NUMBER

Hazard statements (CLP)

H302, H315, H317, H332, H334, H350

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

THE HEALTH HAZARDS INFORMATION GIVEN IN SDS HW-7031 FOR WELDING PRODUCTS AND THERMAL SPRAY WIRE ALSO APPLY. The health hazards described in this section do not apply under normal handling and use of these products in solid form. Cutting, grinding, etc., of these products may produce dust, or particulate containing the component elements of these materials with associated health hazards described in this section. If these products are involved in welding, thermal cutting, or melting, the health hazards described in the Haynes Wire Company SDS for Welding Products and Thermal Spray Wire also apply. GHS Hazard Classification – Signal Word, Classification, and Category Hazard Codes and Hazard Statements separate classifications are provided for each Haynes product or product groups) All products in Section 1: Danger: Carcinogenicity (Category 1A) H350 May cause cancer All products in Section 1: Warning: Skin sensitization, (Category 1) H317 May cause an allergic skin reaction All products in Section 1: Danger: Respiratory sensitization, (Category 1) H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled All products in Section 1: Warning, Skin irritation (Category 2) H315 Causes skin irritation All products in Section 1: Warning: Acute toxicity, inhalation (Category 4) H 332 Harmful if inhaled All products except those listed below: Warning, Acute toxicity, oral (Category 4) H 302 Harmful if swallowed HASTELLOY® HYBRID®BC1, C-86, D205, G-35, N, 601, 690, 242, 75, 625, 718, X-750, 625SQ, and HAYNES® 625(Low Iron) alloy 2.2 Label Elements and Hazards (applies to dust and metal fume only)

Precautionary statements

Symptoms; All products in Section 1 P201 Obtain special instructions before use. DANGER P202 Do not handle until all safety precautions have been read and understood. P261 + P270 Do not eat, drink or smoke when using this product. Avoid breathing dust or fume. P264 Wash hands thoroughly after touching dust created by these products. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves, clothing, eye and/or face protection. WARNING P284 In case of inadequate ventilation, wear respiratory protection Hazards not otherwise classified or not covered by GHS INHALATION: Inhalation of metal dust, fume, or powder may result from melting, dross handling, casting, welding, thermal cutting, grinding, crushing, or similar operations which generate airborne metal particulate during use of these materials. Inhaled particulate may irritate the respiratory tract. Excessive inhalation of aluminum, cobalt, copper, manganese, nickel, and zinc can cause respiratory irritation, cough, bronchitis, chills, “metal fume fever,” and asthma-like symptoms. INGESTION: Hand, clothing, food, and drink contact with metal dust, fume, or powder can cause ingestion of particulate during hand to mouth activities such as drinking, smoking, nail biting, etc. Ingestion of large doses may cause nausea, vomiting, and diarrhea. SKIN: Skin contact with the dust or fume form of these materials may cause irritation and in some sensitive individuals an allergic dermatitis when elements such as chromium, cobalt, copper, and nickel are present. EYES: Contact with particulate metal (dust, fume, or powder) may inflame the conjunctiva. Airborne particulate (chips, dust, or powder) is always a potential problem as well as inserting fingers into the eye socket if the hand or clothing is contaminated with metal particulate. Respiratory disease with symptoms ranging from shortness of breath and cough to permanent disability due to loss of lung function; sensitization or hypersensitivity and fibrosis or subsequent effects on the heart may be caused by excessive exposure to dust or fumes containing cobalt, nickel, titanium, and tungsten. Central nervous system depression has been identified with excessive manganese exposure. Insoluble nickel compounds and hexavalent chromium compounds have been linked to nasal, bronchial, and lung cancers. Aluminum and iron have been indicated to cause gastro-intestinal disorders and non-significant changes in the lung. Chronic health effects specific to an element(s) may be difficult to detect due to the numerous elemental constituents in these alloys.

Medical Conditions Generally Aggravated by Exposure

Individuals who may have had an allergic reaction or sensitivity to metals such as chromium, copper, cobalt, and nickel may encounter skin rash or dermatitis if skin contact with this product occurs. Persons with impaired pulmonary function, airway diseases and conditions such as asthma, emphysema, chronic bronchitis, etc., may incur further disability if excessive concentrations of dust or fume are inhaled. If prior damage or disease to the Neurologic (nervous), Circulatory, Hematologic (blood) or Renal (kidney) systems has occurred, proper screening or examinations should be conducted on individuals who may be exposed to further risk if handling and use of these materials cause excessive exposure.

2.1 Classification of the substance or mixture

Hazard Codes and Hazard Statements (separate classifications are provided for each Haynes product or product groups) All products in Section 1: Danger: Carcinogenicity (Category 1A) H350 May cause cancer All products in Section 1: Warning: Skin sensitization, (Category 1) H317 May cause an allergic skin reaction All products in Section 1: Danger: Respiratory sensitization, (Category 1) H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled All products in Section 1: Warning, Skin irritation (Category 2) H315 Causes skin irritation All products in Section 1: Warning: Acute toxicity, inhalation (Category 4) H 332 Harmful if inhaled All products except those listed below: Warning, Acute toxicity, oral (Category 4) H 302 Harmful if swallowed HASTELLOY® HYBRID®BC1, C-86, D205, G-35, N, 601, 690, 242, 75, 625, 718, X-750, 625SQ, and HAYNES® 625(Low Iron) alloy.