense smoke and derivatives of nitrogen oxides · 5.3 Advice for firefighters Firefighters should always protective equipment and breathing apparatus when handling fire coming from these products · 5.6 Fire and explosion Hazards This product is a flammable liquid. When exposed to high heat vapours may form explosive mixtures with air. All sources of ignition need to be removed. Solvent vapours are heavier than air and may spread along the floor. · Speial protective equipment and fire fighting procedures: No special measures required. · Additional information Collect contaminated fire fighting water separately. It must not enter the sewage system. * SECTION 6: Mere u sluèaju sluèajnog ispuštanja · 6.1 Personal precautions, protective equipment and emergency procedures Keep away from ignition sources. Ensure adequate ventilation Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to section 13. Ensure adequate ventilation. · 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. SECTION 7: Rukovanje i skladištenje · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. · Information about fire - and explosion protection: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. · 7.2 Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available. * SECTION 8: Kontrola izloženosti/ lièna zaštita · 8.1 Control parameters · Ingredients with limit values that require monitoring at the workplace: 123-86-4 n-butyl ester OGV (Serbia) Short-term value: 723 mg/m³, 150 ppm Long-term value: 241 mg/m³, 50 ppm IOELV (EU) Short-term value: 723 mg/m³, 150 ppm Long-term value: 241 mg/m³, 50 ppm 1330-20-7 xylene OGV (Serbia) Short-term value: 442 mg/m³, 100 ppm Long-term value: 221 mg/m³, 50 ppm hemijska materija može štetno delovati na kožu IOELV (EU) Short-term value: 442 mg/m³, 100 ppm Long-term value: 221 mg/m³, 50 ppm Skin 108-65-6 2-methoxy-1-methylethyl acetate OGV (Serbia) Short-term value: 550 mg/m³, 100 ppm Long-term value: 275 mg/m³, 50 ppm hemijska materija može štetno delovati na kožu IOELV (EU) Short-term value: 550 mg/m³, 100 ppm Long-term value: 275 mg/m³, 50 ppm Skin 112-07-2 2-butoxyethyl acetate OGV (Serbia) Short-term value: 333 mg/m³, 50 ppm Long-term value: 133 mg/m³, 20 ppm hemijska materija može štetno delovati na kožu IOELV (EU) Short-term value: 333 mg/m³, 50 ppm Long-term value: 133 mg/m³, 20 ppm Skin · Regulatory information OGV (Serbia): Pravilnik o preventivnim merama za bezbedan i zdrav rad pri izlaganju hemijskim materijama IOELV (EU): (EU) 2019/1831 · DNELs ATE (Acute Toxicity Estimates) Inhalative DNELs 62.7 mg/m3 1330-20-7 xylene Inhalative DNELs 11 mg/m3 (ATE) 112-07-2 2-butoxyethyl acetate Inhalative DNELs 11 mg/m3 (ATE) · Additional information: The lists valid during the making were used as basis. · 8.2 Exposure controls · Individual protection measures, such as personal protective equipment · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the skin. Avoid contact with the eyes and skin. · Respiratory protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self- contained respiratory protective device. · Hand protection Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · For the permanent contact gloves made of the following materials are suitable: Fluorocarbon rubber (Viton) · For the permanent contact of a maximum of 15 minutes gloves made of the following materials are suitable: Rubber gloves · Eye/face protection Tightly sealed goggles · Body protection: Protective work clothing * SECTION 9: Fizièka i hemijska svojstva · 9.1 Information on basic physical and chemical properties · General Information · Physical state Liquid · Colour: According to product specification · Odour: Characteristic · Odour threshold: Not determined. · Melting point/freezing point: Undetermined. · Boiling point or initial boiling point and boiling range 124-128 °C ( 123-86-4 n-butyl ester) · Flammability Flammable. · Lower and upper explosion limit · Lower: 1.2 Vol % ( 123-86-4 n-butyl ester) · Upper: 7.5 Vol % ( 123-86-4 n-butyl ester) · Flash point: 23 - 60 °C · Autoignition temperature: 280 °C ( 112-07-2 2-butoxyethyl acetate) · Decomposition temperature: Not determined. · pH Mixture is non-soluble (in water). · Viscosity: · Kinematic viscosity at 20 °C 0 mm²/s · Dynamic: Not determined. · Solubility · water: Not miscible or difficult to mix. · Partition coefficient n-octanol/water (log value) Not determined. · Vapour pressure at 20 °C: 10.7 hPa ( 123-86-4 n-butyl ester) · Vapour pressure at 50 °C: 55 hPa · Density and/or relative density · Density at 20 °C: 0.98 g/cm³ · Relative density Not determined. · Vapour density Not determined. · 9.2 Other information · Appearance: · Form: Fluid · Important information on protection of health and environment, and on safety. · Ignition temperature: Product is not selfigniting. · Explosive properties: Risk of explosion by shock, friction, fire or other sources of ignition. · Solvent content: · Organic solvents: 53.6 % · VOC (EC) 525.1 g/l · Solids content (volume): 49.0 % · Change in condition · Evaporation rate Not determined. · Information with regard to physical hazard classes · Explosives Void · Flammable gases Void · Aerosols Void · Oxidising gases Void · Gases under pressure Void · Flammable liquids Flammable liquid and vapour. · Flammable solids Void · Self-reactive substances and mixtures Void · Pyrophoric liquids Void · Pyrophoric solids Void · Self-heating substances and mixtures Void · Substances and mixtures, which emit flammable gases in contact with water Void · Oxidising liquids Void · Oxidising solids Void · Organic peroxides Void · Corrosive to metals Void · Desensitised explosives Void SECTION 10: Stabilnost i reaktivnost · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known. · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known. * SECTION 11: Toksikološki podaci · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values relevant for classification: ATE (Acute Toxicity Estimates) Dermal LD50 10.414 mg/kg (rabbit) 123-86-4 n-butyl ester Oral LD50 13,100 mg/kg (rat) Dermal LD50 >5,000 mg/kg (rabbit) Inhalative LC50/4 h >21 mg/l (rat) 1330-20-7 xylene Oral LD50 4,300 mg/kg (rat) Dermal LD50 2,000 mg/kg (rabbit) 108-65-6 2-methoxy-1-methylethyl acetate Oral LD50 8,532 mg/kg (rat) Inhalative LC50/4 h 35.7 mg/l (rat) 112-07-2 2-butoxyethyl acetate Oral LD50 2,400 mg/kg (rat) Dermal LD50 1,580 mg/kg (rabbit) · Primary irritant effect: · Skin corrosion/irritation Causes skin irritation. · Serious eye damage/irritation Based on available data, the classification criteria are not met. · Respiratory or skin sensitisation Based on available data, the classification criteria are not met. · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure May cause drowsiness or dizziness. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed. * SECTION 12: Ekotoksikološki podaci · 12.1 Toxicity · Aquatic toxicity: This product is not toxic for the aquatic life. Nevertheless do not dispose the product or any cleaning solvents used along with this product into the sea · 12.2 Persistence and degradability Heavily biodegradable This prouduct contains polyesteric molecules and organic solvents and is not known to be bioaccumulative. It can be considered as biodegradable in small quantities. In case of disposal, it should be treated as a hazardous material and should be disposed accordingly. Do not just throw it away · Other information: The product is not easily biodegradable. · 12.3 Bioaccumulative potential Due to the distribution coefficient n-octanol/water an accumulation in organisms is not expected. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: This product contains no substance that is considered to be persistent,bioaccumulating or non toxic(PBT). · vPvB: This mixture contains no substance that is considered to be very persistent or very bioaccumulating (vPvB). · 12.6 Endocrine disrupting properties The product does not contain substances with endocrine disrupting properties. · 12.7 Other adverse effects · Remark: Harmful to fish · Additional ecological information: · General notes: Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Harmful to aquatic organisms * SECTION 13: Odlaganje · 13.1 Waste treatment methods · Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. · European waste catalogue HP3 Flammable HP5 Specific Target Organ Toxicity (STOT)/Aspiration Toxicity HP14 Ecotoxic · Uncleaned packaging: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Podaci o transportu · 14.1 UN number or ID number · ADR, IMDG, IATA · 14.2 UN proper shipping name · ADR · IMDG, IATA · 14.3 Transport hazard class(es) · ADR · Class · Label · IMDG, IATA · Class · Label · 14.4 Packing group · ADR, IMDG, IATA · 14.5 Environmental hazards: · Marine pollutant: · 14.6 Special precautions for user · Hazard identification number (Kemler code): · EMS Number: · Stowage Category · 14.7 Maritime transport in bulk according to IMO instruments · Transport/Additional information: · ADR · Limited quantities (LQ) · Excepted quantities (EQ) · Transport category · Tunnel restriction code · IMDG · Limited quantities (LQ) · Excepted quantities (EQ) · UN "Model Regulation": 61.0.37 UN1263 UN1263 PAINT PAINT 3 (F1) Flammable liquids. 3 3 Flammable liquids. 3 III No Warning: Flammable liquids. 30 F-E,S-E A Not applicable. 5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml 3 D/E 5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN 1263 PAINT, 3, III RS SECTION 15: Regulatorni podaci •3Y · 15.1 Safety, health and environmental regulations/legislation specific for the substance or

Results of PBT and vPvB assessment

This product contains no substance that is considered to be persistent,bioaccumulating or non toxic(PBT). This mixture contains no substance that is considered to be very persistent or very bioaccumulating (vPvB).

PBT Substances

Not applicable

vPvB Substances

Not applicable * SECTION 3: Sastav/ Podaci o sastojcima · 3.2 Mixtures · Description: Mixture of hazardous substances listed below with nonhazardous additions.

2.1 Classification of the substance or mixture

· Classification according to Regulation (EC) No 1272/2008